Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3

Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3

Carboxymethyl cellulose (CMC)/ polyvinyl alcohol (PVA) blend (80/20 wt %) as host solid bio-polymer electrolytes complexed with different weight percentage ratios of NH4NO3 were prepared via solution casting approach. Impedance spectroscopy was carried out to disclose the electrical response of the...

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Main Authors: M. A., Saadiah, A. S., Samsudin
Format: Conference or Workshop Item
Language:English
Published: AIP Publishing 2018
Subjects:
QC Physics
Online Access:http://umpir.ump.edu.my/id/eprint/23988/
http://umpir.ump.edu.my/id/eprint/23988/
http://umpir.ump.edu.my/id/eprint/23988/
http://umpir.ump.edu.my/id/eprint/23988/1/Study%20on%20ionic%20conduction%20of%20solid%20bio-polymer%20hybrid%20electrolytes%20based%20carboxymethyl%20cellulose%20%28CMC%29polyvinyl%20alcohol%20%28PVA%29%20doped%20NH4NO3.pdf
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spelling ump-239882019-03-07T02:04:02Z http://umpir.ump.edu.my/id/eprint/23988/ Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3 M. A., Saadiah A. S., Samsudin QC Physics Carboxymethyl cellulose (CMC)/ polyvinyl alcohol (PVA) blend (80/20 wt %) as host solid bio-polymer electrolytes complexed with different weight percentage ratios of NH4NO3 were prepared via solution casting approach. Impedance spectroscopy was carried out to disclose the electrical response of the CMC/PVA hybrid electrolytes as a function of various weight percentage of NH4NO3 salt. It is found that the CMC/PVA blend complexed with 30 wt % of NH4NO3 was demonstrated relatively higher room temperature conductivity by the order of 10−4 S/cm. The dielectric behaviour has been analyzed via complex permittivity (ε*) and complex modulus (M*) which varies anomalously with percentage of NH4NO3 confirms the non-Debye behaviour. Besides that, the temperature dependent dc conductivity of polymer electrolyte seems to obey Arrhenius relation, and the activation energies decrease with an increase in NH4NO3. Thus, confirming their potential as promising candidates of all-solid-state proton conducting electrolyte in the electrochemical devices. AIP Publishing 2018-11 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23988/1/Study%20on%20ionic%20conduction%20of%20solid%20bio-polymer%20hybrid%20electrolytes%20based%20carboxymethyl%20cellulose%20%28CMC%29polyvinyl%20alcohol%20%28PVA%29%20doped%20NH4NO3.pdf M. A., Saadiah and A. S., Samsudin (2018) Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3. In: 4th International Conference on Green Design and Manufacture 2018, IConGDM 2018, 29-30 April 2018 , Eden Star Saigon Hotel, Ho Chi Minh; Viet Nam. pp. 1-8., 2030 (020223). ISSN 0094-243X https://doi.org/10.1063/1.5066864 https://doi.org/10.1063/1.5066864
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic QC Physics
spellingShingle QC Physics
M. A., Saadiah
A. S., Samsudin
Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3
description Carboxymethyl cellulose (CMC)/ polyvinyl alcohol (PVA) blend (80/20 wt %) as host solid bio-polymer electrolytes complexed with different weight percentage ratios of NH4NO3 were prepared via solution casting approach. Impedance spectroscopy was carried out to disclose the electrical response of the CMC/PVA hybrid electrolytes as a function of various weight percentage of NH4NO3 salt. It is found that the CMC/PVA blend complexed with 30 wt % of NH4NO3 was demonstrated relatively higher room temperature conductivity by the order of 10−4 S/cm. The dielectric behaviour has been analyzed via complex permittivity (ε*) and complex modulus (M*) which varies anomalously with percentage of NH4NO3 confirms the non-Debye behaviour. Besides that, the temperature dependent dc conductivity of polymer electrolyte seems to obey Arrhenius relation, and the activation energies decrease with an increase in NH4NO3. Thus, confirming their potential as promising candidates of all-solid-state proton conducting electrolyte in the electrochemical devices.
format Conference or Workshop Item
author M. A., Saadiah
A. S., Samsudin
author_facet M. A., Saadiah
A. S., Samsudin
author_sort M. A., Saadiah
title Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3
title_short Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3
title_full Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3
title_fullStr Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3
title_full_unstemmed Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3
title_sort study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (cmc)/polyvinyl alcohol (pva) doped nh4no3
publisher AIP Publishing
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/23988/
http://umpir.ump.edu.my/id/eprint/23988/
http://umpir.ump.edu.my/id/eprint/23988/
http://umpir.ump.edu.my/id/eprint/23988/1/Study%20on%20ionic%20conduction%20of%20solid%20bio-polymer%20hybrid%20electrolytes%20based%20carboxymethyl%20cellulose%20%28CMC%29polyvinyl%20alcohol%20%28PVA%29%20doped%20NH4NO3.pdf
first_indexed 2023-09-18T22:36:08Z
last_indexed 2023-09-18T22:36:08Z
_version_ 1777416607717392384

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