Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater

silica-rich rice husk ash (RHA, 95.44% SiO2) was used as a silica precursor in the synthesis of KCC-1 for Pb(II) removal. The extraction of silica was carried out under several extraction methods (alkali fusion (AF), reflux (RF) and microwave heating (MW)) and extraction parameters (NaOH/RHA mass ra...

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Main Authors:	Rosalyza, Hasan, Chong, Chi Cheng, Setiabudi, H. D.
Format:	Article
Language:	English English
Published:	Department of Chemical Engineering, Diponegoro University 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/24384/ http://umpir.ump.edu.my/id/eprint/24384/ http://umpir.ump.edu.my/id/eprint/24384/ http://umpir.ump.edu.my/id/eprint/24384/1/Synthesis%20of%20KCC-1%20using%20rice%20husk%20ash%20for%20Pb%20removal%20from%20aqueous%20solution%20and%20petrochemical%20wastewater.pdf http://umpir.ump.edu.my/id/eprint/24384/7/Synthesis%20of%20KCC-1%20using%20rice%20husk%20ash%20for%20Pb%20removal.pdf

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spelling	ump-243842019-03-19T05:02:11Z http://umpir.ump.edu.my/id/eprint/24384/ Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater Rosalyza, Hasan Chong, Chi Cheng Setiabudi, H. D. TP Chemical technology silica-rich rice husk ash (RHA, 95.44% SiO2) was used as a silica precursor in the synthesis of KCC-1 for Pb(II) removal. The extraction of silica was carried out under several extraction methods (alkali fusion (AF), reflux (RF) and microwave heating (MW)) and extraction parameters (NaOH/RHA mass ratio, fusion temperature and H2O/NaOH-fused RHA mass ratio). The highest silica content was obtained using AF method at extraction conditions of NaOH/RHA mass ratio = 2, fusion temperature = 550 ºC, and H2O/NaOH-fused RHA mass ratio = 4, with silica concentration of 85,490 ppm. TEM, FTIR, and BET analyses revealed the synthesized KCC-1 has fibrous morphology with surface area of 220 m2/g. The synthesized KCC-1 showed good performance in removal of Pb(II) from aqueous solution (74%) and petrochemical wastewater (70%). The analyses of petrochemical wastewater revealed that the adsorption process using synthesized KCC-1 effectively decreased the concentration of COD (489 mg/L to 106 mg/L), BOD (56 mg/L to 34 mg/L) and Pb(II) (22.8 mg/L to 6.71 mg/L). This study affirmed that KCC-1 was successfully synthesized using RHA as silica precursor and applied as an efficient adsorbent for Pb(II) removal. Department of Chemical Engineering, Diponegoro University 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24384/1/Synthesis%20of%20KCC-1%20using%20rice%20husk%20ash%20for%20Pb%20removal%20from%20aqueous%20solution%20and%20petrochemical%20wastewater.pdf pdf en cc_by_sa_4 http://umpir.ump.edu.my/id/eprint/24384/7/Synthesis%20of%20KCC-1%20using%20rice%20husk%20ash%20for%20Pb%20removal.pdf Rosalyza, Hasan and Chong, Chi Cheng and Setiabudi, H. D. (2019) Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1). pp. 196-204. ISSN 1978-2993 https://doi.org/10.9767/bcrec.14.1.3619.196-204 https://doi.org/10.9767/bcrec.14.1.3619.196-204
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Rosalyza, Hasan Chong, Chi Cheng Setiabudi, H. D. Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater
description	silica-rich rice husk ash (RHA, 95.44% SiO2) was used as a silica precursor in the synthesis of KCC-1 for Pb(II) removal. The extraction of silica was carried out under several extraction methods (alkali fusion (AF), reflux (RF) and microwave heating (MW)) and extraction parameters (NaOH/RHA mass ratio, fusion temperature and H2O/NaOH-fused RHA mass ratio). The highest silica content was obtained using AF method at extraction conditions of NaOH/RHA mass ratio = 2, fusion temperature = 550 ºC, and H2O/NaOH-fused RHA mass ratio = 4, with silica concentration of 85,490 ppm. TEM, FTIR, and BET analyses revealed the synthesized KCC-1 has fibrous morphology with surface area of 220 m2/g. The synthesized KCC-1 showed good performance in removal of Pb(II) from aqueous solution (74%) and petrochemical wastewater (70%). The analyses of petrochemical wastewater revealed that the adsorption process using synthesized KCC-1 effectively decreased the concentration of COD (489 mg/L to 106 mg/L), BOD (56 mg/L to 34 mg/L) and Pb(II) (22.8 mg/L to 6.71 mg/L). This study affirmed that KCC-1 was successfully synthesized using RHA as silica precursor and applied as an efficient adsorbent for Pb(II) removal.
format	Article
author	Rosalyza, Hasan Chong, Chi Cheng Setiabudi, H. D.
author_facet	Rosalyza, Hasan Chong, Chi Cheng Setiabudi, H. D.
author_sort	Rosalyza, Hasan
title	Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater
title_short	Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater
title_full	Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater
title_fullStr	Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater
title_full_unstemmed	Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater
title_sort	synthesis of kcc-1 using rice husk ash for pb removal from aqueous solution and petrochemical wastewater
publisher	Department of Chemical Engineering, Diponegoro University
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/24384/ http://umpir.ump.edu.my/id/eprint/24384/ http://umpir.ump.edu.my/id/eprint/24384/ http://umpir.ump.edu.my/id/eprint/24384/1/Synthesis%20of%20KCC-1%20using%20rice%20husk%20ash%20for%20Pb%20removal%20from%20aqueous%20solution%20and%20petrochemical%20wastewater.pdf http://umpir.ump.edu.my/id/eprint/24384/7/Synthesis%20of%20KCC-1%20using%20rice%20husk%20ash%20for%20Pb%20removal.pdf
first_indexed	2023-09-18T22:36:52Z
last_indexed	2023-09-18T22:36:52Z
_version_	1777416653543309312

Synthesis of KCC-1 using rice husk ash for Pb removal from aqueous solution and petrochemical wastewater

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