Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach

Corn-cob cellulose supported poly(hydroxamic acid) Cu(II) complex was prepared by the surface modification of waste corn-cob cellulose through graft copolymerization and subsequent hydroximation. The complex was characterized by IR, UV, FESEM, TEM, XPS, EDX and ICP-AES analyses. The complex has been...

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Main Authors:	Mandal, Bablu Hira, Lutfor, M. R., M. M., Yusoff, K. F., Chong, Sarkar, Shaheen M.
Format:	Article
Language:	English
Published:	Elsevier Ltd 2017
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/16576/ http://umpir.ump.edu.my/id/eprint/16576/ http://umpir.ump.edu.my/id/eprint/16576/ http://umpir.ump.edu.my/id/eprint/16576/1/fist-2017-shaheen-Bio-waste%20corn-cob%20cellulose1.pdf

id	ump-16576
recordtype	eprints
spelling	ump-165762019-09-10T02:27:57Z http://umpir.ump.edu.my/id/eprint/16576/ Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach Mandal, Bablu Hira Lutfor, M. R. M. M., Yusoff K. F., Chong Sarkar, Shaheen M. Q Science (General) Corn-cob cellulose supported poly(hydroxamic acid) Cu(II) complex was prepared by the surface modification of waste corn-cob cellulose through graft copolymerization and subsequent hydroximation. The complex was characterized by IR, UV, FESEM, TEM, XPS, EDX and ICP-AES analyses. The complex has been found to be an efficient catalyst for 1,3-dipolar Huisgen cycloaddition (CuAAC) of aryl/alkyl azides with a variety of alkynes as well as one-pot three-components reaction in the presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield and high turn over number (TON 18,600) and turn over frequency (TOF 930 h−1) were achieved. The complex was easy to recover from the reaction mixture and reused six times without significant loss of its catalytic activity. Elsevier Ltd 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16576/1/fist-2017-shaheen-Bio-waste%20corn-cob%20cellulose1.pdf Mandal, Bablu Hira and Lutfor, M. R. and M. M., Yusoff and K. F., Chong and Sarkar, Shaheen M. (2017) Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach. Carbohydrate Polymers, 156. pp. 175-181. ISSN 0144-8617 http://dx.doi.org/10.1016/j.carbpol.2016.09.021 DOI: 10.1016/j.carbpol.2016.09.021
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Mandal, Bablu Hira Lutfor, M. R. M. M., Yusoff K. F., Chong Sarkar, Shaheen M. Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach
description	Corn-cob cellulose supported poly(hydroxamic acid) Cu(II) complex was prepared by the surface modification of waste corn-cob cellulose through graft copolymerization and subsequent hydroximation. The complex was characterized by IR, UV, FESEM, TEM, XPS, EDX and ICP-AES analyses. The complex has been found to be an efficient catalyst for 1,3-dipolar Huisgen cycloaddition (CuAAC) of aryl/alkyl azides with a variety of alkynes as well as one-pot three-components reaction in the presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield and high turn over number (TON 18,600) and turn over frequency (TOF 930 h−1) were achieved. The complex was easy to recover from the reaction mixture and reused six times without significant loss of its catalytic activity.
format	Article
author	Mandal, Bablu Hira Lutfor, M. R. M. M., Yusoff K. F., Chong Sarkar, Shaheen M.
author_facet	Mandal, Bablu Hira Lutfor, M. R. M. M., Yusoff K. F., Chong Sarkar, Shaheen M.
author_sort	Mandal, Bablu Hira
title	Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach
title_short	Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach
title_full	Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach
title_fullStr	Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach
title_full_unstemmed	Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach
title_sort	bio-waste corn-cob cellulose supported poly(hydroxamic acid) copper complex for huisgen reaction: waste to wealth approach
publisher	Elsevier Ltd
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/16576/ http://umpir.ump.edu.my/id/eprint/16576/ http://umpir.ump.edu.my/id/eprint/16576/ http://umpir.ump.edu.my/id/eprint/16576/1/fist-2017-shaheen-Bio-waste%20corn-cob%20cellulose1.pdf
first_indexed	2023-09-18T22:22:22Z
last_indexed	2023-09-18T22:22:22Z
_version_	1777415742166138880

Bio-waste Corn-cob Cellulose Supported Poly(hydroxamic acid) Copper Complex for Huisgen Reaction: Waste to Wealth Approach

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