Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio

Xylose is an abundant raw material coexists with other sugars that can be turned into useful products, such as ethanol, xylitol and 2, 3-butanediol by microorganism such as yeasts, bacteria, and mycelial fungi. However, more than 80 % of the production cost of these products comes solely from the pr...

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Main Authors:	K. H., Mah, Wan Mohd Hafizuddin, Wan Yussof, Mazrul Nizam, Abu Seman, N., Zainol
Format:	Article
Language:	English
Published:	Penerbit Universiti Teknologi Malaysia 2014
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/6404/ http://umpir.ump.edu.my/id/eprint/6404/ http://umpir.ump.edu.my/id/eprint/6404/ http://umpir.ump.edu.my/id/eprint/6404/1/Separation_of_Xylose_From_Glucose_Using_Thin_Film_Composite_%28TFC%29_Nanofiltration_Membrane-_Effect_of_Pressure%2C_Total_Sugar_Concentration_and_Xylose%2CGlucose_Ratio.pdf

id	ump-6404
recordtype	eprints
spelling	ump-64042018-01-15T02:12:58Z http://umpir.ump.edu.my/id/eprint/6404/ Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio K. H., Mah Wan Mohd Hafizuddin, Wan Yussof Mazrul Nizam, Abu Seman N., Zainol TP Chemical technology Xylose is an abundant raw material coexists with other sugars that can be turned into useful products, such as ethanol, xylitol and 2, 3-butanediol by microorganism such as yeasts, bacteria, and mycelial fungi. However, more than 80 % of the production cost of these products comes solely from the production of xylose. Presently, the separation of xylose from hemicellulose hydrolysate relies on chromatographic separation alone. The use of nanofiltration membrane may offer alternative in recovering xylose due to the differences in size compared to other sugars. The aim of this study is to evaluate the ability of membrane developed by interfacial polymerization reaction between triethanolamine (TEOA) (6 % w/v) and tri-mesoyl chloride (TMC) (0.15 % w/v) as monomers on polyethersulfone (PES) microporous substrate to separate xylose from glucose. In this study, factors affecting the process, namely pressure, concentration of total sugars in solution, and composition of monosaccharides in total sugar, were investigated using two-level factorial analysis. The experiment was performed using Amicon Milipore stirred cell (Model 8200) with constant stirring speed at 300 rpm and temperature at ambient. The glucose and xylose concentration was quantified using high performance liquid chromatography (HPLC). It is found that the developed nanofiltration membrane has the ability to separate xylose from glucose.The analysis of the experimental response revealed that the total sugar concentration and composition ratio of xylose: glucose had significant interactive effect on xylose separation factor. Overall from the present study, it can be concluded that nanofiltration has high potential to replace currently in use chromatographic method in xylose separation. Penerbit Universiti Teknologi Malaysia 2014 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6404/1/Separation_of_Xylose_From_Glucose_Using_Thin_Film_Composite_%28TFC%29_Nanofiltration_Membrane-_Effect_of_Pressure%2C_Total_Sugar_Concentration_and_Xylose%2CGlucose_Ratio.pdf K. H., Mah and Wan Mohd Hafizuddin, Wan Yussof and Mazrul Nizam, Abu Seman and N., Zainol (2014) Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio. Jurnal Teknologi (Sciences and Engineering), 70 (1). pp. 93-98. ISSN 0127-9696 (print); 2180-3722 (online) http://dx.doi.org/10.11113/jt.v70.2746 DOI: 10.11113/jt.v70.2746
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology K. H., Mah Wan Mohd Hafizuddin, Wan Yussof Mazrul Nizam, Abu Seman N., Zainol Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio
description	Xylose is an abundant raw material coexists with other sugars that can be turned into useful products, such as ethanol, xylitol and 2, 3-butanediol by microorganism such as yeasts, bacteria, and mycelial fungi. However, more than 80 % of the production cost of these products comes solely from the production of xylose. Presently, the separation of xylose from hemicellulose hydrolysate relies on chromatographic separation alone. The use of nanofiltration membrane may offer alternative in recovering xylose due to the differences in size compared to other sugars. The aim of this study is to evaluate the ability of membrane developed by interfacial polymerization reaction between triethanolamine (TEOA) (6 % w/v) and tri-mesoyl chloride (TMC) (0.15 % w/v) as monomers on polyethersulfone (PES) microporous substrate to separate xylose from glucose. In this study, factors affecting the process, namely pressure, concentration of total sugars in solution, and composition of monosaccharides in total sugar, were investigated using two-level factorial analysis. The experiment was performed using Amicon Milipore stirred cell (Model 8200) with constant stirring speed at 300 rpm and temperature at ambient. The glucose and xylose concentration was quantified using high performance liquid chromatography (HPLC). It is found that the developed nanofiltration membrane has the ability to separate xylose from glucose.The analysis of the experimental response revealed that the total sugar concentration and composition ratio of xylose: glucose had significant interactive effect on xylose separation factor. Overall from the present study, it can be concluded that nanofiltration has high potential to replace currently in use chromatographic method in xylose separation.
format	Article
author	K. H., Mah Wan Mohd Hafizuddin, Wan Yussof Mazrul Nizam, Abu Seman N., Zainol
author_facet	K. H., Mah Wan Mohd Hafizuddin, Wan Yussof Mazrul Nizam, Abu Seman N., Zainol
author_sort	K. H., Mah
title	Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio
title_short	Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio
title_full	Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio
title_fullStr	Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio
title_full_unstemmed	Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio
title_sort	separation of xylose from glucose using thin film composite (tfc) nanofiltration membrane: effect of pressure, total sugar concentration and xylose/glucose ratio
publisher	Penerbit Universiti Teknologi Malaysia
publishDate	2014
url	http://umpir.ump.edu.my/id/eprint/6404/ http://umpir.ump.edu.my/id/eprint/6404/ http://umpir.ump.edu.my/id/eprint/6404/ http://umpir.ump.edu.my/id/eprint/6404/1/Separation_of_Xylose_From_Glucose_Using_Thin_Film_Composite_%28TFC%29_Nanofiltration_Membrane-_Effect_of_Pressure%2C_Total_Sugar_Concentration_and_Xylose%2CGlucose_Ratio.pdf
first_indexed	2023-09-18T22:02:08Z
last_indexed	2023-09-18T22:02:08Z
_version_	1777414468527980544

Separation of Xylose From Glucose Using Thin Film Composite (TFC) Nanofiltration Membrane: Effect of Pressure, Total Sugar Concentration and Xylose/Glucose Ratio

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