Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges

Tin oxide (SnO2) is a candidate for applications requiring high electrical conductivity and optical transparency, such as a photoanode in dye-sensitised solar cells (DSSCs), due to its higher electron mobility and wider optical transparency than many other metal oxide semiconductors (MOS), such as T...

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Main Authors: Qamar, Wali, Azhar, Fakharuddin, Rajan, Jose
Format: Article
Language:English
Published: Elsevier Ltd 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/9392/
http://umpir.ump.edu.my/id/eprint/9392/
http://umpir.ump.edu.my/id/eprint/9392/
http://umpir.ump.edu.my/id/eprint/9392/1/fist-2015-rajan-Tin%20oxide%20as%20a%20photoanode.pdf
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spelling ump-93922018-02-19T07:20:39Z http://umpir.ump.edu.my/id/eprint/9392/ Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges Qamar, Wali Azhar, Fakharuddin Rajan, Jose Q Science (General) Tin oxide (SnO2) is a candidate for applications requiring high electrical conductivity and optical transparency, such as a photoanode in dye-sensitised solar cells (DSSCs), due to its higher electron mobility and wider optical transparency than many other metal oxide semiconductors (MOS), such as TiO2 and ZnO. However, DSSCs employing SnO2 show significantly lower photoconversion efficiency, compared to that achieved by popular choices, such as TiO2, due to its intrinsic limitations such as lower conduction band energy and isoelectric point. A survey of literature shows a revived interest in SnO2-based DSSCs, for example, strategies to (i) increase the dye uptake, (ii) increase its Fermi energy level, and (iii) reduce the recombination, such as by increasing surface roughness and novel morphologies towards (i), and doping of transition metals for (ii) and (iii). In response to these improvements, SnO2-based DSSCs showed similar open circuit voltage and superior short circuit current to that achieved by TiO2. We have undertaken a critical review on the progress made in overcoming the limitations and capitalising the advantages of SnO2 to fabricate more efficient DSSCs. We identify that more investment is required to reduce the recombination in SnO2 for it to emerge as an efficiency record holder in DSSCs. Elsevier Ltd 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9392/1/fist-2015-rajan-Tin%20oxide%20as%20a%20photoanode.pdf Qamar, Wali and Azhar, Fakharuddin and Rajan, Jose (2015) Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges. Journal of Power Sources, 293. pp. 1039-1052. ISSN 0378-7753 http://dx.doi.org/10.1016/j.jpowsour.2015.06.037 doi: 10.1016/j.jpowsour.2015.06.037
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Qamar, Wali
Azhar, Fakharuddin
Rajan, Jose
Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges
description Tin oxide (SnO2) is a candidate for applications requiring high electrical conductivity and optical transparency, such as a photoanode in dye-sensitised solar cells (DSSCs), due to its higher electron mobility and wider optical transparency than many other metal oxide semiconductors (MOS), such as TiO2 and ZnO. However, DSSCs employing SnO2 show significantly lower photoconversion efficiency, compared to that achieved by popular choices, such as TiO2, due to its intrinsic limitations such as lower conduction band energy and isoelectric point. A survey of literature shows a revived interest in SnO2-based DSSCs, for example, strategies to (i) increase the dye uptake, (ii) increase its Fermi energy level, and (iii) reduce the recombination, such as by increasing surface roughness and novel morphologies towards (i), and doping of transition metals for (ii) and (iii). In response to these improvements, SnO2-based DSSCs showed similar open circuit voltage and superior short circuit current to that achieved by TiO2. We have undertaken a critical review on the progress made in overcoming the limitations and capitalising the advantages of SnO2 to fabricate more efficient DSSCs. We identify that more investment is required to reduce the recombination in SnO2 for it to emerge as an efficiency record holder in DSSCs.
format Article
author Qamar, Wali
Azhar, Fakharuddin
Rajan, Jose
author_facet Qamar, Wali
Azhar, Fakharuddin
Rajan, Jose
author_sort Qamar, Wali
title Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges
title_short Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges
title_full Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges
title_fullStr Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges
title_full_unstemmed Tin Oxide as a Photoanode for Dye-sensitised Solar Cells: Current Progress and Future Challenges
title_sort tin oxide as a photoanode for dye-sensitised solar cells: current progress and future challenges
publisher Elsevier Ltd
publishDate 2015
url http://umpir.ump.edu.my/id/eprint/9392/
http://umpir.ump.edu.my/id/eprint/9392/
http://umpir.ump.edu.my/id/eprint/9392/
http://umpir.ump.edu.my/id/eprint/9392/1/fist-2015-rajan-Tin%20oxide%20as%20a%20photoanode.pdf
first_indexed 2023-09-18T22:07:55Z
last_indexed 2023-09-18T22:07:55Z
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