Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions
Bio-heterogeneous poly(amidoxime) copper nanoparticles were prepared on the modified surface of waste corn-cob cellulose through a graft copolymerization process. The Cu-nanoparticles (0.05 mol% to 50 mol ppm) selectively promoted the aza-Michael reaction of aliphatic amines to give the correspondin...
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Royal Society of Chemistry
2016
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ump-168222020-02-21T08:09:09Z http://umpir.ump.edu.my/id/eprint/16822/ Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff QD Chemistry Bio-heterogeneous poly(amidoxime) copper nanoparticles were prepared on the modified surface of waste corn-cob cellulose through a graft copolymerization process. The Cu-nanoparticles (0.05 mol% to 50 mol ppm) selectively promoted the aza-Michael reaction of aliphatic amines to give the corresponding alkylated products at room temperature in methanol. The supported nanoparticles were easy to recover and reused eight times without a significant loss of their activity. Royal Society of Chemistry 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16822/1/fist-2016-shaheen-Waste%20corn-cob%20cellulose1.pdf Sarkar, Shaheen M. and Sultana, Tahnim and Biswas, Tapan Kumar and Lutfor, M. R. and M. M., Yusoff (2016) Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions. New Journal of Chemistry, 40. pp. 497-502. ISSN 1144-0546 http://dx.doi.org/10.1039/C5NJ02437D DOI: 10.1039/C5NJ02437D |
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QD Chemistry Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions |
description |
Bio-heterogeneous poly(amidoxime) copper nanoparticles were prepared on the modified surface of waste corn-cob cellulose through a graft copolymerization process. The Cu-nanoparticles (0.05 mol% to 50 mol ppm) selectively promoted the aza-Michael reaction of aliphatic amines to give the corresponding alkylated products at room temperature in methanol. The supported nanoparticles were easy to recover and reused eight times without a significant loss of their activity. |
format |
Article |
author |
Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff |
author_facet |
Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff |
author_sort |
Sarkar, Shaheen M. |
title |
Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions |
title_short |
Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions |
title_full |
Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions |
title_fullStr |
Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions |
title_full_unstemmed |
Waste Corn-Cob Cellulose Supported Bio-Heterogeneous Copper Nanoparticles for Aza-Michael Reactions |
title_sort |
waste corn-cob cellulose supported bio-heterogeneous copper nanoparticles for aza-michael reactions |
publisher |
Royal Society of Chemistry |
publishDate |
2016 |
url |
http://umpir.ump.edu.my/id/eprint/16822/ http://umpir.ump.edu.my/id/eprint/16822/ http://umpir.ump.edu.my/id/eprint/16822/ http://umpir.ump.edu.my/id/eprint/16822/1/fist-2016-shaheen-Waste%20corn-cob%20cellulose1.pdf |
first_indexed |
2023-09-18T22:22:50Z |
last_indexed |
2023-09-18T22:22:50Z |
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1777415771063844864 |