Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions

A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding...

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Main Authors:	Mandal, Bablu Hira, Sarkar, Shaheen M., Lutfor, M. R., Mohd Hasbi, Ab. Rahim
Format:	Conference or Workshop Item
Language:	English
Published:	Universiti Malaysia Pahang 2016
Subjects:	TA Engineering (General). Civil engineering (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/1/P090%20pg663-675.pdf

id	ump-15778
recordtype	eprints
spelling	ump-157782019-09-10T02:36:01Z http://umpir.ump.edu.my/id/eprint/15778/ Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim TA Engineering (General). Civil engineering (General) A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number(TON) and frequency(TOF) were 144615 and 9641 h–1 respectively. Universiti Malaysia Pahang 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15778/1/P090%20pg663-675.pdf Mandal, Bablu Hira and Sarkar, Shaheen M. and Lutfor, M. R. and Mohd Hasbi, Ab. Rahim (2016) Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions. In: Proceedings of The National Conference for Postgraduate Research (NCON-PGR 2016), 24-25 September 2016 , Universiti Malaysia Pahang (UMP), Pekan, Pahang. pp. 663-675.. http://ee.ump.edu.my/ncon/wp-content/uploads/2016/10/Proceeding-NCON-PGR-2016.zip
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TA Engineering (General). Civil engineering (General)
spellingShingle	TA Engineering (General). Civil engineering (General) Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
description	A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was sythesized and the catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently allylic arylation of allylic ester with sodium tetraarylborates and arylboronic acids in ethanol at 60 °C temperature. Oustanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number(TON) and frequency(TOF) were 144615 and 9641 h–1 respectively.
format	Conference or Workshop Item
author	Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim
author_facet	Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim
author_sort	Mandal, Bablu Hira
title	Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
title_short	Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
title_full	Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
title_fullStr	Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
title_full_unstemmed	Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions
title_sort	synthesis of kenaf cellulose supported highly active poly(amidoxime) palladium complex and its application as a reusable catalyst for allylic arylation reactions
publisher	Universiti Malaysia Pahang
publishDate	2016
url	http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/ http://umpir.ump.edu.my/id/eprint/15778/1/P090%20pg663-675.pdf
first_indexed	2023-09-18T22:20:49Z
last_indexed	2023-09-18T22:20:49Z
_version_	1777415643957559296

Synthesis of Kenaf Cellulose Supported Highly Active Poly(amidoxime) Palladium Complex and Its Application as a Reusable Catalyst for Allylic Arylation reactions

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