New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization

The first example of non-symmetric isoflavone-based fast photo-switchable liquid crystals with different functional groups at the terminal position were synthesized and characterized. Polarizing optical microscopy study revealed that the compounds showed least ordered nematic phase. Optical photo sw...

Full description

Bibliographic Details
Main Authors:	Hegde, Gurumurthy, A. R., Yuvaraj, Wan, Sinn Yam, Tze, Nee Chan, Yit, Peng Goh
Format:	Article
Language:	English
Published:	Elsevier 2015
Subjects:	Q Science (General) QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/8751/ http://umpir.ump.edu.my/id/eprint/8751/ http://umpir.ump.edu.my/id/eprint/8751/ http://umpir.ump.edu.my/id/eprint/8751/1/fist-2015-hedge-New%20Para-Substituted.pdf

id	ump-8751
recordtype	eprints
spelling	ump-87512018-08-28T04:36:56Z http://umpir.ump.edu.my/id/eprint/8751/ New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization Hegde, Gurumurthy A. R., Yuvaraj Wan, Sinn Yam Tze, Nee Chan Yit, Peng Goh Q Science (General) QD Chemistry The first example of non-symmetric isoflavone-based fast photo-switchable liquid crystals with different functional groups at the terminal position were synthesized and characterized. Polarizing optical microscopy study revealed that the compounds showed least ordered nematic phase. Optical photo switching study exhibited very fast photoisomerization effect in solution. The E–Z and Z–E conversion occurred around 3–5 s and 40–700 s respectively. This is also the first example of para-substituted non-symmetric isoflavone liquid crystals exhibiting very fast photo switching property in solution. Argument based on non-symmetrical behaviour might be the reason for the observed behaviour. Elsevier 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8751/1/fist-2015-hedge-New%20Para-Substituted.pdf Hegde, Gurumurthy and A. R., Yuvaraj and Wan, Sinn Yam and Tze, Nee Chan and Yit, Peng Goh (2015) New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 135. pp. 1115-1122. ISSN 1386-1425 (print); 1873-3557 (online) http://dx.doi.org/10.1016/j.saa.2014.08.009 DOI: 10.1016/j.saa.2014.08.009
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General) QD Chemistry
spellingShingle	Q Science (General) QD Chemistry Hegde, Gurumurthy A. R., Yuvaraj Wan, Sinn Yam Tze, Nee Chan Yit, Peng Goh New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization
description	The first example of non-symmetric isoflavone-based fast photo-switchable liquid crystals with different functional groups at the terminal position were synthesized and characterized. Polarizing optical microscopy study revealed that the compounds showed least ordered nematic phase. Optical photo switching study exhibited very fast photoisomerization effect in solution. The E–Z and Z–E conversion occurred around 3–5 s and 40–700 s respectively. This is also the first example of para-substituted non-symmetric isoflavone liquid crystals exhibiting very fast photo switching property in solution. Argument based on non-symmetrical behaviour might be the reason for the observed behaviour.
format	Article
author	Hegde, Gurumurthy A. R., Yuvaraj Wan, Sinn Yam Tze, Nee Chan Yit, Peng Goh
author_facet	Hegde, Gurumurthy A. R., Yuvaraj Wan, Sinn Yam Tze, Nee Chan Yit, Peng Goh
author_sort	Hegde, Gurumurthy
title	New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization
title_short	New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization
title_full	New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization
title_fullStr	New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization
title_full_unstemmed	New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization
title_sort	new para-substituted non-symmetric isoflavones for their fast photo-switching ability: synthesis and their liquid crystal characterization
publisher	Elsevier
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/8751/ http://umpir.ump.edu.my/id/eprint/8751/ http://umpir.ump.edu.my/id/eprint/8751/ http://umpir.ump.edu.my/id/eprint/8751/1/fist-2015-hedge-New%20Para-Substituted.pdf
first_indexed	2023-09-18T22:06:40Z
last_indexed	2023-09-18T22:06:40Z
_version_	1777414753539325952

New Para-substituted Non-symmetric Isoflavones for their Fast Photo-switching Ability: Synthesis and their Liquid Crystal Characterization

Similar Items