Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil

Colloidal Mg(OH)2/MgO nanoparticles were successfully produced in glycerol medium in the presence of hydrazine and subsequently was characterized by XRD. The as-prepared colloidal suspension in glycerol was used for the glycerolysis reaction with palm oil succeeded by polyesterification reaction wit...

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Main Authors:	Munusamy, Thurga Devi, Sumaya, Sarmin, Huei, Ruey Ong, Wei, Teng Gan, Chi, Shein Hong, Khan, Maksudur R.
Format:	Article
Language:	English
Published:	Springer Berlin Heidelberg 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/26684/ http://umpir.ump.edu.my/id/eprint/26684/ http://umpir.ump.edu.my/id/eprint/26684/ http://umpir.ump.edu.my/id/eprint/26684/1/Catalytic%20performance%20and%20antimicrobial%20activity%20of%20Mg1.pdf

id	ump-26684
recordtype	eprints
spelling	ump-266842019-12-03T06:07:16Z http://umpir.ump.edu.my/id/eprint/26684/ Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil Munusamy, Thurga Devi Sumaya, Sarmin Huei, Ruey Ong Wei, Teng Gan Chi, Shein Hong Khan, Maksudur R. TP Chemical technology Colloidal Mg(OH)2/MgO nanoparticles were successfully produced in glycerol medium in the presence of hydrazine and subsequently was characterized by XRD. The as-prepared colloidal suspension in glycerol was used for the glycerolysis reaction with palm oil succeeded by polyesterification reaction with phthalic anhydride to prepare the palm oil-based alkyd resin nanocomposite where the Mg(OH)2/MgO nanoparticles catalysed the reactions. The well-dispersion of Mg(OH)2/MgO nanoparticles in the reaction mixture formed a stable suspension which effectively elevated the rate of reaction of both alcoholysis and polyesterification as compared to conventional NaOH catalysed reactions. The optimum reaction condition of the catalysts was observed at 0.04 wt% of Mg(OH)2/MgO. Alkyd resin nanocomposite formation was verified through FTIR, 13C NMR and 1H NMR. The presence of the Mg(OH)2/MgO nanoparticles in the resin matrix significantly improved the antimicrobial activity as evidenced by Kirby–Bauer Method. Thereby, the formulation of Mg(OH)2/MgO nanoparticles in glycerol medium was proved to be an effective route as compared to traditional NaOH homogeneous base catalyzed system. Springer Berlin Heidelberg 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26684/1/Catalytic%20performance%20and%20antimicrobial%20activity%20of%20Mg1.pdf Munusamy, Thurga Devi and Sumaya, Sarmin and Huei, Ruey Ong and Wei, Teng Gan and Chi, Shein Hong and Khan, Maksudur R. (2019) Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil. Polymer Bulletin. pp. 1-16. ISSN 0170-0839(Print); 1436-2449(Online) https://doi.org/10.1007/s00289-019-02993-8 https://doi.org/10.1007/s00289-019-02993-8
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Munusamy, Thurga Devi Sumaya, Sarmin Huei, Ruey Ong Wei, Teng Gan Chi, Shein Hong Khan, Maksudur R. Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
description	Colloidal Mg(OH)2/MgO nanoparticles were successfully produced in glycerol medium in the presence of hydrazine and subsequently was characterized by XRD. The as-prepared colloidal suspension in glycerol was used for the glycerolysis reaction with palm oil succeeded by polyesterification reaction with phthalic anhydride to prepare the palm oil-based alkyd resin nanocomposite where the Mg(OH)2/MgO nanoparticles catalysed the reactions. The well-dispersion of Mg(OH)2/MgO nanoparticles in the reaction mixture formed a stable suspension which effectively elevated the rate of reaction of both alcoholysis and polyesterification as compared to conventional NaOH catalysed reactions. The optimum reaction condition of the catalysts was observed at 0.04 wt% of Mg(OH)2/MgO. Alkyd resin nanocomposite formation was verified through FTIR, 13C NMR and 1H NMR. The presence of the Mg(OH)2/MgO nanoparticles in the resin matrix significantly improved the antimicrobial activity as evidenced by Kirby–Bauer Method. Thereby, the formulation of Mg(OH)2/MgO nanoparticles in glycerol medium was proved to be an effective route as compared to traditional NaOH homogeneous base catalyzed system.
format	Article
author	Munusamy, Thurga Devi Sumaya, Sarmin Huei, Ruey Ong Wei, Teng Gan Chi, Shein Hong Khan, Maksudur R.
author_facet	Munusamy, Thurga Devi Sumaya, Sarmin Huei, Ruey Ong Wei, Teng Gan Chi, Shein Hong Khan, Maksudur R.
author_sort	Munusamy, Thurga Devi
title	Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
title_short	Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
title_full	Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
title_fullStr	Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
title_full_unstemmed	Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
title_sort	catalytic performance and antimicrobial activity of mg(oh)2/mgo colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil
publisher	Springer Berlin Heidelberg
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/26684/ http://umpir.ump.edu.my/id/eprint/26684/ http://umpir.ump.edu.my/id/eprint/26684/ http://umpir.ump.edu.my/id/eprint/26684/1/Catalytic%20performance%20and%20antimicrobial%20activity%20of%20Mg1.pdf
first_indexed	2023-09-18T22:41:41Z
last_indexed	2023-09-18T22:41:41Z
_version_	1777416957419585536

Catalytic performance and antimicrobial activity of Mg(OH)2/MgO colloidal nanoparticles in alkyd resin nanocomposite derived from palm oil

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