Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts

Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as...

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Main Authors:	Nur Nabillah, Mohd Arif, Vo, Dai-Viet N., Mohammad Tazli, Azizan, Sumaiya, Zainal Abidin
Format:	Article
Language:	English
Published:	Department of Chemical Engineering, Diponegoro University 2016
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/17403/ http://umpir.ump.edu.my/id/eprint/17403/ http://umpir.ump.edu.my/id/eprint/17403/ http://umpir.ump.edu.my/id/eprint/17403/1/fkksa-2016-sumaiya-Carbon%20Dioxide%20Dry%20Reforming%20of%20Glycerol%20for%20Hydrogen.pdf

id	ump-17403
recordtype	eprints
spelling	ump-174032019-10-30T03:29:28Z http://umpir.ump.edu.my/id/eprint/17403/ Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts Nur Nabillah, Mohd Arif Vo, Dai-Viet N. Mohammad Tazli, Azizan Sumaiya, Zainal Abidin TP Chemical technology Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out us-ing Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gra-vimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallin-ity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET. Department of Chemical Engineering, Diponegoro University 2016 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/17403/1/fkksa-2016-sumaiya-Carbon%20Dioxide%20Dry%20Reforming%20of%20Glycerol%20for%20Hydrogen.pdf Nur Nabillah, Mohd Arif and Vo, Dai-Viet N. and Mohammad Tazli, Azizan and Sumaiya, Zainal Abidin (2016) Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2). pp. 200-209. ISSN 1978-2993 http://dx.doi.org/10.9767/bcrec.11.2.551.200-209 doi: 10.9767/bcrec.11.2.551.200-209
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Nur Nabillah, Mohd Arif Vo, Dai-Viet N. Mohammad Tazli, Azizan Sumaiya, Zainal Abidin Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
description	Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out us-ing Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gra-vimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallin-ity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET.
format	Article
author	Nur Nabillah, Mohd Arif Vo, Dai-Viet N. Mohammad Tazli, Azizan Sumaiya, Zainal Abidin
author_facet	Nur Nabillah, Mohd Arif Vo, Dai-Viet N. Mohammad Tazli, Azizan Sumaiya, Zainal Abidin
author_sort	Nur Nabillah, Mohd Arif
title	Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_short	Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_full	Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_fullStr	Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_full_unstemmed	Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_sort	carbon dioxide dry reforming of glycerol for hydrogen production using ni/zro2 and ni/cao as catalysts
publisher	Department of Chemical Engineering, Diponegoro University
publishDate	2016
url	http://umpir.ump.edu.my/id/eprint/17403/ http://umpir.ump.edu.my/id/eprint/17403/ http://umpir.ump.edu.my/id/eprint/17403/ http://umpir.ump.edu.my/id/eprint/17403/1/fkksa-2016-sumaiya-Carbon%20Dioxide%20Dry%20Reforming%20of%20Glycerol%20for%20Hydrogen.pdf
first_indexed	2023-09-18T22:24:00Z
last_indexed	2023-09-18T22:24:00Z
_version_	1777415844877303808

Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts

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