Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield

Crosslinked polymer beads were prepared by photoinitiated dispersion polymerization in a mixture of ethanol and water. In this study, the effect of types of photoinitiator, types of monomer and reaction times on particles morphology, size and size distribution and yield were investigated. Better qua...

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Main Authors:	R., Mahmod, M. Z., Yahya, Norhayati, Abdullah
Format:	Article
Language:	English
Published:	Informatics Publishing Limited 2017
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/17094/ http://umpir.ump.edu.my/id/eprint/17094/ http://umpir.ump.edu.my/id/eprint/17094/ http://umpir.ump.edu.my/id/eprint/17094/1/Photoinitiated%20dispersion%20polymerization%20of%20crosslinked%20polymer%20in%20polar%20solvents.pdf

id	ump-17094
recordtype	eprints
spelling	ump-170942018-03-01T05:29:28Z http://umpir.ump.edu.my/id/eprint/17094/ Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield R., Mahmod M. Z., Yahya Norhayati, Abdullah TP Chemical technology Crosslinked polymer beads were prepared by photoinitiated dispersion polymerization in a mixture of ethanol and water. In this study, the effect of types of photoinitiator, types of monomer and reaction times on particles morphology, size and size distribution and yield were investigated. Better quality of poly(st-co-EGDMA-co-VBC) obtained compared to poly (methylmethacrylate-co- EGDMA-co-VBC). However, the yield of poly(st-co-EGDMA-co-VBC) lower than poly (methylmethacrylate-co-EGDMA-co-VBC). On this regard, poly(methylmethacrylate-co-EGDMA-co-VBC) was selected to investigate further. Changing the types of photoinitiator managed to increase the quality and size of poly (methylmethacrylate-co-EGDMA-co-VBC) particles but yield obtained was decreasing. Meanwhile, longer reaction time leading to high yield and bigger size of poly (methylmethacrylate-co-EGDMA-co- VBC) particles but with lower quality. For all cases, FTIR analysis proved all functional groups have successfully attached to the polymeric backbone. Informatics Publishing Limited 2017-01 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/17094/1/Photoinitiated%20dispersion%20polymerization%20of%20crosslinked%20polymer%20in%20polar%20solvents.pdf R., Mahmod and M. Z., Yahya and Norhayati, Abdullah (2017) Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield. Indian Journal of Science and Technology, 10 (2). pp. 1-7. ISSN 0974-6846(print); 0974-5645(online) http://dx.doi.org/10.17485/ijst%2F2017%2Fv10i2%2F110372 DOI: 10.17485/ijst/2017/v10i2/110372
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology R., Mahmod M. Z., Yahya Norhayati, Abdullah Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield
description	Crosslinked polymer beads were prepared by photoinitiated dispersion polymerization in a mixture of ethanol and water. In this study, the effect of types of photoinitiator, types of monomer and reaction times on particles morphology, size and size distribution and yield were investigated. Better quality of poly(st-co-EGDMA-co-VBC) obtained compared to poly (methylmethacrylate-co- EGDMA-co-VBC). However, the yield of poly(st-co-EGDMA-co-VBC) lower than poly (methylmethacrylate-co-EGDMA-co-VBC). On this regard, poly(methylmethacrylate-co-EGDMA-co-VBC) was selected to investigate further. Changing the types of photoinitiator managed to increase the quality and size of poly (methylmethacrylate-co-EGDMA-co-VBC) particles but yield obtained was decreasing. Meanwhile, longer reaction time leading to high yield and bigger size of poly (methylmethacrylate-co-EGDMA-co- VBC) particles but with lower quality. For all cases, FTIR analysis proved all functional groups have successfully attached to the polymeric backbone.
format	Article
author	R., Mahmod M. Z., Yahya Norhayati, Abdullah
author_facet	R., Mahmod M. Z., Yahya Norhayati, Abdullah
author_sort	R., Mahmod
title	Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield
title_short	Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield
title_full	Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield
title_fullStr	Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield
title_full_unstemmed	Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield
title_sort	photoinitiated dispersion polymerization of crosslinked polymer in polar solvents: effect of reaction parameter on morphology, size and size distribution and yield
publisher	Informatics Publishing Limited
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/17094/ http://umpir.ump.edu.my/id/eprint/17094/ http://umpir.ump.edu.my/id/eprint/17094/ http://umpir.ump.edu.my/id/eprint/17094/1/Photoinitiated%20dispersion%20polymerization%20of%20crosslinked%20polymer%20in%20polar%20solvents.pdf
first_indexed	2023-09-18T22:23:21Z
last_indexed	2023-09-18T22:23:21Z
_version_	1777415803297071104

Photoinitiated Dispersion Polymerization of Crosslinked Polymer in Polar Solvents: Effect of Reaction Parameter on Morphology, Size and Size Distribution and Yield

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