Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer

The capacity of AOT (sodium bis (2-ethylhexyl) sulfosuccinate) and SB3-12 (3-(N, NDimethyldodecylammonio) propanesulfonate) mixed reverse micelle for erythromycin adsorption was assessed using the Langmuir, Freundlich, and Sips isotherm models. The kinetic of erythromycin transport was also evaluate...

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Main Authors:	Siti Norazimah, Mohamad-Aziz, Zularisam, A. W., Mimi Sakinah, A. M.
Format:	Article
Language:	English
Published:	Elsevier B.V. 2019
Subjects:	T Technology (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/25040/ http://umpir.ump.edu.my/id/eprint/25040/ http://umpir.ump.edu.my/id/eprint/25040/ http://umpir.ump.edu.my/id/eprint/25040/1/second%20journal.pdf

id	ump-25040
recordtype	eprints
spelling	ump-250402019-10-30T03:09:03Z http://umpir.ump.edu.my/id/eprint/25040/ Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer Siti Norazimah, Mohamad-Aziz Zularisam, A. W. Mimi Sakinah, A. M. T Technology (General) The capacity of AOT (sodium bis (2-ethylhexyl) sulfosuccinate) and SB3-12 (3-(N, NDimethyldodecylammonio) propanesulfonate) mixed reverse micelle for erythromycin adsorption was assessed using the Langmuir, Freundlich, and Sips isotherm models. The kinetic of erythromycin transport was also evaluated using the two-film model. The results indicated that the Langmuir isotherm model exhibits the highest precision based on the regression coefficient data, however, this applies only for the condition of 80.0 to 160.0 g/L of AOT concentration. Error analysis revealed that for a condition where AOT concentration was low, the process fits the Freundlich isotherm model, suggesting that at a surfactant concentration around 20.0 g/L, forward transfer of erythromycin shows physisorption criteria. The Langmuir isotherm data for higher AOT concentration (80.0 g/L) denotes the chemisorption characteristics, by which erythromycin transfer was at the highest degree. This also signifies that high AOT concentration is a favourable condition where stable mixed reverse micelle was available and erythromycin adsorption was accelerated. In addition, the kinetic data complements the two-film theory for a flat interface model and shows that dissemination of erythromycin into the interfacial layer of mixed reverse micelles depended on surfactant concentration. Overall, this study confirms previous findings and contributes additional evidence for erythromycin extraction, under the influence of anionic-zwitterionic surfactant combination and shows superiority towards solubilising biomolecules. Elsevier B.V. 2019-08 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25040/1/second%20journal.pdf Siti Norazimah, Mohamad-Aziz and Zularisam, A. W. and Mimi Sakinah, A. M. (2019) Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer. Journal of Molecular Liquids, 288 (111086). ISSN 01677322 https://doi.org/10.1016/j.molliq.2019.111086 https://doi.org/10.1016/j.molliq.2019.111086
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	T Technology (General)
spellingShingle	T Technology (General) Siti Norazimah, Mohamad-Aziz Zularisam, A. W. Mimi Sakinah, A. M. Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
description	The capacity of AOT (sodium bis (2-ethylhexyl) sulfosuccinate) and SB3-12 (3-(N, NDimethyldodecylammonio) propanesulfonate) mixed reverse micelle for erythromycin adsorption was assessed using the Langmuir, Freundlich, and Sips isotherm models. The kinetic of erythromycin transport was also evaluated using the two-film model. The results indicated that the Langmuir isotherm model exhibits the highest precision based on the regression coefficient data, however, this applies only for the condition of 80.0 to 160.0 g/L of AOT concentration. Error analysis revealed that for a condition where AOT concentration was low, the process fits the Freundlich isotherm model, suggesting that at a surfactant concentration around 20.0 g/L, forward transfer of erythromycin shows physisorption criteria. The Langmuir isotherm data for higher AOT concentration (80.0 g/L) denotes the chemisorption characteristics, by which erythromycin transfer was at the highest degree. This also signifies that high AOT concentration is a favourable condition where stable mixed reverse micelle was available and erythromycin adsorption was accelerated. In addition, the kinetic data complements the two-film theory for a flat interface model and shows that dissemination of erythromycin into the interfacial layer of mixed reverse micelles depended on surfactant concentration. Overall, this study confirms previous findings and contributes additional evidence for erythromycin extraction, under the influence of anionic-zwitterionic surfactant combination and shows superiority towards solubilising biomolecules.
format	Article
author	Siti Norazimah, Mohamad-Aziz Zularisam, A. W. Mimi Sakinah, A. M.
author_facet	Siti Norazimah, Mohamad-Aziz Zularisam, A. W. Mimi Sakinah, A. M.
author_sort	Siti Norazimah, Mohamad-Aziz
title	Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
title_short	Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
title_full	Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
title_fullStr	Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
title_full_unstemmed	Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
title_sort	partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer
publisher	Elsevier B.V.
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/25040/ http://umpir.ump.edu.my/id/eprint/25040/ http://umpir.ump.edu.my/id/eprint/25040/ http://umpir.ump.edu.my/id/eprint/25040/1/second%20journal.pdf
first_indexed	2023-09-18T22:38:14Z
last_indexed	2023-09-18T22:38:14Z
_version_	1777416740336041984

Partitioning isotherm and kinetic of erythromycin into mixed reverse micelle during forward transfer

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