Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp

Mixed Ni/Fe-base metal-organic framework (Ni/Fe-MOF) with different molar ratios of Ni 2+ /Fe 3+ have been successfully produced using an appropriate solvothermal router. Physicochemical properties of all samples were characterized using X-ray diffraction (XRD), Raman, field emission scanning electr...

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Main Authors:	Vo, Dai-Viet N., Nguyen, Vinh Huu, Nguyen, Trinh Duy, Bach, Long Giang, Hoang, Thai, Bui, Quynh Thi Phuong, Tran, Lam Dai, Nguyen, Chuong V., Do, Sy Trung
Format:	Article
Language:	English
Published:	MDPI 2018
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/23940/ http://umpir.ump.edu.my/id/eprint/23940/ http://umpir.ump.edu.my/id/eprint/23940/ http://umpir.ump.edu.my/id/eprint/23940/1/Effective%20photocatalytic%20activity%20of%20mixed%20NiFe-base%20metal-organic%20framework%20under%20a%20compact%20fluorescent%20daylight%20lamp.pdf

id	ump-23940
recordtype	eprints
spelling	ump-239402019-03-05T09:07:26Z http://umpir.ump.edu.my/id/eprint/23940/ Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp Vo, Dai-Viet N. Nguyen, Vinh Huu Nguyen, Trinh Duy Bach, Long Giang Hoang, Thai Bui, Quynh Thi Phuong Tran, Lam Dai Nguyen, Chuong V. Do, Sy Trung TP Chemical technology Mixed Ni/Fe-base metal-organic framework (Ni/Fe-MOF) with different molar ratios of Ni 2+ /Fe 3+ have been successfully produced using an appropriate solvothermal router. Physicochemical properties of all samples were characterized using X-ray diffraction (XRD), Raman, field emission scanning electron microscopes (FE-SEM), fourier-transform infrared spectroscopy (FT-IR), N 2 adsorption-desorption analysis, X-ray photoelectron spectroscopy (XPS), ultraviolet-visible diffuse reflectance spectra (UV-Vis DRS), and photoluminescence spectra (PL). The photocatalytic degradation performances of the photocatalysts were evaluated in the decomposition of rhodamine B (RhB) under a compact fluorescent daylight lamp. From XRD, IR, XPS, and Raman results, with the presence of mixed ion Fe 3+ and Ni 2+ , MIL-88B (MIL standing for Materials of Institut Lavoisier) crystals based on the mixed metal Fe 2 NiO cluster were formed, while MIL-53(Fe) was formed with the presence of single ion Fe 3+ . From UV-Vis DRS results, Ni/Fe-MOF samples exhibited the absorption spectrum up to the visible region, and then they showed the high photocatalytic activity under visible light irradiation. A Ni/Fe-MOF sample with a Ni 2+ /Fe 3+ molar ratio of 0.3 showed the highest photocatalytic degradation capacity of RhB, superior to that of the MIL-53(Fe) sample. The obtained result could be explained as a consequence of the large surface area with large pore volumes and pore size by the Ni 2+ incorporating into the MOF’s structure. In addition, a mixed metal Fe/Ni-based framework consisted of mixed-metal cluster Fe 2 NiO with an electron transfer effect and may enhance the photocatalytic performance. MDPI 2018-11 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23940/1/Effective%20photocatalytic%20activity%20of%20mixed%20NiFe-base%20metal-organic%20framework%20under%20a%20compact%20fluorescent%20daylight%20lamp.pdf Vo, Dai-Viet N. and Nguyen, Vinh Huu and Nguyen, Trinh Duy and Bach, Long Giang and Hoang, Thai and Bui, Quynh Thi Phuong and Tran, Lam Dai and Nguyen, Chuong V. and Do, Sy Trung (2018) Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp. Catalysts, 8 (11). pp. 1-20. ISSN 2073-4344 https://doi.org/10.3390/catal8110487 https://doi.org/10.3390/catal8110487
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Vo, Dai-Viet N. Nguyen, Vinh Huu Nguyen, Trinh Duy Bach, Long Giang Hoang, Thai Bui, Quynh Thi Phuong Tran, Lam Dai Nguyen, Chuong V. Do, Sy Trung Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp
description	Mixed Ni/Fe-base metal-organic framework (Ni/Fe-MOF) with different molar ratios of Ni 2+ /Fe 3+ have been successfully produced using an appropriate solvothermal router. Physicochemical properties of all samples were characterized using X-ray diffraction (XRD), Raman, field emission scanning electron microscopes (FE-SEM), fourier-transform infrared spectroscopy (FT-IR), N 2 adsorption-desorption analysis, X-ray photoelectron spectroscopy (XPS), ultraviolet-visible diffuse reflectance spectra (UV-Vis DRS), and photoluminescence spectra (PL). The photocatalytic degradation performances of the photocatalysts were evaluated in the decomposition of rhodamine B (RhB) under a compact fluorescent daylight lamp. From XRD, IR, XPS, and Raman results, with the presence of mixed ion Fe 3+ and Ni 2+ , MIL-88B (MIL standing for Materials of Institut Lavoisier) crystals based on the mixed metal Fe 2 NiO cluster were formed, while MIL-53(Fe) was formed with the presence of single ion Fe 3+ . From UV-Vis DRS results, Ni/Fe-MOF samples exhibited the absorption spectrum up to the visible region, and then they showed the high photocatalytic activity under visible light irradiation. A Ni/Fe-MOF sample with a Ni 2+ /Fe 3+ molar ratio of 0.3 showed the highest photocatalytic degradation capacity of RhB, superior to that of the MIL-53(Fe) sample. The obtained result could be explained as a consequence of the large surface area with large pore volumes and pore size by the Ni 2+ incorporating into the MOF’s structure. In addition, a mixed metal Fe/Ni-based framework consisted of mixed-metal cluster Fe 2 NiO with an electron transfer effect and may enhance the photocatalytic performance.
format	Article
author	Vo, Dai-Viet N. Nguyen, Vinh Huu Nguyen, Trinh Duy Bach, Long Giang Hoang, Thai Bui, Quynh Thi Phuong Tran, Lam Dai Nguyen, Chuong V. Do, Sy Trung
author_facet	Vo, Dai-Viet N. Nguyen, Vinh Huu Nguyen, Trinh Duy Bach, Long Giang Hoang, Thai Bui, Quynh Thi Phuong Tran, Lam Dai Nguyen, Chuong V. Do, Sy Trung
author_sort	Vo, Dai-Viet N.
title	Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp
title_short	Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp
title_full	Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp
title_fullStr	Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp
title_full_unstemmed	Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp
title_sort	effective photocatalytic activity of mixed ni/fe-base metal-organic framework under a compact fluorescent daylight lamp
publisher	MDPI
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/23940/ http://umpir.ump.edu.my/id/eprint/23940/ http://umpir.ump.edu.my/id/eprint/23940/ http://umpir.ump.edu.my/id/eprint/23940/1/Effective%20photocatalytic%20activity%20of%20mixed%20NiFe-base%20metal-organic%20framework%20under%20a%20compact%20fluorescent%20daylight%20lamp.pdf
first_indexed	2023-09-18T22:36:04Z
last_indexed	2023-09-18T22:36:04Z
_version_	1777416603925741568

Effective photocatalytic activity of mixed Ni/Fe-base metal-organic framework under a compact fluorescent daylight lamp

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