Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites

Combustion of citrate complex has been a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equival...

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Main Authors: Rajan, Jose, Nair, V. M., Rajul, K., Wariar, P. R. S.
Other Authors: Al-Douri, Yarub
Format: Book Section
Language:English
Published: Penerbit Universiti Malaysia Perlis 2014
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8567/
http://umpir.ump.edu.my/id/eprint/8567/1/fist-2014-rjose-chapter6.pdf
id ump-8567
recordtype eprints
spelling ump-85672018-02-19T07:34:02Z http://umpir.ump.edu.my/id/eprint/8567/ Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites Rajan, Jose Nair, V. M. Rajul, K. Wariar, P. R. S. Q Science (General) Combustion of citrate complex has been a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ratio unity such that combustion energy is a maximum. This chapter demonstrates by employing quantum chemical calculations that the amount of citric acid could be reduced to nearly half if prepared for appreciable amounts. Transition metal oxides belong to quaternary double perovskites, with general formula Ba2 RESbO6 (RE=Rare-earth), have been synthesized as nanocrystals as examples to validate the calculations. Penerbit Universiti Malaysia Perlis Al-Douri, Yarub 2014-02 Book Section PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8567/1/fist-2014-rjose-chapter6.pdf Rajan, Jose and Nair, V. M. and Rajul, K. and Wariar, P. R. S. (2014) Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites. In: Nanostructured Oxides and Materials. Penerbit Universiti Malaysia Perlis, Perlis, Malaysia, pp. 155-184. ISBN 978-967-5415-95-1
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Rajan, Jose
Nair, V. M.
Rajul, K.
Wariar, P. R. S.
Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
description Combustion of citrate complex has been a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ratio unity such that combustion energy is a maximum. This chapter demonstrates by employing quantum chemical calculations that the amount of citric acid could be reduced to nearly half if prepared for appreciable amounts. Transition metal oxides belong to quaternary double perovskites, with general formula Ba2 RESbO6 (RE=Rare-earth), have been synthesized as nanocrystals as examples to validate the calculations.
author2 Al-Douri, Yarub
author_facet Al-Douri, Yarub
Rajan, Jose
Nair, V. M.
Rajul, K.
Wariar, P. R. S.
format Book Section
author Rajan, Jose
Nair, V. M.
Rajul, K.
Wariar, P. R. S.
author_sort Rajan, Jose
title Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
title_short Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
title_full Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
title_fullStr Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
title_full_unstemmed Optimized Combustion Synthesis and Characterization of Nanostructured Ba2RESbO6 Perovskites
title_sort optimized combustion synthesis and characterization of nanostructured ba2resbo6 perovskites
publisher Penerbit Universiti Malaysia Perlis
publishDate 2014
url http://umpir.ump.edu.my/id/eprint/8567/
http://umpir.ump.edu.my/id/eprint/8567/1/fist-2014-rjose-chapter6.pdf
first_indexed 2023-09-18T22:06:17Z
last_indexed 2023-09-18T22:06:17Z
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