Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors

Electrochemical properties of activated carbon (AC) derived from oil palm kernel shell (PKS) are evaluated and compared with other biomass derived AC for fabricating high performance electrochemical double layer capacitors (EDLC). Cleaned PKS are carbonized by pyrolysis and subsequently activated by...

Full description

Bibliographic Details
Main Authors: Rajan, Jose, Izan Izwan, Misnon, Nurul Khairiyyah, Mohd Zain, Radhiyah, Abd Aziz, Baiju, Vidyadharan
Format: Article
Language:English
Published: Elsevier 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/9308/
http://umpir.ump.edu.my/id/eprint/9308/
http://umpir.ump.edu.my/id/eprint/9308/1/fist-2015-rajan-Electrochemical%20Properties.pdf
id ump-9308
recordtype eprints
spelling ump-93082017-11-21T02:03:06Z http://umpir.ump.edu.my/id/eprint/9308/ Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors Rajan, Jose Izan Izwan, Misnon Nurul Khairiyyah, Mohd Zain Radhiyah, Abd Aziz Baiju, Vidyadharan QC Physics QD Chemistry TK Electrical engineering. Electronics Nuclear engineering Electrochemical properties of activated carbon (AC) derived from oil palm kernel shell (PKS) are evaluated and compared with other biomass derived AC for fabricating high performance electrochemical double layer capacitors (EDLC). Cleaned PKS are carbonized by pyrolysis and subsequently activated by physical and chemical methods. The chemically AC show a wider pore distribution (1.49.3 nm) whereas the physically activated one has uniform pores (1.5 nm). The electrochemical properties of the two types of AC are evaluated using cyclic voltammetry (CV), charge–discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS) in three-electrode configuration. High specific capacitance (CS) (210 F g-1 in 1 M KOH electrolyte at 0.5 A g-1) is obtained for chemically AC whereas the CS for the physically AC is 50% lower (123 F g-1). Galvanostatic CDC tests show that the electrodes maintained ~ 9597% of CS after 1000 cycles. The EIS revealed that the PKS AC has low series resistance (< 0.6 ) and relaxation time (~0.69 s) which would therefore offers high power density in the EDLC devices. Elsevier 2015-05-30 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9308/1/fist-2015-rajan-Electrochemical%20Properties.pdf Rajan, Jose and Izan Izwan, Misnon and Nurul Khairiyyah, Mohd Zain and Radhiyah, Abd Aziz and Baiju, Vidyadharan (2015) Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors. Electrochimica Acta, 174. pp. 78-86. ISSN 0013-4686 http://dx.doi.org/10.1016/j.electacta.2015.05.163
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic QC Physics
QD Chemistry
TK Electrical engineering. Electronics Nuclear engineering
spellingShingle QC Physics
QD Chemistry
TK Electrical engineering. Electronics Nuclear engineering
Rajan, Jose
Izan Izwan, Misnon
Nurul Khairiyyah, Mohd Zain
Radhiyah, Abd Aziz
Baiju, Vidyadharan
Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors
description Electrochemical properties of activated carbon (AC) derived from oil palm kernel shell (PKS) are evaluated and compared with other biomass derived AC for fabricating high performance electrochemical double layer capacitors (EDLC). Cleaned PKS are carbonized by pyrolysis and subsequently activated by physical and chemical methods. The chemically AC show a wider pore distribution (1.49.3 nm) whereas the physically activated one has uniform pores (1.5 nm). The electrochemical properties of the two types of AC are evaluated using cyclic voltammetry (CV), charge–discharge cycling (CDC) and electrochemical impedance spectroscopy (EIS) in three-electrode configuration. High specific capacitance (CS) (210 F g-1 in 1 M KOH electrolyte at 0.5 A g-1) is obtained for chemically AC whereas the CS for the physically AC is 50% lower (123 F g-1). Galvanostatic CDC tests show that the electrodes maintained ~ 9597% of CS after 1000 cycles. The EIS revealed that the PKS AC has low series resistance (< 0.6 ) and relaxation time (~0.69 s) which would therefore offers high power density in the EDLC devices.
format Article
author Rajan, Jose
Izan Izwan, Misnon
Nurul Khairiyyah, Mohd Zain
Radhiyah, Abd Aziz
Baiju, Vidyadharan
author_facet Rajan, Jose
Izan Izwan, Misnon
Nurul Khairiyyah, Mohd Zain
Radhiyah, Abd Aziz
Baiju, Vidyadharan
author_sort Rajan, Jose
title Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors
title_short Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors
title_full Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors
title_fullStr Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors
title_full_unstemmed Electrochemical Properties of Carbon from Oil Palm Kernel Shell for High Performance Supercapacitors
title_sort electrochemical properties of carbon from oil palm kernel shell for high performance supercapacitors
publisher Elsevier
publishDate 2015
url http://umpir.ump.edu.my/id/eprint/9308/
http://umpir.ump.edu.my/id/eprint/9308/
http://umpir.ump.edu.my/id/eprint/9308/1/fist-2015-rajan-Electrochemical%20Properties.pdf
first_indexed 2023-09-18T22:07:45Z
last_indexed 2023-09-18T22:07:45Z
_version_ 1777414822126682112