Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach

In this study, the modification of cellulose derivative namely carboxymethyl cellulose (CMC) blended with polyvinyl alcohol (PVA) and doped with different content of NH4Br based solid polymer electrolytes (SPEs) prepared via solution casting method is investigated. The FTIR analysis demonstrated the...

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Main Authors:	N. F., Mazuki, Anwar, P. P. Abdul Majeed, Nagao, Y., A. S., Samsudin
Format:	Article
Language:	English English
Published:	Elsevier Ltd 2020
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/27742/ http://umpir.ump.edu.my/id/eprint/27742/ http://umpir.ump.edu.my/id/eprint/27742/ http://umpir.ump.edu.my/id/eprint/27742/1/Studies%20on%20ionics%20conduction%20properties%20of%20modification%20CMC-PVA.pdf http://umpir.ump.edu.my/id/eprint/27742/2/Studies%20on%20ionics%20conduction%20properties%20of%20modification%20CMC-PVA.pdf

id	ump-27742
recordtype	eprints
spelling	ump-277422020-02-06T08:42:15Z http://umpir.ump.edu.my/id/eprint/27742/ Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach N. F., Mazuki Anwar, P. P. Abdul Majeed Nagao, Y. A. S., Samsudin TP Chemical technology In this study, the modification of cellulose derivative namely carboxymethyl cellulose (CMC) blended with polyvinyl alcohol (PVA) and doped with different content of NH4Br based solid polymer electrolytes (SPEs) prepared via solution casting method is investigated. The FTIR analysis demonstrated the interaction between CMC-PVA and NH4Br via COO−. The optimum ionic conductivity at ambient temperature is found to be 3.21 × 10−4 S/cm for the sample containing 20 wt% NH4Br with the lowest percentage of crystallinity and total weight loss. The conductivity-temperature relationship for the entire SPEs system obeys Arrhenius behaviour. Besides that, based on the Nyquist fitting analysis, it is shown that the ionic conductivity of the SPEs is primarily influenced by the ionic mobility as well as the ions diffusion coefficient. The H+ transference number obtained using non-blocking reversible electrode is 0.31, which further indicates that the conduction species is predominantly due to the cationic conduction. Elsevier Ltd 2020-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/27742/1/Studies%20on%20ionics%20conduction%20properties%20of%20modification%20CMC-PVA.pdf pdf en http://umpir.ump.edu.my/id/eprint/27742/2/Studies%20on%20ionics%20conduction%20properties%20of%20modification%20CMC-PVA.pdf N. F., Mazuki and Anwar, P. P. Abdul Majeed and Nagao, Y. and A. S., Samsudin (2020) Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach. Polymer Testing, 81 (106234). ISSN 0142-9418 https://doi.org/10.1016/j.polymertesting.2019.106234 https://doi.org/10.1016/j.polymertesting.2019.106234
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology N. F., Mazuki Anwar, P. P. Abdul Majeed Nagao, Y. A. S., Samsudin Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach
description	In this study, the modification of cellulose derivative namely carboxymethyl cellulose (CMC) blended with polyvinyl alcohol (PVA) and doped with different content of NH4Br based solid polymer electrolytes (SPEs) prepared via solution casting method is investigated. The FTIR analysis demonstrated the interaction between CMC-PVA and NH4Br via COO−. The optimum ionic conductivity at ambient temperature is found to be 3.21 × 10−4 S/cm for the sample containing 20 wt% NH4Br with the lowest percentage of crystallinity and total weight loss. The conductivity-temperature relationship for the entire SPEs system obeys Arrhenius behaviour. Besides that, based on the Nyquist fitting analysis, it is shown that the ionic conductivity of the SPEs is primarily influenced by the ionic mobility as well as the ions diffusion coefficient. The H+ transference number obtained using non-blocking reversible electrode is 0.31, which further indicates that the conduction species is predominantly due to the cationic conduction.
format	Article
author	N. F., Mazuki Anwar, P. P. Abdul Majeed Nagao, Y. A. S., Samsudin
author_facet	N. F., Mazuki Anwar, P. P. Abdul Majeed Nagao, Y. A. S., Samsudin
author_sort	N. F., Mazuki
title	Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach
title_short	Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach
title_full	Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach
title_fullStr	Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach
title_full_unstemmed	Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach
title_sort	studies on ionics conduction properties of modification cmc-pva based polymer blend electrolytes via impedance approach
publisher	Elsevier Ltd
publishDate	2020
url	http://umpir.ump.edu.my/id/eprint/27742/ http://umpir.ump.edu.my/id/eprint/27742/ http://umpir.ump.edu.my/id/eprint/27742/ http://umpir.ump.edu.my/id/eprint/27742/1/Studies%20on%20ionics%20conduction%20properties%20of%20modification%20CMC-PVA.pdf http://umpir.ump.edu.my/id/eprint/27742/2/Studies%20on%20ionics%20conduction%20properties%20of%20modification%20CMC-PVA.pdf
first_indexed	2023-09-18T22:43:32Z
last_indexed	2023-09-18T22:43:32Z
_version_	1777417073432985600

Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach

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