Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas

Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in mic...

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Main Authors: Norhayati, Abdullah, Cormack, Peter A. G.
Format: Article
Language:English
English
Published: Trans Tech Publications, Switzerland 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8742/
http://umpir.ump.edu.my/id/eprint/8742/
http://umpir.ump.edu.my/id/eprint/8742/
http://umpir.ump.edu.my/id/eprint/8742/1/Non-Aqueous%20Dispersion%20%28NAD%29%20Polymerisation-Based%20Synthetic%20Route%20to%20Hypercrosslinked%20Polymer%20With%20High%20Specific%20Surface%20Areas.pdf
http://umpir.ump.edu.my/id/eprint/8742/7/fkksa-2016-hayati-Non-Aqueous%20Dispersion.pdf
id ump-8742
recordtype eprints
spelling ump-87422018-05-14T07:12:53Z http://umpir.ump.edu.my/id/eprint/8742/ Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas Norhayati, Abdullah Cormack, Peter A. G. TP Chemical technology Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in microsphere form, and were used subsequently in hypercrosslinking reactions. Extensive microporosity was generated in the products, leading to remarkably high inner specific surface areas of up to ~1,500 m2/g. SEM and BET spectroscopy were used to monitor the course of the hypercrosslinking reactions. Trans Tech Publications, Switzerland 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8742/1/Non-Aqueous%20Dispersion%20%28NAD%29%20Polymerisation-Based%20Synthetic%20Route%20to%20Hypercrosslinked%20Polymer%20With%20High%20Specific%20Surface%20Areas.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/8742/7/fkksa-2016-hayati-Non-Aqueous%20Dispersion.pdf Norhayati, Abdullah and Cormack, Peter A. G. (2016) Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas. Advanced Materials Research, 1134. pp. 198-202. ISSN 1022-6680 (print), 1662-8985 (online) http://www.scientific.net/AMR.1134.198 doi: 10.4028/www.scientific.net/AMR.1134.198
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Norhayati, Abdullah
Cormack, Peter A. G.
Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
description Hypercrosslinked polymer microspheres with high specific surface areas were prepared successfully by exposing reactive, gel-type polymer precursors to a Friedel-Crafts catalyst. The lightly crosslinked gel-type polymer precursors were synthesised by non-aqueous dispersion (NAD) polymerisation in microsphere form, and were used subsequently in hypercrosslinking reactions. Extensive microporosity was generated in the products, leading to remarkably high inner specific surface areas of up to ~1,500 m2/g. SEM and BET spectroscopy were used to monitor the course of the hypercrosslinking reactions.
format Article
author Norhayati, Abdullah
Cormack, Peter A. G.
author_facet Norhayati, Abdullah
Cormack, Peter A. G.
author_sort Norhayati, Abdullah
title Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
title_short Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
title_full Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
title_fullStr Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
title_full_unstemmed Non-Aqueous Dispersion (NAD) Polymerisation-Based Synthetic Route to Hypercrosslinked Polymer with High Specific Surface Areas
title_sort non-aqueous dispersion (nad) polymerisation-based synthetic route to hypercrosslinked polymer with high specific surface areas
publisher Trans Tech Publications, Switzerland
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/8742/
http://umpir.ump.edu.my/id/eprint/8742/
http://umpir.ump.edu.my/id/eprint/8742/
http://umpir.ump.edu.my/id/eprint/8742/1/Non-Aqueous%20Dispersion%20%28NAD%29%20Polymerisation-Based%20Synthetic%20Route%20to%20Hypercrosslinked%20Polymer%20With%20High%20Specific%20Surface%20Areas.pdf
http://umpir.ump.edu.my/id/eprint/8742/7/fkksa-2016-hayati-Non-Aqueous%20Dispersion.pdf
first_indexed 2023-09-18T22:06:38Z
last_indexed 2023-09-18T22:06:38Z
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