Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)

Polymerization is a process which is chemically combined of small molecules to produce a very large chain or network molecule, called a polymer. By the way, the small molecules may be alike, or they may represent of two, three, or more different compounds with different molecular weight. This resear...

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Main Author:	Noor Hariah , Wahab
Format:	Undergraduates Project Papers
Language:	English
Published:	2013
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/9457/ http://umpir.ump.edu.my/id/eprint/9457/ http://umpir.ump.edu.my/id/eprint/9457/1/CD8331.pdf

id	ump-9457
recordtype	eprints
spelling	ump-94572015-09-30T06:19:20Z http://umpir.ump.edu.my/id/eprint/9457/ Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA) Noor Hariah , Wahab TP Chemical technology Polymerization is a process which is chemically combined of small molecules to produce a very large chain or network molecule, called a polymer. By the way, the small molecules may be alike, or they may represent of two, three, or more different compounds with different molecular weight. This research proposes is to study the effect of temperature on polymerization kinetics of methyl methacrylate (MMA). Thermal study on methyl methacrylate is important to explain the heat and mass transfer phenomena during polymerization reaction. The objective of this study is to determine the temperature effect on polymerization kinetics of methyl methacrylate (MMA) with initiator. Mass of methyl methacrylate as monomer will be fixed at 3miligrams and also mass of initiator which is azo-bisisobutyronitrile (AIBN) will constant at 2miligrams. These two components will put on the pan by micropipette. The pan will tightly seal and be put into the differential scanning calorimetry (DSC). Each of samples will run until five hours in different temperatures (35°C, 45°C, 55°C, 65°C and 75° C). Then the polymerization kinetics and heat released are analyzed using this differential scanning calorimetry (DSC). From the (DSC) the curves or data of temperature, time and heat released are obtained. From these result obtained, increasing the temperature will decrease the time of reaction taken. High temperature will increase the amount of heat low or heat release. As increase the temperature, the rate of reaction increase due to the increasing of collision frequency and produce more energy to start the reaction. 2013-07 Undergraduates Project Papers NonPeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9457/1/CD8331.pdf Noor Hariah , Wahab (2013) Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA). Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang. http://iportal.ump.edu.my/lib/item?id=chamo:83365&theme=UMP2
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Noor Hariah , Wahab Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)
description	Polymerization is a process which is chemically combined of small molecules to produce a very large chain or network molecule, called a polymer. By the way, the small molecules may be alike, or they may represent of two, three, or more different compounds with different molecular weight. This research proposes is to study the effect of temperature on polymerization kinetics of methyl methacrylate (MMA). Thermal study on methyl methacrylate is important to explain the heat and mass transfer phenomena during polymerization reaction. The objective of this study is to determine the temperature effect on polymerization kinetics of methyl methacrylate (MMA) with initiator. Mass of methyl methacrylate as monomer will be fixed at 3miligrams and also mass of initiator which is azo-bisisobutyronitrile (AIBN) will constant at 2miligrams. These two components will put on the pan by micropipette. The pan will tightly seal and be put into the differential scanning calorimetry (DSC). Each of samples will run until five hours in different temperatures (35°C, 45°C, 55°C, 65°C and 75° C). Then the polymerization kinetics and heat released are analyzed using this differential scanning calorimetry (DSC). From the (DSC) the curves or data of temperature, time and heat released are obtained. From these result obtained, increasing the temperature will decrease the time of reaction taken. High temperature will increase the amount of heat low or heat release. As increase the temperature, the rate of reaction increase due to the increasing of collision frequency and produce more energy to start the reaction.
format	Undergraduates Project Papers
author	Noor Hariah , Wahab
author_facet	Noor Hariah , Wahab
author_sort	Noor Hariah , Wahab
title	Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)
title_short	Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)
title_full	Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)
title_fullStr	Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)
title_full_unstemmed	Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)
title_sort	temperature effect on polymerization kinetics of poly methyl methacrylate (pmma)
publishDate	2013
url	http://umpir.ump.edu.my/id/eprint/9457/ http://umpir.ump.edu.my/id/eprint/9457/ http://umpir.ump.edu.my/id/eprint/9457/1/CD8331.pdf
first_indexed	2023-09-18T22:08:03Z
last_indexed	2023-09-18T22:08:03Z
_version_	1777414841074450432

Temperature effect on polymerization kinetics of poly methyl methacrylate (PMMA)

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