Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]

This paper studied the use of bifunctional ionic liquid as an extractant to extract and separate Sm-Eu-Gd mixed solutions. The extractant combined the conventional extractant di-(2-ethyl hexyl) phosphate (P204) with ionic liquid Aliquat 336 (A336) through acid/base neutralization method. This work e...

Full description

Bibliographic Details
Main Authors:	Ismail, N. A., Hisyam, A., Shariff, S.
Format:	Article
Language:	English
Published:	AIP Publishing 2019
Subjects:	QD Chemistry TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/25846/ http://umpir.ump.edu.my/id/eprint/25846/ http://umpir.ump.edu.my/id/eprint/25846/1/Separation%20of%20Sm-Eu-Gd%20mixed%20solutions%20using%20bifunctional%20ionic%20liquid%20%5BA336%5D%5BP204%5D.pdf

id	ump-25846
recordtype	eprints
spelling	ump-258462019-09-26T09:25:26Z http://umpir.ump.edu.my/id/eprint/25846/ Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204] Ismail, N. A. Hisyam, A. Shariff, S. QD Chemistry TP Chemical technology This paper studied the use of bifunctional ionic liquid as an extractant to extract and separate Sm-Eu-Gd mixed solutions. The extractant combined the conventional extractant di-(2-ethyl hexyl) phosphate (P204) with ionic liquid Aliquat 336 (A336) through acid/base neutralization method. This work explored the effect of extraction medium (chloride, sulphate and nitrate), acid concentration (1.5-5.0 M) and organic to aqueous phase ratio (1:1, 3:2, 7:3, 4:1, 9:1) to determine the separation factor of each metals. Based on the results, Sm(III) showed the highest separation factor of total solute (βSm/total-Sm=2.81) in the nitrate medium with the acid concentration of 3.0M and organic to aqueous phase ratio of 4:1. Sm(III) was chosen to be separated in the first stage of extraction from the Sm-Eu-Gd mixed solution. In the second stage, the optimized condition to separate the remaining Eu-Gd mixed solution into individual metal was also in the nitrate medium with organic to aqueous phase ratio of 3:2, except with lower acid concentration, 2.0M. This work shows that [A336][P204] is an impeccable extractant candidate for an improved and environmental friendly to separate Sm-Eu-Gd in both laboratory and industrial application. AIP Publishing 2019-07-24 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25846/1/Separation%20of%20Sm-Eu-Gd%20mixed%20solutions%20using%20bifunctional%20ionic%20liquid%20%5BA336%5D%5BP204%5D.pdf Ismail, N. A. and Hisyam, A. and Shariff, S. (2019) Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]. AIP Conference Proceedings. 020053-1. https://doi.org/10.1063/1.5117113
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QD Chemistry TP Chemical technology
spellingShingle	QD Chemistry TP Chemical technology Ismail, N. A. Hisyam, A. Shariff, S. Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]
description	This paper studied the use of bifunctional ionic liquid as an extractant to extract and separate Sm-Eu-Gd mixed solutions. The extractant combined the conventional extractant di-(2-ethyl hexyl) phosphate (P204) with ionic liquid Aliquat 336 (A336) through acid/base neutralization method. This work explored the effect of extraction medium (chloride, sulphate and nitrate), acid concentration (1.5-5.0 M) and organic to aqueous phase ratio (1:1, 3:2, 7:3, 4:1, 9:1) to determine the separation factor of each metals. Based on the results, Sm(III) showed the highest separation factor of total solute (βSm/total-Sm=2.81) in the nitrate medium with the acid concentration of 3.0M and organic to aqueous phase ratio of 4:1. Sm(III) was chosen to be separated in the first stage of extraction from the Sm-Eu-Gd mixed solution. In the second stage, the optimized condition to separate the remaining Eu-Gd mixed solution into individual metal was also in the nitrate medium with organic to aqueous phase ratio of 3:2, except with lower acid concentration, 2.0M. This work shows that [A336][P204] is an impeccable extractant candidate for an improved and environmental friendly to separate Sm-Eu-Gd in both laboratory and industrial application.
format	Article
author	Ismail, N. A. Hisyam, A. Shariff, S.
author_facet	Ismail, N. A. Hisyam, A. Shariff, S.
author_sort	Ismail, N. A.
title	Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]
title_short	Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]
title_full	Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]
title_fullStr	Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]
title_full_unstemmed	Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]
title_sort	separation of sm-eu-gd mixed solutions using bifunctional ionic liquid [a336][p204]
publisher	AIP Publishing
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/25846/ http://umpir.ump.edu.my/id/eprint/25846/ http://umpir.ump.edu.my/id/eprint/25846/1/Separation%20of%20Sm-Eu-Gd%20mixed%20solutions%20using%20bifunctional%20ionic%20liquid%20%5BA336%5D%5BP204%5D.pdf
first_indexed	2023-09-18T22:39:54Z
last_indexed	2023-09-18T22:39:54Z
_version_	1777416845367705600

Separation of Sm-Eu-Gd mixed solutions using bifunctional ionic liquid [A336][P204]

Similar Items