Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion

Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion

Recent study claimed that forward osmosis (FO) process could handle the fouling problem due it driven force based on natural osmotic pressure. However, researchers observed that FO membrane had problem with reverse solute diffusion (RSD) of draw solution. Therefore, FO membrane properties must be im...

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Main Authors: Suriani, Husaini, Mazrul Nizam, Abu Seman
Format: Article
Language:English
Published: Bangladesh University of Engineering and Technology 2017
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/20600/
http://umpir.ump.edu.my/id/eprint/20600/
http://umpir.ump.edu.my/id/eprint/20600/
http://umpir.ump.edu.my/id/eprint/20600/1/Performance%20of%20Layer-By-Layer%20%28LbL%29%20Polyelectrolyte%20Forward%20Osmosis%20Membrane%20for%20Humic%20Acid%20Removal%20and%20Reverse%20Solute%20Diffusion.pdf
id ump-20600
recordtype eprints
spelling ump-206002018-02-23T01:16:28Z http://umpir.ump.edu.my/id/eprint/20600/ Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion Suriani, Husaini Mazrul Nizam, Abu Seman TP Chemical technology Recent study claimed that forward osmosis (FO) process could handle the fouling problem due it driven force based on natural osmotic pressure. However, researchers observed that FO membrane had problem with reverse solute diffusion (RSD) of draw solution. Therefore, FO membrane properties must be improved either physically or chemically in order to overcome this problem. Among all, surface modification approach has been acknowledged as a best technique to alter the membrane properties without significantly change the bulk membrane properties. In this study, polyelectrolyte FO membrane has been produced through Layer by Layer (LbL) deposition method by using Poly (diallyl-dimethylammoniumchloride), PDADMAC and Poly (sodium 4-styrene-sulfonate), PSS as an active monomers. Humic acid (HA) as part of Natural Organic Matter constituents was used as the feed solution and NaCl as a draw solution. The chemical structure and morphology of the FO membrane were characterized by FTIR and FESEM, respectively. From this study, the highest water flux and humic acid rejection were achieved at 2.5M of draw solution with value of 2.56 L/m².h and 99%, respectively. In general, the water flux increases as the concentration of draw solutions were increased. However, it was observed that reverse salt diffusion (RSD) become worse at higher concentration of draw solution. Bangladesh University of Engineering and Technology 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/20600/1/Performance%20of%20Layer-By-Layer%20%28LbL%29%20Polyelectrolyte%20Forward%20Osmosis%20Membrane%20for%20Humic%20Acid%20Removal%20and%20Reverse%20Solute%20Diffusion.pdf Suriani, Husaini and Mazrul Nizam, Abu Seman (2017) Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion. Chemical Engineering Research Bulletin, 19. pp. 75-79. ISSN 0379-7678 (Print); 2072-9510 (Online) https://www.banglajol.info/index.php/CERB/article/view/33799 DOI: http://dx.doi.org/10.3329/cerb.v19i0.33799
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Suriani, Husaini
Mazrul Nizam, Abu Seman
Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion
description Recent study claimed that forward osmosis (FO) process could handle the fouling problem due it driven force based on natural osmotic pressure. However, researchers observed that FO membrane had problem with reverse solute diffusion (RSD) of draw solution. Therefore, FO membrane properties must be improved either physically or chemically in order to overcome this problem. Among all, surface modification approach has been acknowledged as a best technique to alter the membrane properties without significantly change the bulk membrane properties. In this study, polyelectrolyte FO membrane has been produced through Layer by Layer (LbL) deposition method by using Poly (diallyl-dimethylammoniumchloride), PDADMAC and Poly (sodium 4-styrene-sulfonate), PSS as an active monomers. Humic acid (HA) as part of Natural Organic Matter constituents was used as the feed solution and NaCl as a draw solution. The chemical structure and morphology of the FO membrane were characterized by FTIR and FESEM, respectively. From this study, the highest water flux and humic acid rejection were achieved at 2.5M of draw solution with value of 2.56 L/m².h and 99%, respectively. In general, the water flux increases as the concentration of draw solutions were increased. However, it was observed that reverse salt diffusion (RSD) become worse at higher concentration of draw solution.
format Article
author Suriani, Husaini
Mazrul Nizam, Abu Seman
author_facet Suriani, Husaini
Mazrul Nizam, Abu Seman
author_sort Suriani, Husaini
title Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion
title_short Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion
title_full Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion
title_fullStr Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion
title_full_unstemmed Performance of Layer-By-Layer (LbL) Polyelectrolyte Forward Osmosis Membrane for Humic Acid Removal and Reverse Solute Diffusion
title_sort performance of layer-by-layer (lbl) polyelectrolyte forward osmosis membrane for humic acid removal and reverse solute diffusion
publisher Bangladesh University of Engineering and Technology
publishDate 2017
url http://umpir.ump.edu.my/id/eprint/20600/
http://umpir.ump.edu.my/id/eprint/20600/
http://umpir.ump.edu.my/id/eprint/20600/
http://umpir.ump.edu.my/id/eprint/20600/1/Performance%20of%20Layer-By-Layer%20%28LbL%29%20Polyelectrolyte%20Forward%20Osmosis%20Membrane%20for%20Humic%20Acid%20Removal%20and%20Reverse%20Solute%20Diffusion.pdf
first_indexed 2023-09-18T22:29:48Z
last_indexed 2023-09-18T22:29:48Z
_version_ 1777416209513316352

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