Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions

A well-known adsorbent, poly(amidoxime) ligand, was prepared from polyacrylonitrile (PAN) grafted kenaf cellulose, and subsequent characterization was performed by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM) and inductively coupled plasma mass...

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Main Authors: Rahman, Md. Lutfor, Mohd Sani, Sarjadi, Sazmal Effendi, Arshad, M. M., Yusoff, Sarkar, Shaheen M., Musta, Baba
Format: Article
Language:English
Published: Springer 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/23034/
http://umpir.ump.edu.my/id/eprint/23034/
http://umpir.ump.edu.my/id/eprint/23034/
http://umpir.ump.edu.my/id/eprint/23034/1/Kenaf%20cellulose-based%20poly%28amidoxime%29%20ligand%20for%20adsorption%20of%20rare%20earth%20ions.pdf
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spelling ump-230342019-02-25T03:49:27Z http://umpir.ump.edu.my/id/eprint/23034/ Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions Rahman, Md. Lutfor Mohd Sani, Sarjadi Sazmal Effendi, Arshad M. M., Yusoff Sarkar, Shaheen M. Musta, Baba Q Science (General) A well-known adsorbent, poly(amidoxime) ligand, was prepared from polyacrylonitrile (PAN) grafted kenaf cellulose, and subsequent characterization was performed by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM) and inductively coupled plasma mass spectrometry (ICP-MS). The adsorption capacities of the prepared ligand for rare earth metals are found to be excellent, with adsorptions of La3+, Ce3+, Pr3+, Gd3+ and Nd3+ experimentally determined to be 262, 255, 244, 241 and 233 mg·g−1, respectively, at pH 6. The experimental values of the adsorption of rare earth metals are well matched with the pseudo-second-order rate equation. The reusability of the adsorbent is examined for seven cycles of sorption/desorption, demonstrating that the proposed adsorbent could be reused for over seven cycles without any significant loss in the original removal capability of the ligand. Springer 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23034/1/Kenaf%20cellulose-based%20poly%28amidoxime%29%20ligand%20for%20adsorption%20of%20rare%20earth%20ions.pdf Rahman, Md. Lutfor and Mohd Sani, Sarjadi and Sazmal Effendi, Arshad and M. M., Yusoff and Sarkar, Shaheen M. and Musta, Baba (2019) Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions. Rare Metals, 38 (3). pp. 259-269. ISSN 1867-7185 https://link.springer.com/article/10.1007/s12598-018-1061-7 https://doi.org/10.1007/s12598-018-1061-7
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Rahman, Md. Lutfor
Mohd Sani, Sarjadi
Sazmal Effendi, Arshad
M. M., Yusoff
Sarkar, Shaheen M.
Musta, Baba
Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
description A well-known adsorbent, poly(amidoxime) ligand, was prepared from polyacrylonitrile (PAN) grafted kenaf cellulose, and subsequent characterization was performed by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM) and inductively coupled plasma mass spectrometry (ICP-MS). The adsorption capacities of the prepared ligand for rare earth metals are found to be excellent, with adsorptions of La3+, Ce3+, Pr3+, Gd3+ and Nd3+ experimentally determined to be 262, 255, 244, 241 and 233 mg·g−1, respectively, at pH 6. The experimental values of the adsorption of rare earth metals are well matched with the pseudo-second-order rate equation. The reusability of the adsorbent is examined for seven cycles of sorption/desorption, demonstrating that the proposed adsorbent could be reused for over seven cycles without any significant loss in the original removal capability of the ligand.
format Article
author Rahman, Md. Lutfor
Mohd Sani, Sarjadi
Sazmal Effendi, Arshad
M. M., Yusoff
Sarkar, Shaheen M.
Musta, Baba
author_facet Rahman, Md. Lutfor
Mohd Sani, Sarjadi
Sazmal Effendi, Arshad
M. M., Yusoff
Sarkar, Shaheen M.
Musta, Baba
author_sort Rahman, Md. Lutfor
title Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
title_short Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
title_full Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
title_fullStr Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
title_full_unstemmed Kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
title_sort kenaf cellulose-based poly(amidoxime) ligand for adsorption of rare earth ions
publisher Springer
publishDate 2019
url http://umpir.ump.edu.my/id/eprint/23034/
http://umpir.ump.edu.my/id/eprint/23034/
http://umpir.ump.edu.my/id/eprint/23034/
http://umpir.ump.edu.my/id/eprint/23034/1/Kenaf%20cellulose-based%20poly%28amidoxime%29%20ligand%20for%20adsorption%20of%20rare%20earth%20ions.pdf
first_indexed 2023-09-18T22:34:21Z
last_indexed 2023-09-18T22:34:21Z
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