Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites

Recycling of atmospheric CO2, the ultimate by-product of all processes involving oxidation of carbon compounds, for use as fuel is one of the most promising alternatives to combat global warming and energy crisis. Photocatalysis (PC) is a very promising technique for reducing CO2 into hydrocarbon fu...

Full description

Bibliographic Details
Main Authors: Khan, Maksudur R., Md. Rezaul, Karim, Huei, Ruey Ong, Hamidah, Abdullah, Cheng, C. K.
Format: Conference or Workshop Item
Language:English
English
Published: 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/22119/
http://umpir.ump.edu.my/id/eprint/22119/1/34.%20Photoelectrochemical%20reduction%20of%20carbon%20dioxide%20over%20copper.pdf
http://umpir.ump.edu.my/id/eprint/22119/2/34.1%20Photoelectrochemical%20reduction%20of%20carbon%20dioxide%20over%20copper.pdf
id ump-22119
recordtype eprints
spelling ump-221192018-12-07T01:42:51Z http://umpir.ump.edu.my/id/eprint/22119/ Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites Khan, Maksudur R. Md. Rezaul, Karim Huei, Ruey Ong Hamidah, Abdullah Cheng, C. K. TP Chemical technology Recycling of atmospheric CO2, the ultimate by-product of all processes involving oxidation of carbon compounds, for use as fuel is one of the most promising alternatives to combat global warming and energy crisis. Photocatalysis (PC) is a very promising technique for reducing CO2 into hydrocarbon fuels[1].The use of photon energy to mimic the photosynthesis process requires photoresponsive materials that can efficiently interact with light, yielding high-energy photogenerated electrons capable of reducing CO2 to produce fuel. To produce hydrocarbons or oxygenated hydrocarbons from CO2 requires proton coupled multiple electron path ways which suffer from slow kinetics, poor product selectivity, and mechanistic complexity[2]. The electrochemical reduction of CO2 is another important route for the conversion of CO2 to chemicals requiring substantial amount of electrical energy. Photoelectrocatalyticapproachintegrates the electrocatalytic and the photocatalytic methods where solar energy can significantly lower the applied voltage, thusdecreasing the electricity consumption[3].Moreover, the bias potential effectively reduces the e-/h+ recombination rate in the photocatalyst leading to higher quantum efficiency.Among photocatalysts, visible light responsive materials are of major interest as it could use solar irradiation as light source. In the present paper, we report the preparationand characterization of graphene oxide (GO) modified CuFe2O4 nanoparticles and their activity towards photoelectrochemical (PEC) reduction of CO2in aqueous solutionunder visible light irradiation. 2018-04 Conference or Workshop Item NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/22119/1/34.%20Photoelectrochemical%20reduction%20of%20carbon%20dioxide%20over%20copper.pdf pdf en http://umpir.ump.edu.my/id/eprint/22119/2/34.1%20Photoelectrochemical%20reduction%20of%20carbon%20dioxide%20over%20copper.pdf Khan, Maksudur R. and Md. Rezaul, Karim and Huei, Ruey Ong and Hamidah, Abdullah and Cheng, C. K. (2018) Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites. In: 23rd International Congress Of Chemical And Process Engineering CHISA 2018, 25 - 29 Ogos 2018 , Prague. pp. 1-2.. (Unpublished)
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
English
topic TP Chemical technology
spellingShingle TP Chemical technology
Khan, Maksudur R.
Md. Rezaul, Karim
Huei, Ruey Ong
Hamidah, Abdullah
Cheng, C. K.
Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
description Recycling of atmospheric CO2, the ultimate by-product of all processes involving oxidation of carbon compounds, for use as fuel is one of the most promising alternatives to combat global warming and energy crisis. Photocatalysis (PC) is a very promising technique for reducing CO2 into hydrocarbon fuels[1].The use of photon energy to mimic the photosynthesis process requires photoresponsive materials that can efficiently interact with light, yielding high-energy photogenerated electrons capable of reducing CO2 to produce fuel. To produce hydrocarbons or oxygenated hydrocarbons from CO2 requires proton coupled multiple electron path ways which suffer from slow kinetics, poor product selectivity, and mechanistic complexity[2]. The electrochemical reduction of CO2 is another important route for the conversion of CO2 to chemicals requiring substantial amount of electrical energy. Photoelectrocatalyticapproachintegrates the electrocatalytic and the photocatalytic methods where solar energy can significantly lower the applied voltage, thusdecreasing the electricity consumption[3].Moreover, the bias potential effectively reduces the e-/h+ recombination rate in the photocatalyst leading to higher quantum efficiency.Among photocatalysts, visible light responsive materials are of major interest as it could use solar irradiation as light source. In the present paper, we report the preparationand characterization of graphene oxide (GO) modified CuFe2O4 nanoparticles and their activity towards photoelectrochemical (PEC) reduction of CO2in aqueous solutionunder visible light irradiation.
format Conference or Workshop Item
author Khan, Maksudur R.
Md. Rezaul, Karim
Huei, Ruey Ong
Hamidah, Abdullah
Cheng, C. K.
author_facet Khan, Maksudur R.
Md. Rezaul, Karim
Huei, Ruey Ong
Hamidah, Abdullah
Cheng, C. K.
author_sort Khan, Maksudur R.
title Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
title_short Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
title_full Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
title_fullStr Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
title_full_unstemmed Photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
title_sort photoelectrochemical reduction of carbon dioxide over copper ferrite - graphene oxide composites
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/22119/
http://umpir.ump.edu.my/id/eprint/22119/1/34.%20Photoelectrochemical%20reduction%20of%20carbon%20dioxide%20over%20copper.pdf
http://umpir.ump.edu.my/id/eprint/22119/2/34.1%20Photoelectrochemical%20reduction%20of%20carbon%20dioxide%20over%20copper.pdf
first_indexed 2023-09-18T22:32:45Z
last_indexed 2023-09-18T22:32:45Z
_version_ 1777416395124899840