Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol

La-promoted 10%Ni/Al2O3catalyst was prepared by wet impregnation method and evaluated for ethanoldry reforming at various reaction temperatures and partial pressure of reactants. Ni particles were finelydispersed on catalyst surface and catalyst exhibited surface area of about 86 m2g−1. X-ray diffra...

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Main Authors:	Vo, Dai-Viet N., Mahadi, Bahari, Phuc, Nguyen Huu Huy, Alenazey, Feraih, Vu, Khanh B., Nurul Aini, Razali
Format:	Article
Language:	English
Published:	Elsevier B.V. 2017
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/19918/ http://umpir.ump.edu.my/id/eprint/19918/ http://umpir.ump.edu.my/id/eprint/19918/ http://umpir.ump.edu.my/id/eprint/19918/1/Mahadi_Catalysis%20Today_2017.pdf

id	ump-19918
recordtype	eprints
spelling	ump-199182019-10-18T02:58:45Z http://umpir.ump.edu.my/id/eprint/19918/ Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol Vo, Dai-Viet N. Mahadi, Bahari Phuc, Nguyen Huu Huy Alenazey, Feraih Vu, Khanh B. Nurul Aini, Razali TP Chemical technology La-promoted 10%Ni/Al2O3catalyst was prepared by wet impregnation method and evaluated for ethanoldry reforming at various reaction temperatures and partial pressure of reactants. Ni particles were finelydispersed on catalyst surface and catalyst exhibited surface area of about 86 m2g−1. X-ray diffractionmeasurements indicated the formation of NiO and La2O3phases whilst NiO and spinel NiLa2O4formswere reduced to metallic Ni during H2reduction. Catalytic activity seemed to be stable with time-on-stream beyond 5–7 h and both C2H5OH and CO2conversions reached to 45.5% and 36.3%, respectively withvarying CO2partial pressure from 0 to 50 kPa. Significantly, H2/CO ratio varied from 1.3–2.3 favoured forFischer-Tropsch synthesis. The optimal C2H5OH partial pressure for reactant conversions was observedat 30–40 kPa. Reaction temperature varied from 923 to 973 K enhanced C2H5OH conversion about 167%.The heterogeneous nature of carbonaceous deposits including filamentous and graphitic carbons on thesurface of spent catalyst was evidenced by SEM, TEM and Raman analyses. However, carbon nanofilamentappeared to be predominant with concentration of 69.8%. Elsevier B.V. 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/19918/1/Mahadi_Catalysis%20Today_2017.pdf Vo, Dai-Viet N. and Mahadi, Bahari and Phuc, Nguyen Huu Huy and Alenazey, Feraih and Vu, Khanh B. and Nurul Aini, Razali (2017) Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol. Catalysis Today, 291. pp. 67-75. ISSN 0920-5861 https://doi.org/10.1016/j.cattod.2017.02.019 DOI: 10.1016/j.cattod.2017.02.019
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Vo, Dai-Viet N. Mahadi, Bahari Phuc, Nguyen Huu Huy Alenazey, Feraih Vu, Khanh B. Nurul Aini, Razali Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol
description	La-promoted 10%Ni/Al2O3catalyst was prepared by wet impregnation method and evaluated for ethanoldry reforming at various reaction temperatures and partial pressure of reactants. Ni particles were finelydispersed on catalyst surface and catalyst exhibited surface area of about 86 m2g−1. X-ray diffractionmeasurements indicated the formation of NiO and La2O3phases whilst NiO and spinel NiLa2O4formswere reduced to metallic Ni during H2reduction. Catalytic activity seemed to be stable with time-on-stream beyond 5–7 h and both C2H5OH and CO2conversions reached to 45.5% and 36.3%, respectively withvarying CO2partial pressure from 0 to 50 kPa. Significantly, H2/CO ratio varied from 1.3–2.3 favoured forFischer-Tropsch synthesis. The optimal C2H5OH partial pressure for reactant conversions was observedat 30–40 kPa. Reaction temperature varied from 923 to 973 K enhanced C2H5OH conversion about 167%.The heterogeneous nature of carbonaceous deposits including filamentous and graphitic carbons on thesurface of spent catalyst was evidenced by SEM, TEM and Raman analyses. However, carbon nanofilamentappeared to be predominant with concentration of 69.8%.
format	Article
author	Vo, Dai-Viet N. Mahadi, Bahari Phuc, Nguyen Huu Huy Alenazey, Feraih Vu, Khanh B. Nurul Aini, Razali
author_facet	Vo, Dai-Viet N. Mahadi, Bahari Phuc, Nguyen Huu Huy Alenazey, Feraih Vu, Khanh B. Nurul Aini, Razali
author_sort	Vo, Dai-Viet N.
title	Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol
title_short	Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol
title_full	Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol
title_fullStr	Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol
title_full_unstemmed	Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol
title_sort	catalytic performance of la-ni/al2o3 catalyst for co2 reforming of ethanol
publisher	Elsevier B.V.
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/19918/ http://umpir.ump.edu.my/id/eprint/19918/ http://umpir.ump.edu.my/id/eprint/19918/ http://umpir.ump.edu.my/id/eprint/19918/1/Mahadi_Catalysis%20Today_2017.pdf
first_indexed	2023-09-18T22:28:32Z
last_indexed	2023-09-18T22:28:32Z
_version_	1777416130081587200

Catalytic Performance of La-Ni/Al2O3 Catalyst for CO2 Reforming of Ethanol

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