Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane

SBA-15 support was successfully synthesized using extracted silica from palm oil fuel ash waste (POFA). Four types of Ni/SBA-15 catalysts were prepared via the ordinary impregnation technique (Ni/SBA-15(IM)) and assisted impregnation techniques including rotary evaporator (Ni/SBA-15(RE)), shaker (Ni...

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Main Authors:	Nornasuha, Abdullah, Nurul Aini, Razali, C. C., Chong, H. A., Razak, Setiabudi, H. D., A. A., Jalil, Vo, Dai-Viet N.
Format:	Article
Language:	English
Published:	Elsevier 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/27045/ http://umpir.ump.edu.my/id/eprint/27045/ http://umpir.ump.edu.my/id/eprint/27045/ http://umpir.ump.edu.my/id/eprint/27045/1/Influence%20of%20impregnation%20assisted%20methods%20of%20Ni1.pdf

id	ump-27045
recordtype	eprints
spelling	ump-270452019-12-18T03:55:13Z http://umpir.ump.edu.my/id/eprint/27045/ Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane Nornasuha, Abdullah Nurul Aini, Razali C. C., Chong H. A., Razak Setiabudi, H. D. A. A., Jalil Vo, Dai-Viet N. TP Chemical technology SBA-15 support was successfully synthesized using extracted silica from palm oil fuel ash waste (POFA). Four types of Ni/SBA-15 catalysts were prepared via the ordinary impregnation technique (Ni/SBA-15(IM)) and assisted impregnation techniques including rotary evaporator (Ni/SBA-15(RE)), shaker (Ni/SBA-15(SH)) and ultrasonic (Ni/SBA-15(US)). The attributes of the Ni/SBA-15 were characterized using XRD, BET, FTIR, XPS, TEM, CO2-TPD and TGA. The performance and stability of Ni/SBA-15 catalysts for up to 24 h were determined using a stainless steel fixed-bed reactor setup at 800 °C. The results in a descending order were ultrasonic (US) > ordinary impregnation (IM) > shaker (SH) > rotary evaporator (RE). The highest catalytic performance was achieved by Ni/SBA-15(US) owing to the location of Ni species inside the SBA-15 micelles, stronger Ni–O–Si interaction, and higher catalyst basicity. Lowest formation of graphite carbon on Ni/SBA-15(US) was correlated to the good dispersion of smaller Ni particles that were able to suppress the coke formation. The ultrasonic irradiation provided a cavitation effect which was able to destroy the soft agglomeration of Ni particles for better dispersion compared to IM, RE, and SH. This study provides an alternative in preparing better properties of catalyst to enhance the CO2 reforming of CH4 (CRM) in terms of activity and stability. Elsevier 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/27045/1/Influence%20of%20impregnation%20assisted%20methods%20of%20Ni1.pdf Nornasuha, Abdullah and Nurul Aini, Razali and C. C., Chong and H. A., Razak and Setiabudi, H. D. and A. A., Jalil and Vo, Dai-Viet N. (2019) Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane. International Journal of Hydrogen Energy. pp. 1-14. ISSN 0360-3199 (In Press) https://doi.org/10.1016/j.ijhydene.2019.09.089 https://doi.org/10.1016/j.ijhydene.2019.09.089
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Nornasuha, Abdullah Nurul Aini, Razali C. C., Chong H. A., Razak Setiabudi, H. D. A. A., Jalil Vo, Dai-Viet N. Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane
description	SBA-15 support was successfully synthesized using extracted silica from palm oil fuel ash waste (POFA). Four types of Ni/SBA-15 catalysts were prepared via the ordinary impregnation technique (Ni/SBA-15(IM)) and assisted impregnation techniques including rotary evaporator (Ni/SBA-15(RE)), shaker (Ni/SBA-15(SH)) and ultrasonic (Ni/SBA-15(US)). The attributes of the Ni/SBA-15 were characterized using XRD, BET, FTIR, XPS, TEM, CO2-TPD and TGA. The performance and stability of Ni/SBA-15 catalysts for up to 24 h were determined using a stainless steel fixed-bed reactor setup at 800 °C. The results in a descending order were ultrasonic (US) > ordinary impregnation (IM) > shaker (SH) > rotary evaporator (RE). The highest catalytic performance was achieved by Ni/SBA-15(US) owing to the location of Ni species inside the SBA-15 micelles, stronger Ni–O–Si interaction, and higher catalyst basicity. Lowest formation of graphite carbon on Ni/SBA-15(US) was correlated to the good dispersion of smaller Ni particles that were able to suppress the coke formation. The ultrasonic irradiation provided a cavitation effect which was able to destroy the soft agglomeration of Ni particles for better dispersion compared to IM, RE, and SH. This study provides an alternative in preparing better properties of catalyst to enhance the CO2 reforming of CH4 (CRM) in terms of activity and stability.
format	Article
author	Nornasuha, Abdullah Nurul Aini, Razali C. C., Chong H. A., Razak Setiabudi, H. D. A. A., Jalil Vo, Dai-Viet N.
author_facet	Nornasuha, Abdullah Nurul Aini, Razali C. C., Chong H. A., Razak Setiabudi, H. D. A. A., Jalil Vo, Dai-Viet N.
author_sort	Nornasuha, Abdullah
title	Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane
title_short	Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane
title_full	Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane
title_fullStr	Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane
title_full_unstemmed	Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane
title_sort	influence of impregnation assisted methods of ni/sba-15 for production of hydrogen via dry reforming of methane
publisher	Elsevier
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/27045/ http://umpir.ump.edu.my/id/eprint/27045/ http://umpir.ump.edu.my/id/eprint/27045/ http://umpir.ump.edu.my/id/eprint/27045/1/Influence%20of%20impregnation%20assisted%20methods%20of%20Ni1.pdf
first_indexed	2023-09-18T22:42:24Z
last_indexed	2023-09-18T22:42:24Z
_version_	1777417002546102272

Influence of impregnation assisted methods of Ni/SBA-15 for production of hydrogen via dry reforming of methane

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