Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture

Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) an...

Full description

Bibliographic Details
Main Authors:	Nor Asiken, Abdul Wahab, Mohd Sani, Sarjadi, Sazmal Effendi, Arshad, M. M., Yusoff, Rahman, Md. Lutfor
Format:	Article
Language:	English
Published:	Asian Publication Corporation 2019
Subjects:	QD Chemistry TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/1/Synthesis%20of%20Ion-Imprinted%20Polymer%20for%20Selective%20Separation.pdf

id	ump-24795
recordtype	eprints
spelling	ump-247952019-07-05T07:31:05Z http://umpir.ump.edu.my/id/eprint/24795/ Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor QD Chemistry TP Chemical technology Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) and 2,2-azobisisobutyronitrile (AIBN). Aqueous HCl was used to leach Cu2+ ions from the imprinted polymer for creation of cavities of template, which is utilized for cooper ions adsorption with high selectivity. The IIP were characterized using ICP-MS, FE-SEM and also solid state analysis by UV-visible NIR spectroscopy. FT-IR study confirmed the successful complexation of Cu-IIP. The optimum pH was found to be 6 and highest adsorption capacity was estimated about 112.5 mg g-1. Thus, IIP gave good selectivity to copper ions in presence of other transition metals and also IIP can be regenerated for eight times without a subst-antial loss in adsorption capacity. Asian Publication Corporation 2019-01-01 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/24795/1/Synthesis%20of%20Ion-Imprinted%20Polymer%20for%20Selective%20Separation.pdf Nor Asiken, Abdul Wahab and Mohd Sani, Sarjadi and Sazmal Effendi, Arshad and M. M., Yusoff and Rahman, Md. Lutfor (2019) Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture. Asian Journal of Chemistry, 31 (2). pp. 427-432. ISSN 0970-7077 https://doi.org/10.14233/ajchem.2019.21544 https://doi.org/10.14233/ajchem.2019.21544
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QD Chemistry TP Chemical technology
spellingShingle	QD Chemistry TP Chemical technology Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
description	Ion imprinted polymers (IIPs) draw great attention in various fields because of powerful selectivity to the target metal ions. Thus, the synthesis of copper-ion imprinted polymer (Cu-IIP) was performed by using copper ion and complexing agent rufigallol with ethylene glycol dimethacrylate (EGDMA) and 2,2-azobisisobutyronitrile (AIBN). Aqueous HCl was used to leach Cu2+ ions from the imprinted polymer for creation of cavities of template, which is utilized for cooper ions adsorption with high selectivity. The IIP were characterized using ICP-MS, FE-SEM and also solid state analysis by UV-visible NIR spectroscopy. FT-IR study confirmed the successful complexation of Cu-IIP. The optimum pH was found to be 6 and highest adsorption capacity was estimated about 112.5 mg g-1. Thus, IIP gave good selectivity to copper ions in presence of other transition metals and also IIP can be regenerated for eight times without a subst-antial loss in adsorption capacity.
format	Article
author	Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor
author_facet	Nor Asiken, Abdul Wahab Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Rahman, Md. Lutfor
author_sort	Nor Asiken, Abdul Wahab
title	Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
title_short	Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
title_full	Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
title_fullStr	Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
title_full_unstemmed	Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
title_sort	synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture
publisher	Asian Publication Corporation
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/ http://umpir.ump.edu.my/id/eprint/24795/1/Synthesis%20of%20Ion-Imprinted%20Polymer%20for%20Selective%20Separation.pdf
first_indexed	2023-09-18T22:37:44Z
last_indexed	2023-09-18T22:37:44Z
_version_	1777416708726718464

Synthesis of ion-imprinted polymer for selective separation of copper (ii) from metal ions mixture

Similar Items