Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process

Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process

Hypercrosslinked microsphere hydrophilic polymer derived from 2-hydroxylethyl methacrylate (HEMA), ethylene glycol dimethacrylate (EDGMA), and vinyl benzene chloride (VBC) have been successfully synthesized using hypercrosslinking reaction chemistry. In this study, dispersion polymerization techniqu...

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Main Authors: Mohammad Zuhaili, Yahya, Norhayati, Abdullah
Format: Article
Language:English
Published: Penerbit Universiti Malaysia Pahang 2016
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/16194/
http://umpir.ump.edu.my/id/eprint/16194/
http://umpir.ump.edu.my/id/eprint/16194/1/fkksa-2016-Development_of_Hypercrosslinked_Hydrophilic_Polymer1.pdf
id ump-16194
recordtype eprints
spelling ump-161942018-09-18T01:06:54Z http://umpir.ump.edu.my/id/eprint/16194/ Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process Mohammad Zuhaili, Yahya Norhayati, Abdullah TP Chemical technology Hypercrosslinked microsphere hydrophilic polymer derived from 2-hydroxylethyl methacrylate (HEMA), ethylene glycol dimethacrylate (EDGMA), and vinyl benzene chloride (VBC) have been successfully synthesized using hypercrosslinking reaction chemistry. In this study, dispersion polymerization technique has been used in order to develop precursor prior to hypercrosslinking reaction. Mixture of water/toluene system as a medium polymerization showed promising result with high yield and good quality of microsphere precursor and meanwhile increasing VBC content up to 5% based on monomer feed showed decreasing in quality of microsphere precursor in term of shape and size. FTIR result showed both EDGMA and VBC successfully incorporated into the precursor polymer backbone. After undergo hypercrosslinking reaction, hypercrosslinked microsphere polymer still can retain their original shape as before hypercrosslinking reaction with satisfy quality. From BET analysis, it showed slightly increment in specific surface area of hypercrosslinked microsphere polymer from 10.621 m2/g to 16.831 m2/g. Penerbit Universiti Malaysia Pahang 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16194/1/fkksa-2016-Development_of_Hypercrosslinked_Hydrophilic_Polymer1.pdf Mohammad Zuhaili, Yahya and Norhayati, Abdullah (2016) Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process. Journal of Malaysian Critical Metals, 1. pp. 31-39. ISSN 0128-2557 http://mycm.ump.edu.my/images/Vol12016/Development_of_Hypercrosslinked_Hydrophilic_Polymer_using_Dispersion_Polymerization_Technique_for_Separation_Process.pdf
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Mohammad Zuhaili, Yahya
Norhayati, Abdullah
Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
description Hypercrosslinked microsphere hydrophilic polymer derived from 2-hydroxylethyl methacrylate (HEMA), ethylene glycol dimethacrylate (EDGMA), and vinyl benzene chloride (VBC) have been successfully synthesized using hypercrosslinking reaction chemistry. In this study, dispersion polymerization technique has been used in order to develop precursor prior to hypercrosslinking reaction. Mixture of water/toluene system as a medium polymerization showed promising result with high yield and good quality of microsphere precursor and meanwhile increasing VBC content up to 5% based on monomer feed showed decreasing in quality of microsphere precursor in term of shape and size. FTIR result showed both EDGMA and VBC successfully incorporated into the precursor polymer backbone. After undergo hypercrosslinking reaction, hypercrosslinked microsphere polymer still can retain their original shape as before hypercrosslinking reaction with satisfy quality. From BET analysis, it showed slightly increment in specific surface area of hypercrosslinked microsphere polymer from 10.621 m2/g to 16.831 m2/g.
format Article
author Mohammad Zuhaili, Yahya
Norhayati, Abdullah
author_facet Mohammad Zuhaili, Yahya
Norhayati, Abdullah
author_sort Mohammad Zuhaili, Yahya
title Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
title_short Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
title_full Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
title_fullStr Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
title_full_unstemmed Development of Hypercrosslinked Hydrophilic Polymer using Dispersion Polymerization Technique for Separation Process
title_sort development of hypercrosslinked hydrophilic polymer using dispersion polymerization technique for separation process
publisher Penerbit Universiti Malaysia Pahang
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/16194/
http://umpir.ump.edu.my/id/eprint/16194/
http://umpir.ump.edu.my/id/eprint/16194/1/fkksa-2016-Development_of_Hypercrosslinked_Hydrophilic_Polymer1.pdf
first_indexed 2023-09-18T22:21:39Z
last_indexed 2023-09-18T22:21:39Z
_version_ 1777415696619143168

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