Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels

Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels

This contribution presents the characterization of poly(acrylamide-co-acrylic acid)-grafted-poly(styrene-co-methyl methacrylate) [poly(AAm-co-AAc)-g-poly(St-co-MMA)] The chemical structure of poly(AAm-co-AAc)-g-poly(St-co-MMA) microgels was proposed. The effect of MBA contents on the degree of cross...

Full description

Bibliographic Details
Main Authors: Ros Azlinawati, Ramli, Shahrir, Hashim, Laftah, Waham Ashaier
Format: Conference or Workshop Item
Language:English
Published: IOP Publishing 2018
Subjects:
Q Science (General)
Online Access:http://umpir.ump.edu.my/id/eprint/24361/
http://umpir.ump.edu.my/id/eprint/24361/
http://umpir.ump.edu.my/id/eprint/24361/1/Chemical%20structure%2C%20water%20absorbency%20and%20thermal%20properties%20of%20poly.pdf
id ump-24361
recordtype eprints
spelling ump-243612019-05-27T04:26:03Z http://umpir.ump.edu.my/id/eprint/24361/ Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels Ros Azlinawati, Ramli Shahrir, Hashim Laftah, Waham Ashaier Q Science (General) This contribution presents the characterization of poly(acrylamide-co-acrylic acid)-grafted-poly(styrene-co-methyl methacrylate) [poly(AAm-co-AAc)-g-poly(St-co-MMA)] The chemical structure of poly(AAm-co-AAc)-g-poly(St-co-MMA) microgels was proposed. The effect of MBA contents on the degree of cross-linking (%), water absorbency (EWC, %), glass transition temperature, Tg and thermal degradation were studied. The degree of cross-linking (%) and EWC, % increased at 1.5 to 1.675 wt.% of MBA might be due to mono cross-links of MBA. The fluctuation of Tg and melting temperature (Tm ) from 1.85 to 2.2 wt.% of MBA might be due to di, poly and cyclic cross-links of MBA. Decomposition of poly(AAm-co-AAc)-g-poly(St-co-MMA) was slightly affected by increasing in MBA contents from 1.5 to 2.2 wt.%. Tg of poly(AAm-co-AAc)-g-poly(St-co-MMA) was decreased at 1.5 to 1.675 wt.% of MBA due to increase in ordered structure and crystallinity content, which led to an increase in Tm . IOP Publishing 2018-12 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24361/1/Chemical%20structure%2C%20water%20absorbency%20and%20thermal%20properties%20of%20poly.pdf Ros Azlinawati, Ramli and Shahrir, Hashim and Laftah, Waham Ashaier (2018) Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels. In: 5th International Conference on Process Engineering and Advanced Materials (ICPEAM 2018), 13-14 August 2018 , Kuala Lumpur. pp. 1-8., 458 (1). ISSN 1757-8981 (Print); 1757-899X (Online) https://iopscience.iop.org/article/10.1088/1757-899X/458/1/012003/pdf
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Ros Azlinawati, Ramli
Shahrir, Hashim
Laftah, Waham Ashaier
Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
description This contribution presents the characterization of poly(acrylamide-co-acrylic acid)-grafted-poly(styrene-co-methyl methacrylate) [poly(AAm-co-AAc)-g-poly(St-co-MMA)] The chemical structure of poly(AAm-co-AAc)-g-poly(St-co-MMA) microgels was proposed. The effect of MBA contents on the degree of cross-linking (%), water absorbency (EWC, %), glass transition temperature, Tg and thermal degradation were studied. The degree of cross-linking (%) and EWC, % increased at 1.5 to 1.675 wt.% of MBA might be due to mono cross-links of MBA. The fluctuation of Tg and melting temperature (Tm ) from 1.85 to 2.2 wt.% of MBA might be due to di, poly and cyclic cross-links of MBA. Decomposition of poly(AAm-co-AAc)-g-poly(St-co-MMA) was slightly affected by increasing in MBA contents from 1.5 to 2.2 wt.%. Tg of poly(AAm-co-AAc)-g-poly(St-co-MMA) was decreased at 1.5 to 1.675 wt.% of MBA due to increase in ordered structure and crystallinity content, which led to an increase in Tm .
format Conference or Workshop Item
author Ros Azlinawati, Ramli
Shahrir, Hashim
Laftah, Waham Ashaier
author_facet Ros Azlinawati, Ramli
Shahrir, Hashim
Laftah, Waham Ashaier
author_sort Ros Azlinawati, Ramli
title Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
title_short Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
title_full Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
title_fullStr Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
title_full_unstemmed Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
title_sort chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
publisher IOP Publishing
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/24361/
http://umpir.ump.edu.my/id/eprint/24361/
http://umpir.ump.edu.my/id/eprint/24361/1/Chemical%20structure%2C%20water%20absorbency%20and%20thermal%20properties%20of%20poly.pdf
first_indexed 2023-09-18T22:36:48Z
last_indexed 2023-09-18T22:36:48Z
_version_ 1777416650210934784

Similar Items