Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization

Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization

Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized b...

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Main Authors: Norhayati, Abdullah, M. Z., Yahya, R., Mahmod
Format: Article
Language:English
Published: Bangladesh University of Engineering and Technology 2017
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/20601/
http://umpir.ump.edu.my/id/eprint/20601/
http://umpir.ump.edu.my/id/eprint/20601/
http://umpir.ump.edu.my/id/eprint/20601/1/Comparative%20Study%20of%20Strong%20Anion%20Exchange%20Hypercrosslinked%20Poly%28HEMA-co-EGDMA-co-VBC%29%20and%20Strong%20Anion%20Exchange%20Poly%28Styrene-Co-EGDMA-Covbc%29-%20Synthesis%20and%20Characterization.pdf
id ump-20601
recordtype eprints
spelling ump-206012018-02-23T01:10:35Z http://umpir.ump.edu.my/id/eprint/20601/ Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization Norhayati, Abdullah M. Z., Yahya R., Mahmod TP Chemical technology Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized by SEM, FTIR, BET and elemental analysis. SEM results showed that there was no significant change of the particles shape after amination reaction for both strong anion exchange hypercrosslinked PHEV and strong anion exchange hypercrosslinked PSEV. Specific surface area (SSA) of strong anion exchange hypercrosslinked PHEV increase from 1035 m2/g to 1090 m2/g when amination reaction take place. However, SSA of strong anion exchange hypercrosslinked PHEV decreased from 124 m2/g to 27 m2/g. From FTIR spectra, significant drop occurred at 1265 cm-1 band after amination reaction of strong anion exchange hypercrosslinked PSEV but SSA of strong anion exchange hypercrosslinkedPHEV showed slightly significant drop. Elemental analysis showed that nitrogen content of strong anion exchange hypercrosslinked PHEV significantly increase from 0.10% to 1.46% resulted to high IEC value. Meanwhile, nitrogen content in strong anion exchange hypercrosslinked PSEV only showed small increment in nitrogen content from 0.36% to 0.63% led to low IEC value. Bangladesh University of Engineering and Technology 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/20601/1/Comparative%20Study%20of%20Strong%20Anion%20Exchange%20Hypercrosslinked%20Poly%28HEMA-co-EGDMA-co-VBC%29%20and%20Strong%20Anion%20Exchange%20Poly%28Styrene-Co-EGDMA-Covbc%29-%20Synthesis%20and%20Characterization.pdf Norhayati, Abdullah and M. Z., Yahya and R., Mahmod (2017) Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization. Chemical Engineering Research Bulletin, 19 (Special). pp. 96-101. ISSN 0379-7678 (Print); 2072-9510 (Online) https://www.banglajol.info/index.php/CERB/article/view/33802 DOI: http://dx.doi.org/10.3329/cerb.v19i0.33802
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Norhayati, Abdullah
M. Z., Yahya
R., Mahmod
Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
description Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized by SEM, FTIR, BET and elemental analysis. SEM results showed that there was no significant change of the particles shape after amination reaction for both strong anion exchange hypercrosslinked PHEV and strong anion exchange hypercrosslinked PSEV. Specific surface area (SSA) of strong anion exchange hypercrosslinked PHEV increase from 1035 m2/g to 1090 m2/g when amination reaction take place. However, SSA of strong anion exchange hypercrosslinked PHEV decreased from 124 m2/g to 27 m2/g. From FTIR spectra, significant drop occurred at 1265 cm-1 band after amination reaction of strong anion exchange hypercrosslinked PSEV but SSA of strong anion exchange hypercrosslinkedPHEV showed slightly significant drop. Elemental analysis showed that nitrogen content of strong anion exchange hypercrosslinked PHEV significantly increase from 0.10% to 1.46% resulted to high IEC value. Meanwhile, nitrogen content in strong anion exchange hypercrosslinked PSEV only showed small increment in nitrogen content from 0.36% to 0.63% led to low IEC value.
format Article
author Norhayati, Abdullah
M. Z., Yahya
R., Mahmod
author_facet Norhayati, Abdullah
M. Z., Yahya
R., Mahmod
author_sort Norhayati, Abdullah
title Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
title_short Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
title_full Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
title_fullStr Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
title_full_unstemmed Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
title_sort comparative study of strong anion exchange hypercrosslinked poly(hema-co-egdma-co-vbc) and strong anion exchange poly(styrene-co-egdma-co-vbc): synthesis and characterization
publisher Bangladesh University of Engineering and Technology
publishDate 2017
url http://umpir.ump.edu.my/id/eprint/20601/
http://umpir.ump.edu.my/id/eprint/20601/
http://umpir.ump.edu.my/id/eprint/20601/
http://umpir.ump.edu.my/id/eprint/20601/1/Comparative%20Study%20of%20Strong%20Anion%20Exchange%20Hypercrosslinked%20Poly%28HEMA-co-EGDMA-co-VBC%29%20and%20Strong%20Anion%20Exchange%20Poly%28Styrene-Co-EGDMA-Covbc%29-%20Synthesis%20and%20Characterization.pdf
first_indexed 2023-09-18T22:29:48Z
last_indexed 2023-09-18T22:29:48Z
_version_ 1777416209660116992

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