Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
Microporous polyvinylidene fluoride (PVDF) membranes with various concentrations of lithium chloride additives were prepared for CO2 stripping test. Physical membrane characterizations such as atomic force microscopy analysis, gas permeation, contact angle measurement and liquid entry pressure were...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2013
|
Subjects: | |
Online Access: | http://umpir.ump.edu.my/id/eprint/6241/ http://umpir.ump.edu.my/id/eprint/6241/ http://umpir.ump.edu.my/id/eprint/6241/ http://umpir.ump.edu.my/id/eprint/6241/1/fkksa-2013-rosmawati-Characterization_of_PVDF_abs_only.pdf |
id |
ump-6241 |
---|---|
recordtype |
eprints |
spelling |
ump-62412015-03-03T09:29:04Z http://umpir.ump.edu.my/id/eprint/6241/ Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis Rosmawati, Naim Khulbe, K.C. A. Fauzi, Ismail T., Matsuura TP Chemical technology Microporous polyvinylidene fluoride (PVDF) membranes with various concentrations of lithium chloride additives were prepared for CO2 stripping test. Physical membrane characterizations such as atomic force microscopy analysis, gas permeation, contact angle measurement and liquid entry pressure were also conducted. Correlations among the membrane properties, i.e. contact angle, gas permeation, mean pore size, nodule aggregates and surface roughness obtained from experimental analysis were discussed. The overall trend showed that increasing lithium chloride concentration has decreased the mean pore size, mean nodule aggregates and mean surface roughness of the membrane. On the contrary, the membrane liquid entry pressure has been significantly improved. It was found that the mean pore size determined by tapping mode atomic force microscopy (TM-AFM) is 2.3 to 2.7 times larger than that of obtained from gas permeation test. The decreases in nodule size, mean pore size and low surface roughness have contributed to the enhancement of CO2 stripping performance in membrane contactor system. Increasing LiCl concentration has increased the CO2 stripping flux and membrane mass transfer coefficient. However, the concentration of LiCl showed minimal effect on the liquid side mass transfer coefficient. Elsevier 2013 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6241/1/fkksa-2013-rosmawati-Characterization_of_PVDF_abs_only.pdf Rosmawati, Naim and Khulbe, K.C. and A. Fauzi, Ismail and T., Matsuura (2013) Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis. Separation and Purification Technology, 109. pp. 98-106. ISSN 1383-5866 http://dx.doi.org/10.1016/j.seppur.2013.02.036 DOI: 10.1016/j.seppur.2013.02.036 |
repository_type |
Digital Repository |
institution_category |
Local University |
institution |
Universiti Malaysia Pahang |
building |
UMP Institutional Repository |
collection |
Online Access |
language |
English |
topic |
TP Chemical technology |
spellingShingle |
TP Chemical technology Rosmawati, Naim Khulbe, K.C. A. Fauzi, Ismail T., Matsuura Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis |
description |
Microporous polyvinylidene fluoride (PVDF) membranes with various concentrations of lithium chloride additives were prepared for CO2 stripping test. Physical membrane characterizations such as atomic force microscopy analysis, gas permeation, contact angle measurement and liquid entry pressure were also conducted. Correlations among the membrane properties, i.e. contact angle, gas permeation, mean pore size, nodule aggregates and surface roughness obtained from experimental analysis were discussed. The overall trend showed that increasing lithium chloride concentration has decreased the mean pore size, mean nodule aggregates and mean surface roughness of the membrane. On the contrary, the membrane liquid entry pressure has been significantly improved. It was found that the mean pore size determined by tapping mode atomic force microscopy (TM-AFM) is 2.3 to 2.7 times larger than that of obtained from gas permeation test. The decreases in nodule size, mean pore size and low surface roughness have contributed to the enhancement of CO2 stripping performance in membrane contactor system. Increasing LiCl concentration has increased the CO2 stripping flux and membrane mass transfer coefficient. However, the concentration of LiCl showed minimal effect on the liquid side mass transfer coefficient. |
format |
Article |
author |
Rosmawati, Naim Khulbe, K.C. A. Fauzi, Ismail T., Matsuura |
author_facet |
Rosmawati, Naim Khulbe, K.C. A. Fauzi, Ismail T., Matsuura |
author_sort |
Rosmawati, Naim |
title |
Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis |
title_short |
Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis |
title_full |
Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis |
title_fullStr |
Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis |
title_full_unstemmed |
Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis |
title_sort |
characterization of pvdf hollow fiber membrane for co2 stripping by atomic force microscopy analysis |
publisher |
Elsevier |
publishDate |
2013 |
url |
http://umpir.ump.edu.my/id/eprint/6241/ http://umpir.ump.edu.my/id/eprint/6241/ http://umpir.ump.edu.my/id/eprint/6241/ http://umpir.ump.edu.my/id/eprint/6241/1/fkksa-2013-rosmawati-Characterization_of_PVDF_abs_only.pdf |
first_indexed |
2023-09-18T22:01:49Z |
last_indexed |
2023-09-18T22:01:49Z |
_version_ |
1777414449410342912 |