Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
Combustion of citrate complex has been a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equival...
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Penerbit Universiti Malaysia Perlis
2014
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Online Access: | http://umpir.ump.edu.my/id/eprint/8567/ http://umpir.ump.edu.my/id/eprint/8567/1/fist-2014-rjose-chapter6.pdf |
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ump-85672018-02-19T07:34:02Z http://umpir.ump.edu.my/id/eprint/8567/ Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites Rajan, Jose Nair, V. M. Rajul, K. Wariar, P. R. S. Q Science (General) Combustion of citrate complex has been a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ratio unity such that combustion energy is a maximum. This chapter demonstrates by employing quantum chemical calculations that the amount of citric acid could be reduced to nearly half if prepared for appreciable amounts. Transition metal oxides belong to quaternary double perovskites, with general formula Ba2 RESbO6 (RE=Rare-earth), have been synthesized as nanocrystals as examples to validate the calculations. Penerbit Universiti Malaysia Perlis Al-Douri, Yarub 2014-02 Book Section PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8567/1/fist-2014-rjose-chapter6.pdf Rajan, Jose and Nair, V. M. and Rajul, K. and Wariar, P. R. S. (2014) Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites. In: Nanostructured Oxides and Materials. Penerbit Universiti Malaysia Perlis, Perlis, Malaysia, pp. 155-184. ISBN 978-967-5415-95-1 |
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Q Science (General) Rajan, Jose Nair, V. M. Rajul, K. Wariar, P. R. S. Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites |
description |
Combustion of citrate complex has been a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ratio unity such that combustion energy is a maximum. This chapter demonstrates by employing quantum chemical calculations that the amount of citric acid could be reduced to nearly half if prepared for appreciable amounts. Transition metal oxides belong to quaternary double perovskites, with general formula Ba2
RESbO6 (RE=Rare-earth), have been synthesized as nanocrystals as examples to validate the calculations.
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author2 |
Al-Douri, Yarub |
author_facet |
Al-Douri, Yarub Rajan, Jose Nair, V. M. Rajul, K. Wariar, P. R. S. |
format |
Book Section |
author |
Rajan, Jose Nair, V. M. Rajul, K. Wariar, P. R. S. |
author_sort |
Rajan, Jose |
title |
Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites |
title_short |
Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites |
title_full |
Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites |
title_fullStr |
Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites |
title_full_unstemmed |
Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites |
title_sort |
optimized combustion synthesis and characterization of nanostructured ba2resbo6 perovskites |
publisher |
Penerbit Universiti Malaysia Perlis |
publishDate |
2014 |
url |
http://umpir.ump.edu.my/id/eprint/8567/ http://umpir.ump.edu.my/id/eprint/8567/1/fist-2014-rjose-chapter6.pdf |
first_indexed |
2023-09-18T22:06:17Z |
last_indexed |
2023-09-18T22:06:17Z |
_version_ |
1777414729770205184 |