Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst

Alumina-supported bimetallic cobalt-nickel catalyst has been prepared and employed in a fixed-bed reactor for the direct production of synthesis gas from glycerol steam reforming. Physicochemical properties of the 5Co-10Ni/85Al2O3 catalyst were determined from N2-physisorption, H2-chemisorption, CO2...

Full description

Bibliographic Details
Main Authors:	Cheng, C. K., Lim, Rwi Hau, Anabil, Ubil, Chin, S. Y., Jolius, Gimbun
Format:	Article
Language:	English
Published:	Scientific Research Publishing 2012
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/6280/ http://umpir.ump.edu.my/id/eprint/6280/ http://umpir.ump.edu.my/id/eprint/6280/ http://umpir.ump.edu.my/id/eprint/6280/1/Hydrogen_as_Carbon_Gasifying_Agent_During_Glycerol_Steam_Reforming_over_Bimetallic_Co-Ni_Catalyst.pdf

id	ump-6280
recordtype	eprints
spelling	ump-62802018-01-11T03:12:30Z http://umpir.ump.edu.my/id/eprint/6280/ Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst Cheng, C. K. Lim, Rwi Hau Anabil, Ubil Chin, S. Y. Jolius, Gimbun TP Chemical technology Alumina-supported bimetallic cobalt-nickel catalyst has been prepared and employed in a fixed-bed reactor for the direct production of synthesis gas from glycerol steam reforming. Physicochemical properties of the 5Co-10Ni/85Al2O3 catalyst were determined from N2-physisorption, H2-chemisorption, CO2 and NH3-temperature-programmed desorption measurements as well as X-ray diffraction analysis. Both weak and strong acid sites are present on the catalyst surface. The acidic:basic ratio is about 7. Carbon deposition was evident at 923 K; addition of H2 however has managed to reduce the carbon deposition. Significantly, this has resulted in the increment of CH4 formation rate, consistent with the increased carbon gasification and methanation. Carbon deposition was almost non-existent, particularly at 1023 K. In addition, the inclusion of hydrogen also has contributed to the decrease of CO2 and increase of CO formation rates. This was attributed to the reverse water-gas-shift reaction. Overall, both the CO2:CO and CO2:CH4 ratios decrease with the hydrogen partial pressure. Scientific Research Publishing 2012 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/6280/1/Hydrogen_as_Carbon_Gasifying_Agent_During_Glycerol_Steam_Reforming_over_Bimetallic_Co-Ni_Catalyst.pdf Cheng, C. K. and Lim, Rwi Hau and Anabil, Ubil and Chin, S. Y. and Jolius, Gimbun (2012) Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst. Advances in Materials Physics and Chemistry, 2 (4). pp. 165-168. ISSN 2162-531X (print); 2162-5328 (online) http://dx.doi.org/10.4236/ampc.2012.24B043 DOI: 10.4236/ampc.2012.24B043
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Cheng, C. K. Lim, Rwi Hau Anabil, Ubil Chin, S. Y. Jolius, Gimbun Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst
description	Alumina-supported bimetallic cobalt-nickel catalyst has been prepared and employed in a fixed-bed reactor for the direct production of synthesis gas from glycerol steam reforming. Physicochemical properties of the 5Co-10Ni/85Al2O3 catalyst were determined from N2-physisorption, H2-chemisorption, CO2 and NH3-temperature-programmed desorption measurements as well as X-ray diffraction analysis. Both weak and strong acid sites are present on the catalyst surface. The acidic:basic ratio is about 7. Carbon deposition was evident at 923 K; addition of H2 however has managed to reduce the carbon deposition. Significantly, this has resulted in the increment of CH4 formation rate, consistent with the increased carbon gasification and methanation. Carbon deposition was almost non-existent, particularly at 1023 K. In addition, the inclusion of hydrogen also has contributed to the decrease of CO2 and increase of CO formation rates. This was attributed to the reverse water-gas-shift reaction. Overall, both the CO2:CO and CO2:CH4 ratios decrease with the hydrogen partial pressure.
format	Article
author	Cheng, C. K. Lim, Rwi Hau Anabil, Ubil Chin, S. Y. Jolius, Gimbun
author_facet	Cheng, C. K. Lim, Rwi Hau Anabil, Ubil Chin, S. Y. Jolius, Gimbun
author_sort	Cheng, C. K.
title	Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst
title_short	Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst
title_full	Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst
title_fullStr	Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst
title_full_unstemmed	Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst
title_sort	hydrogen as carbon gasifying agent during glycerol steam reforming over bimetallic co-ni catalyst
publisher	Scientific Research Publishing
publishDate	2012
url	http://umpir.ump.edu.my/id/eprint/6280/ http://umpir.ump.edu.my/id/eprint/6280/ http://umpir.ump.edu.my/id/eprint/6280/ http://umpir.ump.edu.my/id/eprint/6280/1/Hydrogen_as_Carbon_Gasifying_Agent_During_Glycerol_Steam_Reforming_over_Bimetallic_Co-Ni_Catalyst.pdf
first_indexed	2023-09-18T22:01:54Z
last_indexed	2023-09-18T22:01:54Z
_version_	1777414454145712128

Hydrogen as Carbon Gasifying Agent During Glycerol Steam Reforming over Bimetallic Co-Ni Catalyst

Similar Items