Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes

The carboxymethyl cellulose and polyvinyl alcohol (CMC/PVA) based hybrid polymer (HPe) system with different ratio of composition have been prepared via solution casting. The features of interaction between CMC and PVA were investigated using X-ray diffraction (XRD), and infrared (IR) spectroscopy t...

Full description

Bibliographic Details
Main Authors:	Saadiah, M. A., Zhang, D., Nagao, Y., Saifful Kamaluddin, Muzakir, A. S., Samsudin
Format:	Article
Language:	English
Published:	Elsevier Ltd 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/24381/ http://umpir.ump.edu.my/id/eprint/24381/ http://umpir.ump.edu.my/id/eprint/24381/ http://umpir.ump.edu.my/id/eprint/24381/1/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC-PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes.pdf

id	ump-24381
recordtype	eprints
spelling	ump-243812019-03-19T05:04:23Z http://umpir.ump.edu.my/id/eprint/24381/ Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes Saadiah, M. A. Zhang, D. Nagao, Y. Saifful Kamaluddin, Muzakir A. S., Samsudin TP Chemical technology The carboxymethyl cellulose and polyvinyl alcohol (CMC/PVA) based hybrid polymer (HPe) system with different ratio of composition have been prepared via solution casting. The features of interaction between CMC and PVA were investigated using X-ray diffraction (XRD), and infrared (IR) spectroscopy to disclose the reduction of crystallinity of the HPe system. Morphological properties observed by Scanning electron microscopy (SEM) confirmed the homogeneity of the HPe system. Differential scanning calorimetry (DSC) result explains the miscibility of the HPe system which was confirmed by means of variations in the glass transition temperature (Tg). Two degradation mechanisms were revealed by thermogravimetric analysis (TGA) in the HPe system attributed to the decarboxylation in CMC and degradation of bond scission in PVA backbone. The blend of 80:20 compositions of CMC/PVA HPe system was found to be the optimum ratio with an increase in conductivity of CMC/PVA by one magnitude order from 10−7 to 10−6 S/cm with the lowest in crystallinity. Elsevier Ltd 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24381/1/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC-PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes.pdf Saadiah, M. A. and Zhang, D. and Nagao, Y. and Saifful Kamaluddin, Muzakir and A. S., Samsudin (2019) Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes. Journal of Non-Crystalline Solids, 511. pp. 201-211. ISSN 0022-3093 https://doi.org/10.1016/j.jnoncrysol.2018.11.032 https://doi.org/10.1016/j.jnoncrysol.2018.11.032
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Saadiah, M. A. Zhang, D. Nagao, Y. Saifful Kamaluddin, Muzakir A. S., Samsudin Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
description	The carboxymethyl cellulose and polyvinyl alcohol (CMC/PVA) based hybrid polymer (HPe) system with different ratio of composition have been prepared via solution casting. The features of interaction between CMC and PVA were investigated using X-ray diffraction (XRD), and infrared (IR) spectroscopy to disclose the reduction of crystallinity of the HPe system. Morphological properties observed by Scanning electron microscopy (SEM) confirmed the homogeneity of the HPe system. Differential scanning calorimetry (DSC) result explains the miscibility of the HPe system which was confirmed by means of variations in the glass transition temperature (Tg). Two degradation mechanisms were revealed by thermogravimetric analysis (TGA) in the HPe system attributed to the decarboxylation in CMC and degradation of bond scission in PVA backbone. The blend of 80:20 compositions of CMC/PVA HPe system was found to be the optimum ratio with an increase in conductivity of CMC/PVA by one magnitude order from 10−7 to 10−6 S/cm with the lowest in crystallinity.
format	Article
author	Saadiah, M. A. Zhang, D. Nagao, Y. Saifful Kamaluddin, Muzakir A. S., Samsudin
author_facet	Saadiah, M. A. Zhang, D. Nagao, Y. Saifful Kamaluddin, Muzakir A. S., Samsudin
author_sort	Saadiah, M. A.
title	Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
title_short	Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
title_full	Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
title_fullStr	Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
title_full_unstemmed	Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
title_sort	reducing crystallinity on thin film based cmc/pva hybrid polymer for application as a host in polymer electrolytes
publisher	Elsevier Ltd
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/24381/ http://umpir.ump.edu.my/id/eprint/24381/ http://umpir.ump.edu.my/id/eprint/24381/ http://umpir.ump.edu.my/id/eprint/24381/1/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC-PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes.pdf
first_indexed	2023-09-18T22:36:51Z
last_indexed	2023-09-18T22:36:51Z
_version_	1777416653124927488

Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes

Similar Items