In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications

In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications

Herein, we report the preparation of porous carbon from palm kernel shell and loading of tin oxide‑cobalt oxide in its pores using a facile in-situ encapsulation synthesis strategy. The as-synthesized SnO2/Co3O4@C composite was characterized by powder X-ray diffraction, X-ray photoelectron spectrosc...

Full description

Bibliographic Details
Main Authors: Pal, Bhupender, Krishnan, Syam G., Vijayan, Bincy Lathakumary, Harilal, Midhun, Yang, Chun-Chen, Ezema, Fabian I., M. M., Yusoff, Rajan, Jose
Format: Article
Language:English
Published: Elsevier B.V. 2018
Subjects:
Q Science (General)
Online Access:http://umpir.ump.edu.my/id/eprint/23045/
http://umpir.ump.edu.my/id/eprint/23045/
http://umpir.ump.edu.my/id/eprint/23045/
http://umpir.ump.edu.my/id/eprint/23045/1/In%20situ%20encapsulation%20of%20tin%20oxide%20and%20cobalt%20oxide%20composite%20in%20porous%20carbon.pdf
id ump-23045
recordtype eprints
spelling ump-230452019-01-28T08:40:46Z http://umpir.ump.edu.my/id/eprint/23045/ In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications Pal, Bhupender Krishnan, Syam G. Vijayan, Bincy Lathakumary Harilal, Midhun Yang, Chun-Chen Ezema, Fabian I. M. M., Yusoff Rajan, Jose Q Science (General) Herein, we report the preparation of porous carbon from palm kernel shell and loading of tin oxide‑cobalt oxide in its pores using a facile in-situ encapsulation synthesis strategy. The as-synthesized SnO2/Co3O4@C composite was characterized by powder X-ray diffraction, X-ray photoelectron spectroscopy and field-emission scanning electron microscopy techniques. This composite was used as an electrode for supercapacitors. Electrochemical charge storage capabilities of the composite were measured using cyclic voltammetry, charge-discharge cycling and electrochemical impedance spectroscopy in aqueous 6 M KOH and 1 M Na2SO4 electrolytes. The SnO2/Co3O4@C composite showed over 70% higher specific capacitance (177 F g−1) than the pure porous carbon (106 F g−1) in 6 M KOH. Among these electrolytes, the composite exhibited an enhanced electrochemical performance in KOH electrolyte due to its smaller hydrated ion radius, high ionic mobility and lower equivalent series resistance than Na2SO4. Elsevier B.V. 2018-05 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23045/1/In%20situ%20encapsulation%20of%20tin%20oxide%20and%20cobalt%20oxide%20composite%20in%20porous%20carbon.pdf Pal, Bhupender and Krishnan, Syam G. and Vijayan, Bincy Lathakumary and Harilal, Midhun and Yang, Chun-Chen and Ezema, Fabian I. and M. M., Yusoff and Rajan, Jose (2018) In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications. Journal of Electroanalytical Chemistry, 817. pp. 217-225. ISSN 1572-6657 https://www.sciencedirect.com/science/article/pii/S157266571830273X https://doi.org/10.1016/j.jelechem.2018.04.019
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Pal, Bhupender
Krishnan, Syam G.
Vijayan, Bincy Lathakumary
Harilal, Midhun
Yang, Chun-Chen
Ezema, Fabian I.
M. M., Yusoff
Rajan, Jose
In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
description Herein, we report the preparation of porous carbon from palm kernel shell and loading of tin oxide‑cobalt oxide in its pores using a facile in-situ encapsulation synthesis strategy. The as-synthesized SnO2/Co3O4@C composite was characterized by powder X-ray diffraction, X-ray photoelectron spectroscopy and field-emission scanning electron microscopy techniques. This composite was used as an electrode for supercapacitors. Electrochemical charge storage capabilities of the composite were measured using cyclic voltammetry, charge-discharge cycling and electrochemical impedance spectroscopy in aqueous 6 M KOH and 1 M Na2SO4 electrolytes. The SnO2/Co3O4@C composite showed over 70% higher specific capacitance (177 F g−1) than the pure porous carbon (106 F g−1) in 6 M KOH. Among these electrolytes, the composite exhibited an enhanced electrochemical performance in KOH electrolyte due to its smaller hydrated ion radius, high ionic mobility and lower equivalent series resistance than Na2SO4.
format Article
author Pal, Bhupender
Krishnan, Syam G.
Vijayan, Bincy Lathakumary
Harilal, Midhun
Yang, Chun-Chen
Ezema, Fabian I.
M. M., Yusoff
Rajan, Jose
author_facet Pal, Bhupender
Krishnan, Syam G.
Vijayan, Bincy Lathakumary
Harilal, Midhun
Yang, Chun-Chen
Ezema, Fabian I.
M. M., Yusoff
Rajan, Jose
author_sort Pal, Bhupender
title In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
title_short In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
title_full In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
title_fullStr In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
title_full_unstemmed In situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
title_sort in situ encapsulation of tin oxide and cobalt oxide composite in porous carbon for high-performance energy storage applications
publisher Elsevier B.V.
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/23045/
http://umpir.ump.edu.my/id/eprint/23045/
http://umpir.ump.edu.my/id/eprint/23045/
http://umpir.ump.edu.my/id/eprint/23045/1/In%20situ%20encapsulation%20of%20tin%20oxide%20and%20cobalt%20oxide%20composite%20in%20porous%20carbon.pdf
first_indexed 2023-09-18T22:34:22Z
last_indexed 2023-09-18T22:34:22Z
_version_ 1777416496875569152

Similar Items