Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]

In this research, biodiesel was produced by transesterification of rubber seed oil with methanol catalyzed by three types of alumina-supported catalyst. The catalysts were Al2O3 -CaO, Al2O3 -KI, and Al2O3 -CaO-KI. The catalysts were prepared by heating a mixture of alumina and the corresponding salt...

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Main Authors: Abdul Razak, Zainal Kifli, Shahida Hanum, Kamarullah, Siti Norhafiza, Mohd Khazaai, Gaanty Pragas, Maniam
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/21626/
http://umpir.ump.edu.my/id/eprint/21626/
http://umpir.ump.edu.my/id/eprint/21626/
http://umpir.ump.edu.my/id/eprint/21626/1/Synthesis%20of%20alumina-cao-ki%20catalyst%20for%20the%20production%20of%20biodiesel%20from%20rubber%20seed%20oil.pdf
id ump-21626
recordtype eprints
spelling ump-216262018-09-14T04:23:46Z http://umpir.ump.edu.my/id/eprint/21626/ Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah] Abdul Razak, Zainal Kifli Shahida Hanum, Kamarullah Siti Norhafiza, Mohd Khazaai Gaanty Pragas, Maniam Q Science (General) In this research, biodiesel was produced by transesterification of rubber seed oil with methanol catalyzed by three types of alumina-supported catalyst. The catalysts were Al2O3 -CaO, Al2O3 -KI, and Al2O3 -CaO-KI. The catalysts were prepared by heating a mixture of alumina and the corresponding salt in a furnace at 700 oC. Transesterification reactions were carried out at 65 °C using a mixture of rubber seed oil: methanol of mass ratio 1:9 with different catalyst loadings between 0 and 3.5%. The optimum catalyst loading was at 2.0% for all types of catalyst and Al2O3 -CaO-KI gave the highest yield (91.6%) followed by Al2O3 -KI (90.7%) and Al2O3 -CaO (63.5%). The catalyst Al2O3 -CaO-KI also gave high biodiesel yields over a wider range of catalyst loadings compared to the other two catalysts. Reactions were also carried out at different temperatures (25, 40 and 65°C). It was observed that the yield increased drastically with increasing reaction temperature. At all temperatures the Al2O3 -CaO-KI catalyst gave the highest yield. Therefore, the study showed that among these three catalysts the most productive was Al2O3 -CaO-KI, (100:30:35). Universiti Kebangsaan Malaysia 2018-04 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/21626/1/Synthesis%20of%20alumina-cao-ki%20catalyst%20for%20the%20production%20of%20biodiesel%20from%20rubber%20seed%20oil.pdf Abdul Razak, Zainal Kifli and Shahida Hanum, Kamarullah and Siti Norhafiza, Mohd Khazaai and Gaanty Pragas, Maniam (2018) Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]. Malaysian Journal of Analytical Sciences, 22 (2). pp. 279-285. ISSN 1394-2506 http://www.ukm.my/mjas/v22_n2/pdf/ZainalKifli_22_2_13.pdf 10.17576/mjas-2018-2202-13
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Abdul Razak, Zainal Kifli
Shahida Hanum, Kamarullah
Siti Norhafiza, Mohd Khazaai
Gaanty Pragas, Maniam
Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
description In this research, biodiesel was produced by transesterification of rubber seed oil with methanol catalyzed by three types of alumina-supported catalyst. The catalysts were Al2O3 -CaO, Al2O3 -KI, and Al2O3 -CaO-KI. The catalysts were prepared by heating a mixture of alumina and the corresponding salt in a furnace at 700 oC. Transesterification reactions were carried out at 65 °C using a mixture of rubber seed oil: methanol of mass ratio 1:9 with different catalyst loadings between 0 and 3.5%. The optimum catalyst loading was at 2.0% for all types of catalyst and Al2O3 -CaO-KI gave the highest yield (91.6%) followed by Al2O3 -KI (90.7%) and Al2O3 -CaO (63.5%). The catalyst Al2O3 -CaO-KI also gave high biodiesel yields over a wider range of catalyst loadings compared to the other two catalysts. Reactions were also carried out at different temperatures (25, 40 and 65°C). It was observed that the yield increased drastically with increasing reaction temperature. At all temperatures the Al2O3 -CaO-KI catalyst gave the highest yield. Therefore, the study showed that among these three catalysts the most productive was Al2O3 -CaO-KI, (100:30:35).
format Article
author Abdul Razak, Zainal Kifli
Shahida Hanum, Kamarullah
Siti Norhafiza, Mohd Khazaai
Gaanty Pragas, Maniam
author_facet Abdul Razak, Zainal Kifli
Shahida Hanum, Kamarullah
Siti Norhafiza, Mohd Khazaai
Gaanty Pragas, Maniam
author_sort Abdul Razak, Zainal Kifli
title Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
title_short Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
title_full Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
title_fullStr Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
title_full_unstemmed Synthesis of alumina-CaO-KI catalyst for the production of biodiesel from rubber seed oil [Sintesis mangkin alumina-CaO-KI untuk penghasilan biodiesel daripada minyak biji getah]
title_sort synthesis of alumina-cao-ki catalyst for the production of biodiesel from rubber seed oil [sintesis mangkin alumina-cao-ki untuk penghasilan biodiesel daripada minyak biji getah]
publisher Universiti Kebangsaan Malaysia
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/21626/
http://umpir.ump.edu.my/id/eprint/21626/
http://umpir.ump.edu.my/id/eprint/21626/
http://umpir.ump.edu.my/id/eprint/21626/1/Synthesis%20of%20alumina-cao-ki%20catalyst%20for%20the%20production%20of%20biodiesel%20from%20rubber%20seed%20oil.pdf
first_indexed 2023-09-18T22:31:49Z
last_indexed 2023-09-18T22:31:49Z
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