Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System

This paper describes the experimental characterization of a 25 cm2 laboratory scale vanadium redox flow battery (V-RFB). The unit cell performance with respect to voltage, coulombic and energy efficiencies under different performance parameters (current densities, operating temperatures, flow rates,...

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Main Authors: Mohd Rusllim, Mohamed, P. K., Leung, M. H., Sulaiman
Format: Article
Published: Elsevier 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/7495/
http://umpir.ump.edu.my/id/eprint/7495/
http://umpir.ump.edu.my/id/eprint/7495/
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spelling ump-74952018-03-07T04:24:28Z http://umpir.ump.edu.my/id/eprint/7495/ Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System Mohd Rusllim, Mohamed P. K., Leung M. H., Sulaiman TK Electrical engineering. Electronics Nuclear engineering QD Chemistry This paper describes the experimental characterization of a 25 cm2 laboratory scale vanadium redox flow battery (V-RFB). The unit cell performance with respect to voltage, coulombic and energy efficiencies under different performance parameters (current densities, operating temperatures, flow rates, electrolyte concentrations and material properties of 5 cm × 5 cm electrodes) are presented. The cell exhibits different characteristics under different operating parameters; the highest energy efficiency is recorded at c.a. 82%, operating at 308 K, 60 mA cm−2 and 3 cm3 s−1 volumetric flow rate for 250 cm3 electrolytes (each reservoir) of 1.6 mol dm−3V(III)/V(IV) in 4 mol dm−3 H2SO4. Formation charge of the mixture of vanadium species into single electro-active species at positive and negative electrodes are presented. Estimated time for the electro-active species to complete the formation charge using electrochemical calculation of Faraday’s constant are presented; a discrepancy of 4.5% is found between the theoretical and experimental data using current density of 80 mA cm−2. Elsevier 2015 Article PeerReviewed Mohd Rusllim, Mohamed and P. K., Leung and M. H., Sulaiman (2015) Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System. Applied Energy, 137. pp. 402-412. ISSN 0306-2619 http://dx.doi.org/10.1016/j.apenergy.2014.10.042 DOI. 10.1016/j.apenergy.2014.10.042
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
topic TK Electrical engineering. Electronics Nuclear engineering
QD Chemistry
spellingShingle TK Electrical engineering. Electronics Nuclear engineering
QD Chemistry
Mohd Rusllim, Mohamed
P. K., Leung
M. H., Sulaiman
Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System
description This paper describes the experimental characterization of a 25 cm2 laboratory scale vanadium redox flow battery (V-RFB). The unit cell performance with respect to voltage, coulombic and energy efficiencies under different performance parameters (current densities, operating temperatures, flow rates, electrolyte concentrations and material properties of 5 cm × 5 cm electrodes) are presented. The cell exhibits different characteristics under different operating parameters; the highest energy efficiency is recorded at c.a. 82%, operating at 308 K, 60 mA cm−2 and 3 cm3 s−1 volumetric flow rate for 250 cm3 electrolytes (each reservoir) of 1.6 mol dm−3V(III)/V(IV) in 4 mol dm−3 H2SO4. Formation charge of the mixture of vanadium species into single electro-active species at positive and negative electrodes are presented. Estimated time for the electro-active species to complete the formation charge using electrochemical calculation of Faraday’s constant are presented; a discrepancy of 4.5% is found between the theoretical and experimental data using current density of 80 mA cm−2.
format Article
author Mohd Rusllim, Mohamed
P. K., Leung
M. H., Sulaiman
author_facet Mohd Rusllim, Mohamed
P. K., Leung
M. H., Sulaiman
author_sort Mohd Rusllim, Mohamed
title Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System
title_short Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System
title_full Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System
title_fullStr Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System
title_full_unstemmed Performance Characterization of a Vanadium Redox Flow Battery at Different Operating Parameters under a Standardized Test-Bed System
title_sort performance characterization of a vanadium redox flow battery at different operating parameters under a standardized test-bed system
publisher Elsevier
publishDate 2015
url http://umpir.ump.edu.my/id/eprint/7495/
http://umpir.ump.edu.my/id/eprint/7495/
http://umpir.ump.edu.my/id/eprint/7495/
first_indexed 2023-09-18T22:04:09Z
last_indexed 2023-09-18T22:04:09Z
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