Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis

Microporous polyvinylidene fluoride (PVDF) membranes with various concentrations of lithium chloride additives were prepared for CO2 stripping test. Physical membrane characterizations such as atomic force microscopy analysis, gas permeation, contact angle measurement and liquid entry pressure were...

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Main Authors: Rosmawati, Naim, Khulbe, K.C., A. Fauzi, Ismail, T., Matsuura
Format: Article
Language:English
Published: Elsevier 2013
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spelling ump-62412015-03-03T09:29:04Z http://umpir.ump.edu.my/id/eprint/6241/ Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis Rosmawati, Naim Khulbe, K.C. A. Fauzi, Ismail T., Matsuura TP Chemical technology Microporous polyvinylidene fluoride (PVDF) membranes with various concentrations of lithium chloride additives were prepared for CO2 stripping test. Physical membrane characterizations such as atomic force microscopy analysis, gas permeation, contact angle measurement and liquid entry pressure were also conducted. Correlations among the membrane properties, i.e. contact angle, gas permeation, mean pore size, nodule aggregates and surface roughness obtained from experimental analysis were discussed. The overall trend showed that increasing lithium chloride concentration has decreased the mean pore size, mean nodule aggregates and mean surface roughness of the membrane. On the contrary, the membrane liquid entry pressure has been significantly improved. It was found that the mean pore size determined by tapping mode atomic force microscopy (TM-AFM) is 2.3 to 2.7 times larger than that of obtained from gas permeation test. The decreases in nodule size, mean pore size and low surface roughness have contributed to the enhancement of CO2 stripping performance in membrane contactor system. Increasing LiCl concentration has increased the CO2 stripping flux and membrane mass transfer coefficient. However, the concentration of LiCl showed minimal effect on the liquid side mass transfer coefficient. Elsevier 2013 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6241/1/fkksa-2013-rosmawati-Characterization_of_PVDF_abs_only.pdf Rosmawati, Naim and Khulbe, K.C. and A. Fauzi, Ismail and T., Matsuura (2013) Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis. Separation and Purification Technology, 109. pp. 98-106. ISSN 1383-5866 http://dx.doi.org/10.1016/j.seppur.2013.02.036 DOI: 10.1016/j.seppur.2013.02.036
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Rosmawati, Naim
Khulbe, K.C.
A. Fauzi, Ismail
T., Matsuura
Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
description Microporous polyvinylidene fluoride (PVDF) membranes with various concentrations of lithium chloride additives were prepared for CO2 stripping test. Physical membrane characterizations such as atomic force microscopy analysis, gas permeation, contact angle measurement and liquid entry pressure were also conducted. Correlations among the membrane properties, i.e. contact angle, gas permeation, mean pore size, nodule aggregates and surface roughness obtained from experimental analysis were discussed. The overall trend showed that increasing lithium chloride concentration has decreased the mean pore size, mean nodule aggregates and mean surface roughness of the membrane. On the contrary, the membrane liquid entry pressure has been significantly improved. It was found that the mean pore size determined by tapping mode atomic force microscopy (TM-AFM) is 2.3 to 2.7 times larger than that of obtained from gas permeation test. The decreases in nodule size, mean pore size and low surface roughness have contributed to the enhancement of CO2 stripping performance in membrane contactor system. Increasing LiCl concentration has increased the CO2 stripping flux and membrane mass transfer coefficient. However, the concentration of LiCl showed minimal effect on the liquid side mass transfer coefficient.
format Article
author Rosmawati, Naim
Khulbe, K.C.
A. Fauzi, Ismail
T., Matsuura
author_facet Rosmawati, Naim
Khulbe, K.C.
A. Fauzi, Ismail
T., Matsuura
author_sort Rosmawati, Naim
title Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
title_short Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
title_full Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
title_fullStr Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
title_full_unstemmed Characterization of PVDF Hollow Fiber Membrane for CO2 Stripping by Atomic Force Microscopy Analysis
title_sort characterization of pvdf hollow fiber membrane for co2 stripping by atomic force microscopy analysis
publisher Elsevier
publishDate 2013
url http://umpir.ump.edu.my/id/eprint/6241/
http://umpir.ump.edu.my/id/eprint/6241/
http://umpir.ump.edu.my/id/eprint/6241/
http://umpir.ump.edu.my/id/eprint/6241/1/fkksa-2013-rosmawati-Characterization_of_PVDF_abs_only.pdf
first_indexed 2023-09-18T22:01:49Z
last_indexed 2023-09-18T22:01:49Z
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