Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices

The photoisomerization effect of new bent-shaped azo dyes in the presence of aliphatic and aromatic spacers is reported for the first time. The synthesized compounds with n-hexane and benzene as central moieties were characterized by different spectral analytical techniques such as 1 H-NMR, 13C-NMR,...

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Main Authors:	Hegde, Gurumurthy, Yuvaraj, A. R., Gan, Siew Mei, Ajaykumar, D. Kulkarni, M. M., Yusoff
Format:	Article
Published:	Royal Society of Chemistry 2014
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/8097/ http://umpir.ump.edu.my/id/eprint/8097/ http://umpir.ump.edu.my/id/eprint/8097/

id	ump-8097
recordtype	eprints
spelling	ump-80972018-01-18T01:27:28Z http://umpir.ump.edu.my/id/eprint/8097/ Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices Hegde, Gurumurthy Yuvaraj, A. R. Gan, Siew Mei Ajaykumar, D. Kulkarni M. M., Yusoff Q Science (General) The photoisomerization effect of new bent-shaped azo dyes in the presence of aliphatic and aromatic spacers is reported for the first time. The synthesized compounds with n-hexane and benzene as central moieties were characterized by different spectral analytical techniques such as 1 H-NMR, 13C-NMR, FTIR and UV-Vis. They revealed the photoisomerization effect in solution and on the solid cells as well. In solution, the E–Z and Z–E isomerization occurred in around 17–18 seconds and 7–13 hours, respectively. The dramatic variation in back relaxation is speculated to take place due to the nature of the spacers involved in the system. The synthesized materials are expected to be more useful in optical storage devices. Royal Society of Chemistry 2014 Article PeerReviewed Hegde, Gurumurthy and Yuvaraj, A. R. and Gan, Siew Mei and Ajaykumar, D. Kulkarni and M. M., Yusoff (2014) Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices. RSC Advances, 4 (92). pp. 50811-50818. ISSN 2046-2069 http://dx.doi.org/10.1039/c4ra08219b DOI: 10.1039/c4ra08219b
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
topic	Q Science (General)
spellingShingle	Q Science (General) Hegde, Gurumurthy Yuvaraj, A. R. Gan, Siew Mei Ajaykumar, D. Kulkarni M. M., Yusoff Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices
description	The photoisomerization effect of new bent-shaped azo dyes in the presence of aliphatic and aromatic spacers is reported for the first time. The synthesized compounds with n-hexane and benzene as central moieties were characterized by different spectral analytical techniques such as 1 H-NMR, 13C-NMR, FTIR and UV-Vis. They revealed the photoisomerization effect in solution and on the solid cells as well. In solution, the E–Z and Z–E isomerization occurred in around 17–18 seconds and 7–13 hours, respectively. The dramatic variation in back relaxation is speculated to take place due to the nature of the spacers involved in the system. The synthesized materials are expected to be more useful in optical storage devices.
format	Article
author	Hegde, Gurumurthy Yuvaraj, A. R. Gan, Siew Mei Ajaykumar, D. Kulkarni M. M., Yusoff
author_facet	Hegde, Gurumurthy Yuvaraj, A. R. Gan, Siew Mei Ajaykumar, D. Kulkarni M. M., Yusoff
author_sort	Hegde, Gurumurthy
title	Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices
title_short	Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices
title_full	Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices
title_fullStr	Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices
title_full_unstemmed	Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices
title_sort	aliphatic/aromatic spacers based azo dye dimers: synthesis and application for optical storage devices
publisher	Royal Society of Chemistry
publishDate	2014
url	http://umpir.ump.edu.my/id/eprint/8097/ http://umpir.ump.edu.my/id/eprint/8097/ http://umpir.ump.edu.my/id/eprint/8097/
first_indexed	2023-09-18T22:05:23Z
last_indexed	2023-09-18T22:05:23Z
_version_	1777414673532977152

Aliphatic/aromatic Spacers Based Azo Dye Dimers: Synthesis and Application for Optical Storage Devices

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