Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions

A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was synthesized and characterized with FTIR, UV-Vis, FESEM, XPS and TEM analyses. The catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently the allylic arylation of allylic ester with sodium tetraarylborates...

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Main Authors:	Mandal, Bablu Hira, Sarkar, Shaheen M., Lutfor, M. R., Mohd Hasbi, Ab. Rahim
Format:	Conference or Workshop Item
Language:	English
Published:	UTM Press 2016
Subjects:	QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/1/526-528.pdf

id	ump-15767
recordtype	eprints
spelling	ump-157672019-09-10T02:35:17Z http://umpir.ump.edu.my/id/eprint/15767/ Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim QD Chemistry A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was synthesized and characterized with FTIR, UV-Vis, FESEM, XPS and TEM analyses. The catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently the allylic arylation of allylic ester with sodium tetraarylborates in ethanol at 60 °C temperature. Outstanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number (TON) and frequency (TOF) were 144615 and 9641 h–1 respectively. UTM Press 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15767/1/526-528.pdf Mandal, Bablu Hira and Sarkar, Shaheen M. and Lutfor, M. R. and Mohd Hasbi, Ab. Rahim (2016) Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions. In: Proceedings of the 6th IGCESH2016: International Graduate Conference on Engineering, Science and Humanities, 15-17 August 2016 , Universiti Teknologi Malaysia, Johor. pp. 498-500.. ISBN 978-967-0194-67-7 http://sps.utm.my/igcesh2016/conference-proceedings/
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
description	A highly active kenaf cellulose supported poly(amidoxime) palladium catalyst was synthesized and characterized with FTIR, UV-Vis, FESEM, XPS and TEM analyses. The catalyst (65 mol ppm to 6.5 mol ppm) was found to promote efficiently the allylic arylation of allylic ester with sodium tetraarylborates in ethanol at 60 °C temperature. Outstanding yields of the corresponding products as well as significant reusability of the catalyst were obtained. The total turnover number (TON) and frequency (TOF) were 144615 and 9641 h–1 respectively.
format	Conference or Workshop Item
author	Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim
author_facet	Mandal, Bablu Hira Sarkar, Shaheen M. Lutfor, M. R. Mohd Hasbi, Ab. Rahim
author_sort	Mandal, Bablu Hira
title	Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
title_short	Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
title_full	Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
title_fullStr	Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
title_full_unstemmed	Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions
title_sort	kenaf cellulose supported highly active poly(amidoxime) palladium complex as a reusable heterogeneous catalyst for allylic arylation reactions
publisher	UTM Press
publishDate	2016
url	http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/ http://umpir.ump.edu.my/id/eprint/15767/1/526-528.pdf
first_indexed	2023-09-18T22:20:47Z
last_indexed	2023-09-18T22:20:47Z
_version_	1777415642371063808

Kenaf Cellulose Supported Highly Active Poly(Amidoxime) Palladium Complex as a Reusable Heterogeneous Catalyst For Allylic Arylation Reactions

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