Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior

Two new ether substituted azodyes were synthesized and characterized by different spectral analysis such as 1H NMR, 13C NMR, FTIR and UV/Vis. Synthesized compounds were used to study the photoisomerization phenomenon by using UV–Vis spectro-photometer. Interesting polarity dependent effect is observ...

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Main Authors:	Gan, Siew Mei, Zynia, Fernandes Pearl, A. R., Yuvaraj, Lutfor, M. R., Hegde, Gurumurthy
Format:	Article
Language:	English
Published:	Elsevier 2015
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/9275/ http://umpir.ump.edu.my/id/eprint/9275/ http://umpir.ump.edu.my/id/eprint/9275/ http://umpir.ump.edu.my/id/eprint/9275/1/fist-2015-siew-Polarity%20Dependent%20Photoisomerization.pdf

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spelling	ump-92752018-05-17T05:23:22Z http://umpir.ump.edu.my/id/eprint/9275/ Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior Gan, Siew Mei Zynia, Fernandes Pearl A. R., Yuvaraj Lutfor, M. R. Hegde, Gurumurthy Q Science (General) Two new ether substituted azodyes were synthesized and characterized by different spectral analysis such as 1H NMR, 13C NMR, FTIR and UV/Vis. Synthesized compounds were used to study the photoisomerization phenomenon by using UV–Vis spectro-photometer. Interesting polarity dependent effect is observed for the first time on these materials. Trans–cis (E–Z) and cis–trans (Z–E) conversion occurred within 41 s and 445 min, respectively for both the compounds in solutions. Polarizing optical microscopy studies revealed that there is no liquid crystal phase for both the compounds. The dramatic variation in the optical property is speculated to be the polarity of the chemical species. These derivatives are useful to fabricate optical data storage devices. Elsevier 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9275/1/fist-2015-siew-Polarity%20Dependent%20Photoisomerization.pdf Gan, Siew Mei and Zynia, Fernandes Pearl and A. R., Yuvaraj and Lutfor, M. R. and Hegde, Gurumurthy (2015) Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 149. pp. 875-880. ISSN 1386-1425 (print); 1873-3557 (online) http://dx.doi.org/10.1016/j.saa.2015.05.027 doi: 10.1016/j.saa.2015.05.027
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Gan, Siew Mei Zynia, Fernandes Pearl A. R., Yuvaraj Lutfor, M. R. Hegde, Gurumurthy Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior
description	Two new ether substituted azodyes were synthesized and characterized by different spectral analysis such as 1H NMR, 13C NMR, FTIR and UV/Vis. Synthesized compounds were used to study the photoisomerization phenomenon by using UV–Vis spectro-photometer. Interesting polarity dependent effect is observed for the first time on these materials. Trans–cis (E–Z) and cis–trans (Z–E) conversion occurred within 41 s and 445 min, respectively for both the compounds in solutions. Polarizing optical microscopy studies revealed that there is no liquid crystal phase for both the compounds. The dramatic variation in the optical property is speculated to be the polarity of the chemical species. These derivatives are useful to fabricate optical data storage devices.
format	Article
author	Gan, Siew Mei Zynia, Fernandes Pearl A. R., Yuvaraj Lutfor, M. R. Hegde, Gurumurthy
author_facet	Gan, Siew Mei Zynia, Fernandes Pearl A. R., Yuvaraj Lutfor, M. R. Hegde, Gurumurthy
author_sort	Gan, Siew Mei
title	Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior
title_short	Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior
title_full	Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior
title_fullStr	Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior
title_full_unstemmed	Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior
title_sort	polarity dependent photoisomerization of ether substituted azodyes: synthesis and photoswitching behavior
publisher	Elsevier
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/9275/ http://umpir.ump.edu.my/id/eprint/9275/ http://umpir.ump.edu.my/id/eprint/9275/ http://umpir.ump.edu.my/id/eprint/9275/1/fist-2015-siew-Polarity%20Dependent%20Photoisomerization.pdf
first_indexed	2023-09-18T22:07:41Z
last_indexed	2023-09-18T22:07:41Z
_version_	1777414817748877312

Polarity Dependent Photoisomerization of Ether Substituted Azodyes: Synthesis and Photoswitching Behavior

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