Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement
Reaction of 1,3-di-t,'rt-bu~.laziridinonc (la) and similar aziridinones with thiosemicarbazide affords, as one of the products, a compound devoid of sulfur, vie., a substituted N- aminoimidazolidinone (3a) by selective cleavage of the acyl-nitrogcn bond. Compound 3a undergoes a novel, acid-cata...
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| Format: | Article |
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Elsevier
1996
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| Online Access: | http://umpir.ump.edu.my/id/eprint/4788/ http://umpir.ump.edu.my/id/eprint/4788/ http://umpir.ump.edu.my/id/eprint/4788/ |
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ump-4788 |
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eprints |
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ump-47882018-01-22T01:36:12Z http://umpir.ump.edu.my/id/eprint/4788/ Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement M. M., Yusoff Talaty, Erach R Q Science (General) Reaction of 1,3-di-t,'rt-bu~.laziridinonc (la) and similar aziridinones with thiosemicarbazide affords, as one of the products, a compound devoid of sulfur, vie., a substituted N- aminoimidazolidinone (3a) by selective cleavage of the acyl-nitrogcn bond. Compound 3a undergoes a novel, acid-catalyzed rearrangement to a 3-imino-hexahydro-1,2,4-tri~in-6-one (7a), which can also be obtained ~' treatment of la with hydrazinc followed by BrCN. involving again selective cleavage of the acyl-nitrogen bond. Elsevier 1996-11-25 Article PeerReviewed M. M., Yusoff and Talaty, Erach R (1996) Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement. Tetrahedron Letters, 37 (48). pp. 8695-8698. ISSN 0040-4039 http://dx.doi.org/10.1016/S0040-4039(96)02039-4 DOI: 10.1016/S0040-4039(96)02039-4 |
| repository_type |
Digital Repository |
| institution_category |
Local University |
| institution |
Universiti Malaysia Pahang |
| building |
UMP Institutional Repository |
| collection |
Online Access |
| topic |
Q Science (General) |
| spellingShingle |
Q Science (General) M. M., Yusoff Talaty, Erach R Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement |
| description |
Reaction of 1,3-di-t,'rt-bu~.laziridinonc (la) and similar aziridinones with thiosemicarbazide affords, as one of the products, a compound devoid of sulfur, vie., a substituted N- aminoimidazolidinone (3a) by selective cleavage of the acyl-nitrogcn bond. Compound 3a undergoes a novel, acid-catalyzed rearrangement to a 3-imino-hexahydro-1,2,4-tri~in-6-one (7a), which can also be obtained ~' treatment of la with hydrazinc followed by BrCN. involving again selective cleavage of the
acyl-nitrogen bond. |
| format |
Article |
| author |
M. M., Yusoff Talaty, Erach R |
| author_facet |
M. M., Yusoff Talaty, Erach R |
| author_sort |
M. M., Yusoff |
| title |
Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement |
| title_short |
Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement |
| title_full |
Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement |
| title_fullStr |
Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement |
| title_full_unstemmed |
Ring-expansion of an Aziridinone to a Hexahydrotriazine Through the Agency of a Novel Rearrangement |
| title_sort |
ring-expansion of an aziridinone to a hexahydrotriazine through the agency of a novel rearrangement |
| publisher |
Elsevier |
| publishDate |
1996 |
| url |
http://umpir.ump.edu.my/id/eprint/4788/ http://umpir.ump.edu.my/id/eprint/4788/ http://umpir.ump.edu.my/id/eprint/4788/ |
| first_indexed |
2023-09-18T21:59:42Z |
| last_indexed |
2023-09-18T21:59:42Z |
| _version_ |
1777414315262869504 |