Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures

Combustion of citrate complex is a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ra...

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Main Authors:	Nair, V. M., Rajan, Jose, Raju, K., Wariar, P. R. S.
Format:	Article
Language:	English
Published:	Elsevier Ltd 2013
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/6297/ http://umpir.ump.edu.my/id/eprint/6297/ http://umpir.ump.edu.my/id/eprint/6297/ http://umpir.ump.edu.my/id/eprint/6297/1/Optimization%20Of%20Citrate%20Complex%20Combustion%20For%20Synthesis%20Of%20Transition%20Metal%20Oxide%20Nanostructures.pdf

id	ump-6297
recordtype	eprints
spelling	ump-62972018-02-19T07:10:13Z http://umpir.ump.edu.my/id/eprint/6297/ Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures Nair, V. M. Rajan, Jose Raju, K. Wariar, P. R. S. Q Science (General) Combustion of citrate complex is a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ratio unity such that combustion energy is a maximum. This paper demonstrates by employing quantum chemical calculations that the amount of citric acid could be reduced to nearly two-third if prepared for appreciable amounts. Transition metal oxides belong to quaternary double perovskite has been synthesized as nanocrystals as examples to validate the calculations. Elsevier Ltd 2013 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6297/1/Optimization%20Of%20Citrate%20Complex%20Combustion%20For%20Synthesis%20Of%20Transition%20Metal%20Oxide%20Nanostructures.pdf Nair, V. M. and Rajan, Jose and Raju, K. and Wariar, P. R. S. (2013) Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures. Journal of Alloys and Compounds, 552. pp. 180-185. ISSN 0925-8388 (print), 1873-4669 (online) http://dx.doi.org/10.1016/j.jallcom.2012.10.030 DOI: 10.1016/j.jallcom.2012.10.030
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Nair, V. M. Rajan, Jose Raju, K. Wariar, P. R. S. Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures
description	Combustion of citrate complex is a popular choice to synthesize nanocrystals of transition metal oxides in a single-step process. The amount of citric acid used for combustion is conventionally calculated based on the total valence of the oxidizing and reducing agents while keeping the equivalent ratio unity such that combustion energy is a maximum. This paper demonstrates by employing quantum chemical calculations that the amount of citric acid could be reduced to nearly two-third if prepared for appreciable amounts. Transition metal oxides belong to quaternary double perovskite has been synthesized as nanocrystals as examples to validate the calculations.
format	Article
author	Nair, V. M. Rajan, Jose Raju, K. Wariar, P. R. S.
author_facet	Nair, V. M. Rajan, Jose Raju, K. Wariar, P. R. S.
author_sort	Nair, V. M.
title	Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures
title_short	Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures
title_full	Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures
title_fullStr	Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures
title_full_unstemmed	Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures
title_sort	optimization of citrate complex combustion for synthesis of transition metal oxide nanostructures
publisher	Elsevier Ltd
publishDate	2013
url	http://umpir.ump.edu.my/id/eprint/6297/ http://umpir.ump.edu.my/id/eprint/6297/ http://umpir.ump.edu.my/id/eprint/6297/ http://umpir.ump.edu.my/id/eprint/6297/1/Optimization%20Of%20Citrate%20Complex%20Combustion%20For%20Synthesis%20Of%20Transition%20Metal%20Oxide%20Nanostructures.pdf
first_indexed	2023-09-18T22:01:56Z
last_indexed	2023-09-18T22:01:56Z
_version_	1777414456328847360

Optimization Of Citrate Complex Combustion For Synthesis Of Transition Metal Oxide Nanostructures

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