Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer

The main issue in the synthesis of molecular imprinted polymer nanoparticles is the identification and optimization of the key factors affecting the material structure and molecular recognition properties. This paper focus on the application of experimental design approach to synthesis bisphenol A m...

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Main Authors:	C. K. M., Faizal, Shareena, Mohd Sharif
Format:	Article
Language:	English
Published:	World Academy of Reseacrh and Publication 2012
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/5743/ http://umpir.ump.edu.my/id/eprint/5743/ http://umpir.ump.edu.my/id/eprint/5743/1/fkksa-2012-cheku-influence_of_factorial.pdf

id	ump-5743
recordtype	eprints
spelling	ump-57432018-01-12T02:44:46Z http://umpir.ump.edu.my/id/eprint/5743/ Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer C. K. M., Faizal Shareena, Mohd Sharif TP Chemical technology The main issue in the synthesis of molecular imprinted polymer nanoparticles is the identification and optimization of the key factors affecting the material structure and molecular recognition properties. This paper focus on the application of experimental design approach to synthesis bisphenol A molecular imprinted polymers (BPA-MIPs) aimed at the effect on polymerisation temperature, agitation rate, cross-linker to solvent ratio, and percentage of initiator; and determine the influence on hydrolysis breakage to remove template molecule, discussed by FTIR spectra results. The polymers were prepared under thermal suspension polymerization and their functional group stretching and degradation was evaluated. The results presented demonstrate the importance of keeping the right balance between the four parameters conditions which are approximately 55Â°C, 100rpm, 65% solvent ratio and 1% initiator, respectively. The FTIR results shows that the particle sizes variation affects the performance of MIP where particles with 4 #m size reached 84% removal within time constrain rather than particles with 514 #m size only manage 40% of template removal. Generally, it could be concluded that smaller MIPs achieve removal better than the bigger ones and is expected to perform better in further investigations. World Academy of Reseacrh and Publication 2012 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/5743/1/fkksa-2012-cheku-influence_of_factorial.pdf C. K. M., Faizal and Shareena, Mohd Sharif (2012) Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer. International Journal of Chemical and Environmental Engineering, 3 (2). pp. 147-151. ISSN 2078-0737 http://www.warponline.org/uploads/contents/15-content-Influence-of-factorial-design-analysis-on-the-performance-of-bisphenol-A-molecular-imprinted-polymer.pdf
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology C. K. M., Faizal Shareena, Mohd Sharif Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer
description	The main issue in the synthesis of molecular imprinted polymer nanoparticles is the identification and optimization of the key factors affecting the material structure and molecular recognition properties. This paper focus on the application of experimental design approach to synthesis bisphenol A molecular imprinted polymers (BPA-MIPs) aimed at the effect on polymerisation temperature, agitation rate, cross-linker to solvent ratio, and percentage of initiator; and determine the influence on hydrolysis breakage to remove template molecule, discussed by FTIR spectra results. The polymers were prepared under thermal suspension polymerization and their functional group stretching and degradation was evaluated. The results presented demonstrate the importance of keeping the right balance between the four parameters conditions which are approximately 55Â°C, 100rpm, 65% solvent ratio and 1% initiator, respectively. The FTIR results shows that the particle sizes variation affects the performance of MIP where particles with 4 #m size reached 84% removal within time constrain rather than particles with 514 #m size only manage 40% of template removal. Generally, it could be concluded that smaller MIPs achieve removal better than the bigger ones and is expected to perform better in further investigations.
format	Article
author	C. K. M., Faizal Shareena, Mohd Sharif
author_facet	C. K. M., Faizal Shareena, Mohd Sharif
author_sort	C. K. M., Faizal
title	Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer
title_short	Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer
title_full	Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer
title_fullStr	Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer
title_full_unstemmed	Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer
title_sort	influence of factorial design analysis on the performance of bisphenol a molecular imprinted polymer
publisher	World Academy of Reseacrh and Publication
publishDate	2012
url	http://umpir.ump.edu.my/id/eprint/5743/ http://umpir.ump.edu.my/id/eprint/5743/ http://umpir.ump.edu.my/id/eprint/5743/1/fkksa-2012-cheku-influence_of_factorial.pdf
first_indexed	2023-09-18T22:01:08Z
last_indexed	2023-09-18T22:01:08Z
_version_	1777414405732958208

Influence of Factorial Design Analysis on the Performance of Bisphenol A Molecular Imprinted Polymer

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