Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite

Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphe...

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Main Authors:	Anis Sakinah, Zainal Abidin, Kamal, Yusoh, Saidatul Shima, Jamari, Abu Hannifa, Abdullah, Zulhelmi, Ismail
Format:	Article
Language:	English English
Published:	Springer Berlin Heidelberg 2018
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/19847/ http://umpir.ump.edu.my/id/eprint/19847/ http://umpir.ump.edu.my/id/eprint/19847/ http://umpir.ump.edu.my/id/eprint/19847/1/Surface%20functionalization%20of%20graphene%20oxide1.pdf http://umpir.ump.edu.my/id/eprint/19847/2/Surface%20functionalization%20of%20graphene%20oxide.pdf

id	ump-19847
recordtype	eprints
spelling	ump-198472018-08-08T07:13:34Z http://umpir.ump.edu.my/id/eprint/19847/ Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite Anis Sakinah, Zainal Abidin Kamal, Yusoh Saidatul Shima, Jamari Abu Hannifa, Abdullah Zulhelmi, Ismail TP Chemical technology Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphene oxide/octadecylamine (GOODA) nanofiller. Biodegradable polybutylene succinate (PBS) was incorporated with GOODA via solution intercalation method. GOODA does not profoundly affect the crystallinity of PBS/GOODA nanocomposite, but interestingly improves the mechanical and thermal properties. The addition of only 0.1 wt% GOODA nanofiller loading exhibited a sharp increase in tensile strength and Young’s modulus of up to 50 and 58.9%, respectively. The improvement in strength and thermal behavior could be attributed to the successful interfacial interaction between amine group in GOODA and carboxylic group in PBS chain tail via nucleophilic substitution reaction. This improved interphase structure enhanced the dispersion and exfoliation of GOODA in PBS matrix. Springer Berlin Heidelberg 2018 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/19847/1/Surface%20functionalization%20of%20graphene%20oxide1.pdf pdf en http://umpir.ump.edu.my/id/eprint/19847/2/Surface%20functionalization%20of%20graphene%20oxide.pdf Anis Sakinah, Zainal Abidin and Kamal, Yusoh and Saidatul Shima, Jamari and Abu Hannifa, Abdullah and Zulhelmi, Ismail (2018) Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite. Polymer Bulletin, 75 (8). pp. 3499-3522. ISSN 0170-0839(Print); 1436-2449(Online) https://doi.org/10.1007/s00289-017-2217-6 doi: 10.1007/s00289-017-2217-6
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Anis Sakinah, Zainal Abidin Kamal, Yusoh Saidatul Shima, Jamari Abu Hannifa, Abdullah Zulhelmi, Ismail Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
description	Modification of graphene oxide (GO) with long-chain aliphatic amine offers a substantial improvement in high-performance polymer as nanofiller in the composite. In this work, graphene oxide was functionalized with octadecylamine via sonochemical exfoliation method producing mono- to few-layer graphene oxide/octadecylamine (GOODA) nanofiller. Biodegradable polybutylene succinate (PBS) was incorporated with GOODA via solution intercalation method. GOODA does not profoundly affect the crystallinity of PBS/GOODA nanocomposite, but interestingly improves the mechanical and thermal properties. The addition of only 0.1 wt% GOODA nanofiller loading exhibited a sharp increase in tensile strength and Young’s modulus of up to 50 and 58.9%, respectively. The improvement in strength and thermal behavior could be attributed to the successful interfacial interaction between amine group in GOODA and carboxylic group in PBS chain tail via nucleophilic substitution reaction. This improved interphase structure enhanced the dispersion and exfoliation of GOODA in PBS matrix.
format	Article
author	Anis Sakinah, Zainal Abidin Kamal, Yusoh Saidatul Shima, Jamari Abu Hannifa, Abdullah Zulhelmi, Ismail
author_facet	Anis Sakinah, Zainal Abidin Kamal, Yusoh Saidatul Shima, Jamari Abu Hannifa, Abdullah Zulhelmi, Ismail
author_sort	Anis Sakinah, Zainal Abidin
title	Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_short	Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_full	Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_fullStr	Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_full_unstemmed	Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
title_sort	surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite
publisher	Springer Berlin Heidelberg
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/19847/ http://umpir.ump.edu.my/id/eprint/19847/ http://umpir.ump.edu.my/id/eprint/19847/ http://umpir.ump.edu.my/id/eprint/19847/1/Surface%20functionalization%20of%20graphene%20oxide1.pdf http://umpir.ump.edu.my/id/eprint/19847/2/Surface%20functionalization%20of%20graphene%20oxide.pdf
first_indexed	2023-09-18T22:28:27Z
last_indexed	2023-09-18T22:28:27Z
_version_	1777416124518891520

Surface functionalization of graphene oxide with octadecylamine for improved thermal and mechanical properties in polybutylene succinate nanocomposite

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