Optimization by RSM for the preparation of bioresin from palm oil

Synthetic resins are useful material for various applications, but they are majorly derived from petroleum and its derivatives. Petroleum derived products are usually nonbiodegradable, and production of them involves high manufacturing cost. During their processing, consumption of huge heat energy a...

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Main Authors:	Beg, M. D. H., Islam, Mir Sujaul, B., Ahmed, R. M., Yunus
Format:	Conference or Workshop Item
Language:	English English
Published:	2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/26330/ http://umpir.ump.edu.my/id/eprint/26330/1/4.%20Optimization%20by%20RSM%20for%20the%20preparation%20of%20bioresin%20from%20palm%20oil.pdf http://umpir.ump.edu.my/id/eprint/26330/2/4.1%20Optimization%20by%20RSM%20for%20the%20preparation%20of%20bioresin%20from%20palm%20oil.pdf

id	ump-26330
recordtype	eprints
spelling	ump-263302019-12-23T02:12:01Z http://umpir.ump.edu.my/id/eprint/26330/ Optimization by RSM for the preparation of bioresin from palm oil Beg, M. D. H. Islam, Mir Sujaul B., Ahmed R. M., Yunus TP Chemical technology Synthetic resins are useful material for various applications, but they are majorly derived from petroleum and its derivatives. Petroleum derived products are usually nonbiodegradable, and production of them involves high manufacturing cost. During their processing, consumption of huge heat energy and emissions of greenhouse gases are common concerns.Vegetable oil is one of the renewable bioresources which can be used as an alternative of petroleum-based raw materials for the preparation of polymeric materials. Palm oil is largely-produced vegetable oil in the world and can be used in this purpose. In this research work, polyalkyd-based resin was prepared from palm oil by using polycondensation reaction. A two-step method viz. alcoholysis and esterification was conducted to synthesize polyalkyd-based resin. Prior to alcoholysis, crude palm oil was subjected for catalytic dehydration process to increase its unsaturation for the preparation of good quality alkyd resins. Response surface methodology was used to optimize the esterification reaction parameters like reaction temperature, reaction time, catalyst concentration, acid anhydride to mono-glyceride ratio and agitation speed. Result analyses through RSM revealed a desirability of 0.985, predicted reaction time of 88.64 min, catalyst concentration of 0.04 wt.%, agitation speed of 584.20 rpm and phthalic anhydride: mono-glyceride (PA:MG) molar ratio of 0.35:1 at reaction temperature 240oC. Moreover, 91.5% fractional conversion was achieved, which is close to the predicted value. 2019 Conference or Workshop Item NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26330/1/4.%20Optimization%20by%20RSM%20for%20the%20preparation%20of%20bioresin%20from%20palm%20oil.pdf pdf en http://umpir.ump.edu.my/id/eprint/26330/2/4.1%20Optimization%20by%20RSM%20for%20the%20preparation%20of%20bioresin%20from%20palm%20oil.pdf Beg, M. D. H. and Islam, Mir Sujaul and B., Ahmed and R. M., Yunus (2019) Optimization by RSM for the preparation of bioresin from palm oil. In: The 6th Global Conference On Polymer And Composite Materials (PCM 2019), 8-11 July2019 , Bangkok, Thailand. pp. 1-13.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Beg, M. D. H. Islam, Mir Sujaul B., Ahmed R. M., Yunus Optimization by RSM for the preparation of bioresin from palm oil
description	Synthetic resins are useful material for various applications, but they are majorly derived from petroleum and its derivatives. Petroleum derived products are usually nonbiodegradable, and production of them involves high manufacturing cost. During their processing, consumption of huge heat energy and emissions of greenhouse gases are common concerns.Vegetable oil is one of the renewable bioresources which can be used as an alternative of petroleum-based raw materials for the preparation of polymeric materials. Palm oil is largely-produced vegetable oil in the world and can be used in this purpose. In this research work, polyalkyd-based resin was prepared from palm oil by using polycondensation reaction. A two-step method viz. alcoholysis and esterification was conducted to synthesize polyalkyd-based resin. Prior to alcoholysis, crude palm oil was subjected for catalytic dehydration process to increase its unsaturation for the preparation of good quality alkyd resins. Response surface methodology was used to optimize the esterification reaction parameters like reaction temperature, reaction time, catalyst concentration, acid anhydride to mono-glyceride ratio and agitation speed. Result analyses through RSM revealed a desirability of 0.985, predicted reaction time of 88.64 min, catalyst concentration of 0.04 wt.%, agitation speed of 584.20 rpm and phthalic anhydride: mono-glyceride (PA:MG) molar ratio of 0.35:1 at reaction temperature 240oC. Moreover, 91.5% fractional conversion was achieved, which is close to the predicted value.
format	Conference or Workshop Item
author	Beg, M. D. H. Islam, Mir Sujaul B., Ahmed R. M., Yunus
author_facet	Beg, M. D. H. Islam, Mir Sujaul B., Ahmed R. M., Yunus
author_sort	Beg, M. D. H.
title	Optimization by RSM for the preparation of bioresin from palm oil
title_short	Optimization by RSM for the preparation of bioresin from palm oil
title_full	Optimization by RSM for the preparation of bioresin from palm oil
title_fullStr	Optimization by RSM for the preparation of bioresin from palm oil
title_full_unstemmed	Optimization by RSM for the preparation of bioresin from palm oil
title_sort	optimization by rsm for the preparation of bioresin from palm oil
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/26330/ http://umpir.ump.edu.my/id/eprint/26330/1/4.%20Optimization%20by%20RSM%20for%20the%20preparation%20of%20bioresin%20from%20palm%20oil.pdf http://umpir.ump.edu.my/id/eprint/26330/2/4.1%20Optimization%20by%20RSM%20for%20the%20preparation%20of%20bioresin%20from%20palm%20oil.pdf
first_indexed	2023-09-18T22:40:56Z
last_indexed	2023-09-18T22:40:56Z
_version_	1777416909438844928

Optimization by RSM for the preparation of bioresin from palm oil

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