Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction

ZSM-5 zeolite is one type of heterogeneous catalyst which obtained in the solid form. There are several advantages of heterogeneous catalyst in the chemical reaction compared to homogeneous such cost reduction, environmental friendly and easy to separate. In this study, ZSM-5 zeolite was synthesiz...

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Main Author:	Nik Rohani, Nik Mustapa
Format:	Undergraduates Project Papers
Language:	English
Published:	2012
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/7816/ http://umpir.ump.edu.my/id/eprint/7816/ http://umpir.ump.edu.my/id/eprint/7816/1/NIK_ROHANI_BT._NIK_MUSTAPA.PDF

id	ump-7816
recordtype	eprints
spelling	ump-78162018-07-27T01:53:15Z http://umpir.ump.edu.my/id/eprint/7816/ Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction Nik Rohani, Nik Mustapa TP Chemical technology ZSM-5 zeolite is one type of heterogeneous catalyst which obtained in the solid form. There are several advantages of heterogeneous catalyst in the chemical reaction compared to homogeneous such cost reduction, environmental friendly and easy to separate. In this study, ZSM-5 zeolite was synthesized using hydrothermal method utilising rice husk ash (RHA) which is agriculture waste of silica source. Then, the prepared ZSM-5 zeolite with different ratios of Si0 2/Al2 0 3 was characterized by means of Fourier Transformed-Infrared Spectroscopy (FT-IR), Surface Area Analyzer (BET), X-Ray Diffraction (XRD) and Thermogravimetric Analysis (TGA). The catalytic activity of ZSM-5 zeolite was tested by the reaction of acetophenone and benzaldehyde to chalcone at 150 °C and 6 hours. The conversion of the reaction was evaluated using Gas Chromatography-Flame Ion Detector (GC-FID). The conversion to chalcone by HZSM-5(30) give yield up to 82.44 %, Na-ZSM-5(60) give 82.72 %, H-ZSM-5(60) give 82.86 % and Na-ZSM-5(30) give the highest yield of 91.95 %. Keywords: heterogeneous catalyst, ZSM-5, zeolite, chalcone, acidic properties 2012 Undergraduates Project Papers NonPeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/7816/1/NIK_ROHANI_BT._NIK_MUSTAPA.PDF Nik Rohani, Nik Mustapa (2012) Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction. Faculty of Industrial Sciences & Technology, Universiti Malaysia Pahang. http://iportal.ump.edu.my/lib/item?id=chamo:76329&theme=UMP2
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Nik Rohani, Nik Mustapa Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
description	ZSM-5 zeolite is one type of heterogeneous catalyst which obtained in the solid form. There are several advantages of heterogeneous catalyst in the chemical reaction compared to homogeneous such cost reduction, environmental friendly and easy to separate. In this study, ZSM-5 zeolite was synthesized using hydrothermal method utilising rice husk ash (RHA) which is agriculture waste of silica source. Then, the prepared ZSM-5 zeolite with different ratios of Si0 2/Al2 0 3 was characterized by means of Fourier Transformed-Infrared Spectroscopy (FT-IR), Surface Area Analyzer (BET), X-Ray Diffraction (XRD) and Thermogravimetric Analysis (TGA). The catalytic activity of ZSM-5 zeolite was tested by the reaction of acetophenone and benzaldehyde to chalcone at 150 °C and 6 hours. The conversion of the reaction was evaluated using Gas Chromatography-Flame Ion Detector (GC-FID). The conversion to chalcone by HZSM-5(30) give yield up to 82.44 %, Na-ZSM-5(60) give 82.72 %, H-ZSM-5(60) give 82.86 % and Na-ZSM-5(30) give the highest yield of 91.95 %. Keywords: heterogeneous catalyst, ZSM-5, zeolite, chalcone, acidic properties
format	Undergraduates Project Papers
author	Nik Rohani, Nik Mustapa
author_facet	Nik Rohani, Nik Mustapa
author_sort	Nik Rohani, Nik Mustapa
title	Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
title_short	Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
title_full	Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
title_fullStr	Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
title_full_unstemmed	Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction
title_sort	synthesis and characterization of zsm-5 zeolite as catalyst in claisen-schmidt condensation reaction
publishDate	2012
url	http://umpir.ump.edu.my/id/eprint/7816/ http://umpir.ump.edu.my/id/eprint/7816/ http://umpir.ump.edu.my/id/eprint/7816/1/NIK_ROHANI_BT._NIK_MUSTAPA.PDF
first_indexed	2023-09-18T22:04:50Z
last_indexed	2023-09-18T22:04:50Z
_version_	1777414638706622464

Synthesis and characterization of ZSM-5 zeolite as catalyst in Claisen-Schmidt condensation reaction

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