New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity

New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity

The study aimed to synthesize and characterize a zeolite type X from recycling fly ash by hydrothermal treatment in the presence of sodium hydroxide and used it as decontaminant agent to remove some heavy metals (Zn+2, Pb+2 and Cu+2) from standard aqueous solution by adsorption process. The prepared...

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Main Authors: Tsabih, M. A., A. O., Mohamed, Ahmed, Omer Abdalla, Ali, Ayman A. A., Ghada, M., Nour, A. H., Ahmed, Aimun A. E.
Format: Article
Language:English
Published: JOCPR 2018
Subjects:
TD Environmental technology. Sanitary engineering
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/24424/
http://umpir.ump.edu.my/id/eprint/24424/
http://umpir.ump.edu.my/id/eprint/24424/1/New%2C%20cheap%20and%20efficient%20synthetic%20Zeolite-X%20decontaminant%20agent%20from%20fly%20ash%20for%20heavy%20metal%20toxicity.pdf
id ump-24424
recordtype eprints
spelling ump-244242019-03-19T03:10:05Z http://umpir.ump.edu.my/id/eprint/24424/ New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity Tsabih, M. A. A. O., Mohamed Ahmed, Omer Abdalla Ali, Ayman A. A. Ghada, M. Nour, A. H. Ahmed, Aimun A. E. TD Environmental technology. Sanitary engineering TP Chemical technology The study aimed to synthesize and characterize a zeolite type X from recycling fly ash by hydrothermal treatment in the presence of sodium hydroxide and used it as decontaminant agent to remove some heavy metals (Zn+2, Pb+2 and Cu+2) from standard aqueous solution by adsorption process. The prepared zeolite from fly ash by hydrothermal process was successively analyzed and characterized by X-ray Diffraction (XRD) and Fourier transfer infra-red (FTIRs) spectroscopy. Atomic absorption was used to determine the adsorption kinetic isotherm profile for the synthetic Zeolite-X, whilst the order of reaction was determined by application of Langmuir and Freundlich isotherm models. The results showed that, the produced yield of Zeolite-X (Potassium Sodium Aluminum Silicate, Chemical formula: (K57Na42(Al96 Si96 O38) was (74.8%). The kinetic isotherm studies showed time-dependent heterogenous adsorption profile following Freundlich isotherm model with first order kinetic reaction. Finally, we concluded that, the amount of Zeolite-X produced by hydrothermal process from Sudanese fly ash was found to be greater than others and was useful as a very sensitive and efficient synthetic decontaminant for elimination of heavy metals from aqueous solutions in very low concentrations. The preferable heterogeneous Freundlich isotherm model was more applicable for this synthetic Zeolite-X than the homogenous Langmuir model. It was strongly recommended to use Zeolite X in industrial areas as well as areas sufferings form water pollution by heavy metals. JOCPR 2018 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24424/1/New%2C%20cheap%20and%20efficient%20synthetic%20Zeolite-X%20decontaminant%20agent%20from%20fly%20ash%20for%20heavy%20metal%20toxicity.pdf Tsabih, M. A. and A. O., Mohamed and Ahmed, Omer Abdalla and Ali, Ayman A. A. and Ghada, M. and Nour, A. H. and Ahmed, Aimun A. E. (2018) New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity. Journal of Chemical and Pharmaceutical Research, 10 (6). pp. 110-118. ISSN 0975-7384 http://www.jocpr.com/articles/new-cheap-and-efficient-synthetic-zeolitex-decontaminant-agent-from-fly-ash-for-heavy-metal-toxicity.pdf
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TD Environmental technology. Sanitary engineering
TP Chemical technology
spellingShingle TD Environmental technology. Sanitary engineering
TP Chemical technology
Tsabih, M. A.
A. O., Mohamed
Ahmed, Omer Abdalla
Ali, Ayman A. A.
Ghada, M.
Nour, A. H.
Ahmed, Aimun A. E.
New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity
description The study aimed to synthesize and characterize a zeolite type X from recycling fly ash by hydrothermal treatment in the presence of sodium hydroxide and used it as decontaminant agent to remove some heavy metals (Zn+2, Pb+2 and Cu+2) from standard aqueous solution by adsorption process. The prepared zeolite from fly ash by hydrothermal process was successively analyzed and characterized by X-ray Diffraction (XRD) and Fourier transfer infra-red (FTIRs) spectroscopy. Atomic absorption was used to determine the adsorption kinetic isotherm profile for the synthetic Zeolite-X, whilst the order of reaction was determined by application of Langmuir and Freundlich isotherm models. The results showed that, the produced yield of Zeolite-X (Potassium Sodium Aluminum Silicate, Chemical formula: (K57Na42(Al96 Si96 O38) was (74.8%). The kinetic isotherm studies showed time-dependent heterogenous adsorption profile following Freundlich isotherm model with first order kinetic reaction. Finally, we concluded that, the amount of Zeolite-X produced by hydrothermal process from Sudanese fly ash was found to be greater than others and was useful as a very sensitive and efficient synthetic decontaminant for elimination of heavy metals from aqueous solutions in very low concentrations. The preferable heterogeneous Freundlich isotherm model was more applicable for this synthetic Zeolite-X than the homogenous Langmuir model. It was strongly recommended to use Zeolite X in industrial areas as well as areas sufferings form water pollution by heavy metals.
format Article
author Tsabih, M. A.
A. O., Mohamed
Ahmed, Omer Abdalla
Ali, Ayman A. A.
Ghada, M.
Nour, A. H.
Ahmed, Aimun A. E.
author_facet Tsabih, M. A.
A. O., Mohamed
Ahmed, Omer Abdalla
Ali, Ayman A. A.
Ghada, M.
Nour, A. H.
Ahmed, Aimun A. E.
author_sort Tsabih, M. A.
title New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity
title_short New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity
title_full New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity
title_fullStr New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity
title_full_unstemmed New, cheap and efficient synthetic Zeolite-X decontaminant agent from fly ash for heavy metal toxicity
title_sort new, cheap and efficient synthetic zeolite-x decontaminant agent from fly ash for heavy metal toxicity
publisher JOCPR
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/24424/
http://umpir.ump.edu.my/id/eprint/24424/
http://umpir.ump.edu.my/id/eprint/24424/1/New%2C%20cheap%20and%20efficient%20synthetic%20Zeolite-X%20decontaminant%20agent%20from%20fly%20ash%20for%20heavy%20metal%20toxicity.pdf
first_indexed 2023-09-18T22:36:57Z
last_indexed 2023-09-18T22:36:57Z
_version_ 1777416659366051840

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