Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach

In the present study, hydrogen production from palm oil mill effluent (POME) was investigated with the incorporation of nanoparticles (NPs) comprising of nickel (NiO) and cobalt oxides (CoO). The NPs of NiO and CoO were prepared using hydrothermal method and were further applied to analyse, their ef...

Full description

Bibliographic Details
Main Authors: Puranjan, Mishra, Thakur, Sveta, Mahapatra, Durga Madhab, Zularisam, A. W., Liu, Hong, Singh, Lakhveer
Format: Article
Language:English
Published: Elsevier 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/20497/
http://umpir.ump.edu.my/id/eprint/20497/
http://umpir.ump.edu.my/id/eprint/20497/
http://umpir.ump.edu.my/id/eprint/20497/1/ftech-2017-zularisam-Impacts%20of%20nano-metal%20oxides%20on%20hydrogen1.pdf
id ump-20497
recordtype eprints
spelling ump-204972019-09-10T02:40:32Z http://umpir.ump.edu.my/id/eprint/20497/ Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach Puranjan, Mishra Thakur, Sveta Mahapatra, Durga Madhab Zularisam, A. W. Liu, Hong Singh, Lakhveer QD Chemistry In the present study, hydrogen production from palm oil mill effluent (POME) was investigated with the incorporation of nanoparticles (NPs) comprising of nickel (NiO) and cobalt oxides (CoO). The NPs of NiO and CoO were prepared using hydrothermal method and were further applied to analyse, their effect on hydrogen production. The results demonstrated that, a maxima volumetric hydrogen production rate of 21 ml H2/L-POME/h with the hydrogen yield of 0.563 L H2/g-CODremoved was obtained with 1.5 mg/L concentration of NiO NPs. On the other hand, the addition of CoO NPs produced maximum volumetric hydrogen production rate of 18 ml H2/L-POME/h with a hydrogen yield of 0.487 L H2/g-CODremoved with 1.0 mg/L of CoO NPs. Results showed that addition of optimal concentration of NiO and CoO NPs to the POME enhances the hydrogen yield by 1.51 and 1.67 fold respectively. Besides, this addition of NiO and CoO enhanced the COD removal efficiency by 15 and 10% respectively as compared to an un-additive NPs POME. The toxicity of NPs was also tested using bacterial viability test, which revealed that application of 3.0 mg/L of NiO and CoO NPs to modified Luria-Bertani (LB) medium had 63% and 83% reduction in bacterial cell growth. The results concluded that supplementation of NiO and CoO NPs under an optimal range to the wastewater can improve the hydrogen productivity. Elsevier 2018 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/20497/1/ftech-2017-zularisam-Impacts%20of%20nano-metal%20oxides%20on%20hydrogen1.pdf Puranjan, Mishra and Thakur, Sveta and Mahapatra, Durga Madhab and Zularisam, A. W. and Liu, Hong and Singh, Lakhveer (2018) Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach. International Journal of Hydrogen Energy, 43 (5). pp. 2666-2676. ISSN 0360-3199 https://doi.org/10.1016/j.ijhydene.2017.12.108 doi: 10.1016/j.ijhydene.2017.12.108
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Puranjan, Mishra
Thakur, Sveta
Mahapatra, Durga Madhab
Zularisam, A. W.
Liu, Hong
Singh, Lakhveer
Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach
description In the present study, hydrogen production from palm oil mill effluent (POME) was investigated with the incorporation of nanoparticles (NPs) comprising of nickel (NiO) and cobalt oxides (CoO). The NPs of NiO and CoO were prepared using hydrothermal method and were further applied to analyse, their effect on hydrogen production. The results demonstrated that, a maxima volumetric hydrogen production rate of 21 ml H2/L-POME/h with the hydrogen yield of 0.563 L H2/g-CODremoved was obtained with 1.5 mg/L concentration of NiO NPs. On the other hand, the addition of CoO NPs produced maximum volumetric hydrogen production rate of 18 ml H2/L-POME/h with a hydrogen yield of 0.487 L H2/g-CODremoved with 1.0 mg/L of CoO NPs. Results showed that addition of optimal concentration of NiO and CoO NPs to the POME enhances the hydrogen yield by 1.51 and 1.67 fold respectively. Besides, this addition of NiO and CoO enhanced the COD removal efficiency by 15 and 10% respectively as compared to an un-additive NPs POME. The toxicity of NPs was also tested using bacterial viability test, which revealed that application of 3.0 mg/L of NiO and CoO NPs to modified Luria-Bertani (LB) medium had 63% and 83% reduction in bacterial cell growth. The results concluded that supplementation of NiO and CoO NPs under an optimal range to the wastewater can improve the hydrogen productivity.
format Article
author Puranjan, Mishra
Thakur, Sveta
Mahapatra, Durga Madhab
Zularisam, A. W.
Liu, Hong
Singh, Lakhveer
author_facet Puranjan, Mishra
Thakur, Sveta
Mahapatra, Durga Madhab
Zularisam, A. W.
Liu, Hong
Singh, Lakhveer
author_sort Puranjan, Mishra
title Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach
title_short Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach
title_full Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach
title_fullStr Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach
title_full_unstemmed Impacts of Nano-Metal Oxides on Hydrogen Production in Anaerobic Digestion of Palm Oil Mill Effluent - A Novel Approach
title_sort impacts of nano-metal oxides on hydrogen production in anaerobic digestion of palm oil mill effluent - a novel approach
publisher Elsevier
publishDate 2018
url http://umpir.ump.edu.my/id/eprint/20497/
http://umpir.ump.edu.my/id/eprint/20497/
http://umpir.ump.edu.my/id/eprint/20497/
http://umpir.ump.edu.my/id/eprint/20497/1/ftech-2017-zularisam-Impacts%20of%20nano-metal%20oxides%20on%20hydrogen1.pdf
first_indexed 2023-09-18T22:29:35Z
last_indexed 2023-09-18T22:29:35Z
_version_ 1777416195817865216