Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.

A unique core-shell fibrous silica zeolite HY (HY@KCC-1) catalyst with high surface area of 568 m2/g was successfully synthesized via a facile silica solvothermal procedure coupled with zeolite crystalseed crystallization, and subsequently investigated for n-dodecane hydroisomerization. Field Emissi...

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Main Authors:	Y., Gambo, A. A., Jalil, S., Triwahyono, S. M., Izan, A. A., Abdulrasheed, Mastura, Ibrahim, Herma Dina, Setiabudi
Format:	Conference or Workshop Item
Language:	English
Published:	2018
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/23849/ http://umpir.ump.edu.my/id/eprint/23849/1/25.%20Pt-promoted%20HY%40KCC-1%20as%20a%20highly%20selective%20catalyst.pdf

id	ump-23849
recordtype	eprints
spelling	ump-238492019-01-17T08:40:37Z http://umpir.ump.edu.my/id/eprint/23849/ Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation. Y., Gambo A. A., Jalil S., Triwahyono S. M., Izan A. A., Abdulrasheed Mastura, Ibrahim Herma Dina, Setiabudi TP Chemical technology A unique core-shell fibrous silica zeolite HY (HY@KCC-1) catalyst with high surface area of 568 m2/g was successfully synthesized via a facile silica solvothermal procedure coupled with zeolite crystalseed crystallization, and subsequently investigated for n-dodecane hydroisomerization. Field Emission Scanning Microscope (FESEM) combined with X-ray Diffraction (XRD) revealed the fibrous silica growth. Probing of the Brønsted (BAS) and Lewis (LAS) acid sites with 2,6-dimethylpyridine (2,6-DMP) via Fourier Transform Infrared Spectroscopy (FT-IR) revealed that Pt/HY@KCC-1 had abundant strong acid sites with improved accessibility relative to unmodified Pt/HY catalyst. The Pt/HY@KCC-1 has displayed complete n-dodecane conversion coupled with an incredibly enhanced isomer yield of 72 % at 350 oC, nearly two-fold higher than unmodified Pt/HY catalyst. Additionally, the unique morphology and increased mesopores on Pt/HY@KCC-1 led to the superb catalytic activity via enhanced acid site accessibility by bulky n-dodecane reactant molecules and easy desorption of product isomers prior to being cracked. Remarkably, Pt/HY@KCC-1 had an internal effectiveness factor (η) of unity, thus suggesting its potential application in hydroisomerization of higher hydrocarbons for enhancing fuel properties 2018-08 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23849/1/25.%20Pt-promoted%20HY%40KCC-1%20as%20a%20highly%20selective%20catalyst.pdf Y., Gambo and A. A., Jalil and S., Triwahyono and S. M., Izan and A. A., Abdulrasheed and Mastura, Ibrahim and Herma Dina, Setiabudi (2018) Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation. In: 4th International Conference Of Chemical Engineering And Industrial Biotechnology (ICCEIB 2018), 1-2 Aug 2018 , Seri Pacific Hotel, Kuala Lumpur. pp. 239-241..
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Y., Gambo A. A., Jalil S., Triwahyono S. M., Izan A. A., Abdulrasheed Mastura, Ibrahim Herma Dina, Setiabudi Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
description	A unique core-shell fibrous silica zeolite HY (HY@KCC-1) catalyst with high surface area of 568 m2/g was successfully synthesized via a facile silica solvothermal procedure coupled with zeolite crystalseed crystallization, and subsequently investigated for n-dodecane hydroisomerization. Field Emission Scanning Microscope (FESEM) combined with X-ray Diffraction (XRD) revealed the fibrous silica growth. Probing of the Brønsted (BAS) and Lewis (LAS) acid sites with 2,6-dimethylpyridine (2,6-DMP) via Fourier Transform Infrared Spectroscopy (FT-IR) revealed that Pt/HY@KCC-1 had abundant strong acid sites with improved accessibility relative to unmodified Pt/HY catalyst. The Pt/HY@KCC-1 has displayed complete n-dodecane conversion coupled with an incredibly enhanced isomer yield of 72 % at 350 oC, nearly two-fold higher than unmodified Pt/HY catalyst. Additionally, the unique morphology and increased mesopores on Pt/HY@KCC-1 led to the superb catalytic activity via enhanced acid site accessibility by bulky n-dodecane reactant molecules and easy desorption of product isomers prior to being cracked. Remarkably, Pt/HY@KCC-1 had an internal effectiveness factor (η) of unity, thus suggesting its potential application in hydroisomerization of higher hydrocarbons for enhancing fuel properties
format	Conference or Workshop Item
author	Y., Gambo A. A., Jalil S., Triwahyono S. M., Izan A. A., Abdulrasheed Mastura, Ibrahim Herma Dina, Setiabudi
author_facet	Y., Gambo A. A., Jalil S., Triwahyono S. M., Izan A. A., Abdulrasheed Mastura, Ibrahim Herma Dina, Setiabudi
author_sort	Y., Gambo
title	Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
title_short	Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
title_full	Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
title_fullStr	Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
title_full_unstemmed	Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
title_sort	pt-promoted hy@kcc-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/23849/ http://umpir.ump.edu.my/id/eprint/23849/1/25.%20Pt-promoted%20HY%40KCC-1%20as%20a%20highly%20selective%20catalyst.pdf
first_indexed	2023-09-18T22:35:54Z
last_indexed	2023-09-18T22:35:54Z
_version_	1777416593016356864

Pt-promoted HY@KCC-1 as a highly selective catalyst for hydroisomerization of n-dodecane with enhanced mass transfer limitation.

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