Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses

We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applicat...

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Main Authors:	Israr, Hira, Rasool, Nasir, Rizwan, Komal, Hashmi, Muhammad Ali, Mahmood, Tariq, Rashid, Umer, Mohd Zobir, Hussein, Akhtar, Muhammad Nadeem
Format:	Article
Language:	English
Published:	MDPI AG 2019
Subjects:	QD Chemistry TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf

id	ump-25577
recordtype	eprints
spelling	ump-255772019-11-20T07:49:17Z http://umpir.ump.edu.my/id/eprint/25577/ Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem QD Chemistry TP Chemical technology We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities. MDPI AG 2019-05-01 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf Israr, Hira and Rasool, Nasir and Rizwan, Komal and Hashmi, Muhammad Ali and Mahmood, Tariq and Rashid, Umer and Mohd Zobir, Hussein and Akhtar, Muhammad Nadeem (2019) Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses. Symmetry, 11 (5). pp. 1-11. ISSN 2073-8994 https://doi.org/10.3390/sym11050622 https://doi.org/10.3390/sym11050622
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QD Chemistry TP Chemical technology
spellingShingle	QD Chemistry TP Chemical technology Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
description	We have synthesized aniline based amides (3a–h) via palladium catalyzed Suzuki cross coupling of N-(2,5-dibromophenyl) acetamide with different arylboronic acids in moderate to good yields. A variety of functional groups were well tolerated in reaction conditions. For exploring the possible applications as optoelectronic devices, the nonlinear optical (NLO) properties of all synthesized derivatives (3a–h) were investigated with the help of density functional theory (DFT) methods. The frontier molecular orbitals analysis and reactivity descriptors were investigated for exploring the reactivities.
format	Article
author	Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem
author_facet	Israr, Hira Rasool, Nasir Rizwan, Komal Hashmi, Muhammad Ali Mahmood, Tariq Rashid, Umer Mohd Zobir, Hussein Akhtar, Muhammad Nadeem
author_sort	Israr, Hira
title	Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_short	Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_full	Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_fullStr	Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_full_unstemmed	Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
title_sort	synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses
publisher	MDPI AG
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/ http://umpir.ump.edu.my/id/eprint/25577/1/Synthesis%20and%20reactivities%20of%20triphenyl%20acetamide%20analogs%20for%20potential%20.pdf
first_indexed	2023-09-18T22:39:21Z
last_indexed	2023-09-18T22:39:21Z
_version_	1777416810110386176

Synthesis and reactivities of triphenyl acetamide analogs for potential nonlinear optical material uses

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