Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors

A flower-shaped hydrated layered sodium titanate material, Na2Ti2O4(OH)2, have been synthesized through a facile hydrothermal method and subsequently converted into sodium free titania (anatase). Potential application of the Na2Ti2O4(OH)2 as an electrode for supercapacitors under pseudo-capacitance...

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Main Authors: M. M., Yusoff, Rajan, Jose, K. F., Chong, Radhiyah, Abd Aziz, Izan Izwan, Misnon
Format: Article
Language:English
Published: Elsevier 2013
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Online Access:http://umpir.ump.edu.my/id/eprint/4702/
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spelling ump-47022018-07-27T03:22:53Z http://umpir.ump.edu.my/id/eprint/4702/ Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors M. M., Yusoff Rajan, Jose K. F., Chong Radhiyah, Abd Aziz Izan Izwan, Misnon Q Science (General) QD Chemistry A flower-shaped hydrated layered sodium titanate material, Na2Ti2O4(OH)2, have been synthesized through a facile hydrothermal method and subsequently converted into sodium free titania (anatase). Potential application of the Na2Ti2O4(OH)2 as an electrode for supercapacitors under pseudo-capacitance storage mode is evaluated. The Na2Ti2O4(OH)2 showed sixfold higher specific capacitance (CS ∼ 300 F g−1) in an aqueous electrolyte than the anatase and demonstrated stable electrochemical cycling. This high CS is originated from a combination of electrochemical double layer and pseudo-capacitance storage mechanisms. The presence of hydrated layered within some loose interlayer plays an important role in assisting the diffusion process of ions as confirmed in electrical impedance spectroscopy analysis. Elsevier 2013-12-15 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/4702/1/fist-2013-mashitah-LayeredSodiumTitanateAbsOnly.pdf M. M., Yusoff and Rajan, Jose and K. F., Chong and Radhiyah, Abd Aziz and Izan Izwan, Misnon (2013) Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors. Electrochimica Acta, 113. pp. 141-148. ISSN 0013-4686 http://dx.doi.org/10.1016/j.electacta.2013.09.128 DOI: 10.1016/j.electacta.2013.09.128
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
M. M., Yusoff
Rajan, Jose
K. F., Chong
Radhiyah, Abd Aziz
Izan Izwan, Misnon
Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
description A flower-shaped hydrated layered sodium titanate material, Na2Ti2O4(OH)2, have been synthesized through a facile hydrothermal method and subsequently converted into sodium free titania (anatase). Potential application of the Na2Ti2O4(OH)2 as an electrode for supercapacitors under pseudo-capacitance storage mode is evaluated. The Na2Ti2O4(OH)2 showed sixfold higher specific capacitance (CS ∼ 300 F g−1) in an aqueous electrolyte than the anatase and demonstrated stable electrochemical cycling. This high CS is originated from a combination of electrochemical double layer and pseudo-capacitance storage mechanisms. The presence of hydrated layered within some loose interlayer plays an important role in assisting the diffusion process of ions as confirmed in electrical impedance spectroscopy analysis.
format Article
author M. M., Yusoff
Rajan, Jose
K. F., Chong
Radhiyah, Abd Aziz
Izan Izwan, Misnon
author_facet M. M., Yusoff
Rajan, Jose
K. F., Chong
Radhiyah, Abd Aziz
Izan Izwan, Misnon
author_sort M. M., Yusoff
title Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
title_short Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
title_full Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
title_fullStr Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
title_full_unstemmed Layered Sodium Titanate Nanostructures as a New Electrode for High Energy Density Supercapacitors
title_sort layered sodium titanate nanostructures as a new electrode for high energy density supercapacitors
publisher Elsevier
publishDate 2013
url http://umpir.ump.edu.my/id/eprint/4702/
http://umpir.ump.edu.my/id/eprint/4702/
http://umpir.ump.edu.my/id/eprint/4702/
http://umpir.ump.edu.my/id/eprint/4702/1/fist-2013-mashitah-LayeredSodiumTitanateAbsOnly.pdf
first_indexed 2023-09-18T21:59:33Z
last_indexed 2023-09-18T21:59:33Z
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