Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte

Glycerolized dextran-ammonium nitrate (NH4NO3) biopolymer electrolytes are prepared by solution cast technique. The addition of 20 wt% glycerol has increased the conductivity value from (3.00 ± 1.60) × 10−5 S cm−1 to (1.15 ± 0.08) × 10−3 S cm−1. The study of ionic conductivities at high temperature...

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Main Authors:	Hamsan, Muhamad H., Aziz, Shujahadeen B., M.A.S., Azha, A.A., Azli, M.F., Shukur, Y.M., Yusof, Saifful Kamaluddin, Muzakir, Ninie S.A., Manan, M.F.Z., Kadir
Format:	Article
Language:	English
Published:	Elsevier 2020
Subjects:	QD Chemistry QP Physiology RM Therapeutics. Pharmacology
Online Access:	http://umpir.ump.edu.my/id/eprint/27245/ http://umpir.ump.edu.my/id/eprint/27245/ http://umpir.ump.edu.my/id/eprint/27245/ http://umpir.ump.edu.my/id/eprint/27245/1/Solid-state%20double%20layer%20capacitors%20and%20protonic%20cell%20fabricated%20.pdf

id	ump-27245
recordtype	eprints
spelling	ump-272452020-03-10T10:02:25Z http://umpir.ump.edu.my/id/eprint/27245/ Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte Hamsan, Muhamad H. Aziz, Shujahadeen B. M.A.S., Azha A.A., Azli M.F., Shukur Y.M., Yusof Saifful Kamaluddin, Muzakir Ninie S.A., Manan M.F.Z., Kadir QD Chemistry QP Physiology RM Therapeutics. Pharmacology Glycerolized dextran-ammonium nitrate (NH4NO3) biopolymer electrolytes are prepared by solution cast technique. The addition of 20 wt% glycerol has increased the conductivity value from (3.00 ± 1.60) × 10−5 S cm−1 to (1.15 ± 0.08) × 10−3 S cm−1. The study of ionic conductivities at high temperature is carried out from 298 K to 353 K and found that the conductivities harmonized with the Arrhenius rule. Results from dielectric analysis have proved that the dielectric constant of the electrolytes has increased as the glycerol concentration is increased. The trend of dielectric analysis follows the conductivity pattern at high temperature. Transference number of the highest conducting electrolyte is found to be 0.97, which proves that ion is the dominant conducting species. From conduction mechanism analysis, the electrolytes obey the correlated barrier hopping (CBH) model. Linear sweep voltammetry (LSV) confirms that the highest conducting electrolyte is suitable to be applied in electrochemical devices with potential stability up to 1.75 V. The fabricated supercapacitor is stable over 1000 cycles with the highest specific capacitance (Cs) of ~15.7 F g−1. The open circuit potential (OCP) for the fabricated protonic cell is ~ (1.40 ± 0.01) V with capacity of 11.6 ± 0.5 mAh. Elsevier 2020-02-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/27245/1/Solid-state%20double%20layer%20capacitors%20and%20protonic%20cell%20fabricated%20.pdf Hamsan, Muhamad H. and Aziz, Shujahadeen B. and M.A.S., Azha and A.A., Azli and M.F., Shukur and Y.M., Yusof and Saifful Kamaluddin, Muzakir and Ninie S.A., Manan and M.F.Z., Kadir (2020) Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte. Materials Chemistry and Physics, 241 (122290). ISSN 0254-0584 https://doi.org/10.1016/j.matchemphys.2019.122290 https://doi.org/10.1016/j.matchemphys.2019.122290
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QD Chemistry QP Physiology RM Therapeutics. Pharmacology
spellingShingle	QD Chemistry QP Physiology RM Therapeutics. Pharmacology Hamsan, Muhamad H. Aziz, Shujahadeen B. M.A.S., Azha A.A., Azli M.F., Shukur Y.M., Yusof Saifful Kamaluddin, Muzakir Ninie S.A., Manan M.F.Z., Kadir Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
description	Glycerolized dextran-ammonium nitrate (NH4NO3) biopolymer electrolytes are prepared by solution cast technique. The addition of 20 wt% glycerol has increased the conductivity value from (3.00 ± 1.60) × 10−5 S cm−1 to (1.15 ± 0.08) × 10−3 S cm−1. The study of ionic conductivities at high temperature is carried out from 298 K to 353 K and found that the conductivities harmonized with the Arrhenius rule. Results from dielectric analysis have proved that the dielectric constant of the electrolytes has increased as the glycerol concentration is increased. The trend of dielectric analysis follows the conductivity pattern at high temperature. Transference number of the highest conducting electrolyte is found to be 0.97, which proves that ion is the dominant conducting species. From conduction mechanism analysis, the electrolytes obey the correlated barrier hopping (CBH) model. Linear sweep voltammetry (LSV) confirms that the highest conducting electrolyte is suitable to be applied in electrochemical devices with potential stability up to 1.75 V. The fabricated supercapacitor is stable over 1000 cycles with the highest specific capacitance (Cs) of ~15.7 F g−1. The open circuit potential (OCP) for the fabricated protonic cell is ~ (1.40 ± 0.01) V with capacity of 11.6 ± 0.5 mAh.
format	Article
author	Hamsan, Muhamad H. Aziz, Shujahadeen B. M.A.S., Azha A.A., Azli M.F., Shukur Y.M., Yusof Saifful Kamaluddin, Muzakir Ninie S.A., Manan M.F.Z., Kadir
author_facet	Hamsan, Muhamad H. Aziz, Shujahadeen B. M.A.S., Azha A.A., Azli M.F., Shukur Y.M., Yusof Saifful Kamaluddin, Muzakir Ninie S.A., Manan M.F.Z., Kadir
author_sort	Hamsan, Muhamad H.
title	Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
title_short	Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
title_full	Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
title_fullStr	Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
title_full_unstemmed	Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
title_sort	solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte
publisher	Elsevier
publishDate	2020
url	http://umpir.ump.edu.my/id/eprint/27245/ http://umpir.ump.edu.my/id/eprint/27245/ http://umpir.ump.edu.my/id/eprint/27245/ http://umpir.ump.edu.my/id/eprint/27245/1/Solid-state%20double%20layer%20capacitors%20and%20protonic%20cell%20fabricated%20.pdf
first_indexed	2023-09-18T22:42:46Z
last_indexed	2023-09-18T22:42:46Z
_version_	1777417024859799552

Solid-state double layer capacitors and protonic cell fabricated with dextran from leuconostoc mesenteroides based green polymer electrolyte

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