Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells

Various one-dimensional nano-morphologies, such as multiporous nanofibers (MPNFs), porous nanofibers (PNFs), and nanowires (NWs) of SnO2, are synthesized using electrospinning technique by controlling the tin precursor concentration. The MPNFs have [similar]8-fold higher surface area compared to the...

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Main Authors: Fakharuddin, Azhar, Wali, Qamar, Irfan, Ahmed, Mohd Hasbi, Ab. Rahim, Jamil, Ismail, Rajan, Jose
Format: Article
Published: Royal Society of Chemistry 2014
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Online Access:http://umpir.ump.edu.my/id/eprint/7527/
http://umpir.ump.edu.my/id/eprint/7527/
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spelling ump-75272018-11-22T08:12:01Z http://umpir.ump.edu.my/id/eprint/7527/ Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells Fakharuddin, Azhar Wali, Qamar Irfan, Ahmed Mohd Hasbi, Ab. Rahim Jamil, Ismail Rajan, Jose QD Chemistry Various one-dimensional nano-morphologies, such as multiporous nanofibers (MPNFs), porous nanofibers (PNFs), and nanowires (NWs) of SnO2, are synthesized using electrospinning technique by controlling the tin precursor concentration. The MPNFs have [similar]8-fold higher surface area compared to the other morphologies. Dye-sensitized solar cells (DSCs) were fabricated using these nanostructures as photoanodes and their performance was compared. The MPNFs surpass the performance of PNFs and NWs as well as conventional TiO2 paste. Record photoconversion efficiency (PCE) of [similar]7.4% was realized in MPNFs DSCs, which was twice to that achieved using PNFs ([similar]3.5%). Furthermore, the MPNFs showed over >80% incident photon to current conversion efficiency (22% higher than that achieved by spherical P25 TiO2 particles) and also demonstrated [similar]3 times longer electron lifetime and electron diffusion length. Owing to the possibility to produce large quantities using electrospinning technique, huge commercial potential of SnO2 nanostructures, and promising results achieved herein, the MPNFs are expected soon to be utilized in commercial devices. Royal Society of Chemistry 2014 Article PeerReviewed Fakharuddin, Azhar and Wali, Qamar and Irfan, Ahmed and Mohd Hasbi, Ab. Rahim and Jamil, Ismail and Rajan, Jose (2014) Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells. Journal of Materials Chemistry A, 2 (41). pp. 17427-17434. ISSN 2050-7488 (print); 2050-7496 (online) http://dx.doi.org/10.1039/C4TA03056G DOI: 10.1039/C4TA03056G
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
topic QD Chemistry
spellingShingle QD Chemistry
Fakharuddin, Azhar
Wali, Qamar
Irfan, Ahmed
Mohd Hasbi, Ab. Rahim
Jamil, Ismail
Rajan, Jose
Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells
description Various one-dimensional nano-morphologies, such as multiporous nanofibers (MPNFs), porous nanofibers (PNFs), and nanowires (NWs) of SnO2, are synthesized using electrospinning technique by controlling the tin precursor concentration. The MPNFs have [similar]8-fold higher surface area compared to the other morphologies. Dye-sensitized solar cells (DSCs) were fabricated using these nanostructures as photoanodes and their performance was compared. The MPNFs surpass the performance of PNFs and NWs as well as conventional TiO2 paste. Record photoconversion efficiency (PCE) of [similar]7.4% was realized in MPNFs DSCs, which was twice to that achieved using PNFs ([similar]3.5%). Furthermore, the MPNFs showed over >80% incident photon to current conversion efficiency (22% higher than that achieved by spherical P25 TiO2 particles) and also demonstrated [similar]3 times longer electron lifetime and electron diffusion length. Owing to the possibility to produce large quantities using electrospinning technique, huge commercial potential of SnO2 nanostructures, and promising results achieved herein, the MPNFs are expected soon to be utilized in commercial devices.
format Article
author Fakharuddin, Azhar
Wali, Qamar
Irfan, Ahmed
Mohd Hasbi, Ab. Rahim
Jamil, Ismail
Rajan, Jose
author_facet Fakharuddin, Azhar
Wali, Qamar
Irfan, Ahmed
Mohd Hasbi, Ab. Rahim
Jamil, Ismail
Rajan, Jose
author_sort Fakharuddin, Azhar
title Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells
title_short Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells
title_full Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells
title_fullStr Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells
title_full_unstemmed Multiporous Nanofibers of SnO2 by Electrospinning for High Efficiency Dye-Sensitized Solar Cells
title_sort multiporous nanofibers of sno2 by electrospinning for high efficiency dye-sensitized solar cells
publisher Royal Society of Chemistry
publishDate 2014
url http://umpir.ump.edu.my/id/eprint/7527/
http://umpir.ump.edu.my/id/eprint/7527/
http://umpir.ump.edu.my/id/eprint/7527/
first_indexed 2023-09-18T22:04:12Z
last_indexed 2023-09-18T22:04:12Z
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